On the deformation of quartzite

In view of the apparent difficulty of satisfying the von Mises criterion for general plasticity by dislocation glide alone, the climb mechanism proposed by Nabarro (1967) has been considered as an important contributor to the steady state deformation of quartzites in the earth's crust. The proposed deformation mechanism can provide the necessary strain rates; it is consistent with the observed dislocation structures and leads to a simple explanation of the water weakening phenomenon in terms of the increase in diffusivity of the atom species. In addition, the experimentally observed effects of strain rate and temperature on the opening angle of the characteristic ‘girdle’ fabrics of quartzite are a natural consequence of the model and this relationship could provide analytical procedures for the establishment of crustal deformation conditions.     

New constraints on granulite facies metamorphism and melt production in the Lewisian Complex,northwest Scotland

In this study, we investigate the metamorphic history of the Assynt and Gruinard blocks of the Archean Lewisian Complex, northwest Scotland, which are considered by some to represent discrete crustal terranes. For samples of mafic and intermediate rocks, phase diagrams were constructed in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O₂ (NCKFMASHTO) system using whole‐rock compositions. Our results indicate that all samples equilibrated at similar peak metamorphic conditions of ~8–10 kbar and ~900–1,000°C, consistent with field evidence for in situ partial melting and the classic interpretation of the central region of the Lewisian Complex as representing a single crustal block. Melt‐reintegration modelling was employed in order to estimate probable protolith compositions. Phase equilibria calculated for these modelled undepleted precursors match well with those determined for a subsolidus amphibolite from Gairloch in the southern region of the Lewisian Complex. Both subsolidus lithologies exhibit similar phase relations and potential melt fertility, with both expected to produce orthopyroxene‐bearing hornblende granulites, with or without garnet, at the conditions inferred for the Badcallian metamorphic peak. For fully hydrated protoliths, prograde melting is predicted to first occur at ~620°C and ~9.5 kbar, with up to 45% partial melt predicted to form at peak conditions in a closed‐system environment. Partial melts calculated for both compositions between 610 and 1,050°C are mostly trondhjemitic. Although the melt‐reintegrated granulite is predicted to produce more potassic (granitic) melts at ~700–900°C, the modelled melts are consistent with the measured compositions of felsic sheets from the central region Lewisian Complex.     

Palaeoclimatic reconstruction from Lateglacial (Younger Dryas Chronozone) cirque glaciers in Snowdonia,North Wales

The cirques of Snowdonia, North Wales were last occupied by glacier ice during the Younger Dryas Chronozone (YDC), c. 12.9–11.7 ka. New mapping presented here indicates 38 small YDC cirque glaciers formed in Snowdonia, covering a total area of 20.74 km². Equilibrium line altitudes (ELAs) for these glaciers, calculated using an area–altitude balance ratio (AABR) approach, ranged from 380 to 837 m asl. A northeastwards rise in YDC ELAs across Snowdonia is consistent with southwesterly snow-bearing winds. Regional palaeoclimate reconstructions indicate that the YDC in North Wales was colder and drier than at present. Palaeotemperature and annual temperature range estimates, derived from published palaeoecological datasets, were used to reconstruct values of annual accumulation and ‘winter balance plus summer precipitation’ using a degree-day model (DDM) and non-linear regression function, respectively. The DDM acted as the best-estimate for stadial precipitation and yielded values between 2073 and 2687 mm a^?1 (lapse rate: 0.006 °C m^?1) and 1782–2470 mm a^?1 (lapse rate: 0.007 °C m^?1). Accounting for the potential input of windblown and avalanched snow onto former glacier surfaces, accumulation values dropped to between 1791 and 2616 mm a^?1 (lapse rate: 0.006 °C m^?1) and 1473–2390 mm a^?1 (lapse rate: 0.007 °C m^?1). The spatial pattern of stadial accumulation suggests a steep precipitation gradient and provides verification of the northeastwards rise in ELAs. Glaciers nearer the coast of North Wales were most responsive to fluctuations in climate during the YDC, responding to sea-ice enforced continentality during the coldest phases of the stadial and to abrupt warming at the end of the stadial.     

Factor of safety in a partially saturated slope inferred from hydro‐mechanical continuum modeling

Rainfall weakens an earth slope and triggers mass movement. Relevant triggering mechanisms are complex and include reduction of capillary pressure due to increased saturation and frictional drag on the sediment induced by fluid flow. Physics‐based continuum models utilizing modern computational tools are useful for understanding the mechanisms of deformation in partially saturated slopes; however, they do not provide a scalar indicator called ‘factor of safety’ that measures the potential of a given slope for mass movement. In the present work, we employ sequential calculations consisting of a physics‐based finite element model that couples solid deformation with fluid flow to quantify the stress and deformation fields in a steep hillside slope subjected to rainfall infiltration. This is followed by a limit‐equilibrium calculation based on the method of slices that evaluates the desired factor of safety. The field condition investigated is similar to the steep experimental catchment CB1 near Coos Bay, Oregon, which failed as a large debris flow from heavy rainfall. Copyright © 2011 John Wiley & Sons, Ltd.     

Hydrogen and oxygen isotope exchange reactions between clay minerals and water

The extent of hydrogen and oxygen isotope exchange between clay minerals and water has been measured in the temperature range 100–350° for bomb runs of up to almost 2 years. Hydrogen isotope exchange between water and the clays was demonstrable at 100°. Exchange rates were 3–5 times greater for montmorillonite than for kaolinite or illite and this is attributed to the presence of interlayer water in the montmorillonite structure.Negligible oxygen isotope exchange occurred at these low temperatures. The great disparity in D and O¹⁸ exchange rates observed in every experiment demonstrates that hydrogen isotope exchange occurred by a mechanism of proton exchange independent of the slower process of O¹⁸ exchange.At 350° kaolinite reacted to form pyrophyllite and diaspore. This was accompanied by essentially complete D exchange but minor O¹⁸ exchange and implies that intact structural units in the pyrophyllite were inherited from the kaolinite precursor.     

Water activity changes across an amphibolite-granulite facies transition,Broken Hill,Australia

Phase compositions in pelitic and mafic gneisses place tight constraints on pressure (ranging from 3 up to 6 kb), and, to a lesser extent, on temperature (500° up to 800° C) during prograde regional metamorphism of the Willyama Complex, Broken Hill, SE Australia. These limits allow an evaluation of water activity across the terrain using various equilibria in pelitic and mafic gneisses. The stability of cummingtonite and biotite over much of the terrain places upper limits on temperature, and the presence of syn-metamorphic partial melts in the metasediments places lower limits on a(H₂O). Garnet-biotitesillimanite-K feldspar-quartz relations combined with the partial melting data suggest a decrease in water activity from near 1.0 in the lower grade zones to 0.5±0.2 in the Broken Hill — Little Broken Hill part of the two pyroxene zone. This result is compatible with less precise hornblende-orthopyroxene-clinopyroxene-quartz relations.These P-T-a(H₂O) data from the Willyama Complex support a continuum from amphibolite to granulite facies, as proposed by Binns (1964) and suggest that the higher grade assemblages are formed in response to both higher temperature and lower water activity. The formation of granulite facies terrains by prior crustal dehydration is unsubstantiated in the present example. Instead, the decrease from a(H₂O)-1.0 in the andalusite/sillimanite-muscovite zones to a(H₂O) < 1.0 found at higher grades, is likely to reflect buffering by partial melting and dehydration reactions in the volumetrically dominant metasediments.     

Complex zoning between super-calcic pigeonite and augite from the Graveyard Point sill, Oregon: a record of the interplay between bulk and interstitial liquid fractionation

The 150 m thick late Miocene Graveyard Point sill (GPS) is situated at the Idaho-Oregon border near the southwestern edge of the western Snake River Plain. It records from bottom to top continuous fractional crystallization of a tholeiitic parent magma (lower chilled border, FeO/(FeO+MgO) = 0.59, Ni = 90 ppm) towards granophyres (late pods and dikes, FeO/(FeO+MgO) = 0.98, 78 wt% SiO₂ 3.5 wt% K₂O, <4 ppm Ni) showing a typical trend of Fe and P enrichment. Fractionating minerals are olivine (Fo₇₉-Fo₂), augite (X _Fe = 0.18−0.95), feldspars (An₈₀Or₁-An₁Or₆₂), Fe-Ti oxides (Ti-rich magnetite and ilmenite), apatite and in two samples super-calcic pigeonite (Wo_18–28 Fs_41–54). The granophyres may bear some quartz. Compositionally zoned minerals record a large interval of the fractionation process in every single sample, but this interval changes with stratigraphic height. In super-calcic pigeonite-bearing samples, olivine is scarce or lacking and because super-calcic pigeonite occurs as characteristic overgrowths on augite, its formation is interpreted to be related to the schematic reaction: augite + olivine (component in melt) + SiO₂ (in melt) = pigeonite, that defines the cotectic between augite and pigeonite in olivine-saturated basaltic systems. Line measurements with the electron microprobe reveal that the transition from augite to super-calcic pigeonite is continuous. However, some crystals show an abrupt “reversal” towards augite after super-calcic pigeonite growth. Two processes compete with each other in the GPS: fractional crystallization of the bulk liquid (the bulk melt separates from solids and interstitial liquids in the solidification front) and fractional crystallization of interstitial melt in the solidification front itself. Interplay between those two processes is proposed to account for the observed variations in mineral chemistry and mineral textures. Received: 25 November 1998 / Accepted: 14 June 1999     

Architecture of a tide-influenced river delta in the Frontier Formation of central Wyoming, USA

The Frewens sandstone is composed of two elongate tide-influenced sandstone bodies that are positioned directly above and slightly landward of a more wave-influenced lobate sandstone. The 20-km-long, 3-km-wide Frewens sandstone bodies coarsen upwards and fine away from their axes, have gradational bases and margins and have eroded tops abruptly overlain by marine shales. These sandstones are superbly exposed in large cliffs on the banks of the South Fork of the Powder River in central Wyoming, USA. The deposits change upwards from thinly interbedded sandstones and mudstones to metre-thick heterolithic cross-strata and, finally, to metres-thick sandstone-dominated cross-strata. There is abundant evidence for tidal modulation of depositional flows; however, palaeocurrents were strongly ebb-dominated and nearly parallel the trend of sandstone-body elongation. Detailed mapping of stratal geometry and facies across these exposures shows a complex internal architecture. Large-scale bedding units within sandstone bodies are defined by alternations in facies, bed thickness and the abundance of shales. Such bedsets are inclined (5°–15°) in walls oriented parallel to palaeoflow and gradually decrease in dip over hundreds of metres as they extend from the sandstone-dominated deposits higher in a sandstone body to muddier deposits lower in the body. Where viewed perpendicular to palaeoflow, bedsets are 100-metre-wide lenses that shingle off the sandstone-body axis towards its margins. The sandstone bodies are interpreted as sand ridge deposits formed on the shoreface of a tide-influenced river delta. Metres-thick cross-strata in the upper parts of sandstone bodies resemble deposits of bars (sandwaves) formed where tidal currents moved across shallows and the tops of tidal ridges. Heterolithic deposits lower in sandstone bodies record fluctuating currents caused by ebb and flood tides and varying river discharge. Erosion surfaces capping sandstone bodies record tidal ravinement. The tidal ridges were abandoned following transgression and covered with marine mud as waters deepened.     

A critical evaluation of multi‐proxy dendroclimatology in northern Finland

Twentieth‐century summer (July–August) temperatures in northern Finland are reconstructed using ring widths, maximum density and stable carbon isotope ratios (δ¹³C) of Scots pine tree rings, and using combinations of these proxies. Verification is based on the coefficient of determination (r²), reduction of error (RE) and coefficient of efficiency (CE) statistics. Of the individual proxies, δ¹³C performs best, followed by maximum density. Combining δ¹³C and maximum density strengthens the climate signal but adding ring widths leads to little improvement. Blue intensity, an inexpensive alternative to X‐ray densitometry, is shown to perform similarly. Multi‐proxy reconstruction of summer temperatures from a single site produces strong correlations with gridded climate data over most of northern Fennoscandia. Since relatively few trees are required (<15) the approach could be applied to long sub‐fossil chronologies where replication may be episodically low. Copyright © 2010 John Wiley & Sons, Ltd.