Reach‐scale channel geometry of a mountain river

Mountain rivers can be subject to strong constraints imposed by changes in gradient and grain size supplied by processes such as glaciation and rockfall. Nonetheless, adjustments in the channel geometry and hydraulics of mountain rivers at the reach scale can produce discernible patterns analogous to those in fully alluvial rivers. Mountain rivers can differ in that imposed reach‐scale gradient is an especially important control on reach‐scale channel characteristics, as indicated by examination of North St Vrain Creek in Colorado. North St Vrain Creek drains 250 km² of the Rocky Mountains. We used 25 study reaches within the basin to examine controls on reach‐scale channel geometry. Variables measured included channel geometry, large woody debris, grain size, and mean velocity. Drainage area at the study reaches ranged from 2·2 to 245 km², and gradient from 0·013 to 0·147 m m^?1. We examined correlations among (1) potential reach‐scale response variables describing channel bankfull dimension and shape, hydraulics, bedform wavelength and amplitude, grain size, ?ow resistance, standard deviation of hydraulic radius, and volume of large woody debris, and (2) potential control variables that change progressively downstream (drainage area, discharge) or that are likely to re?ect a reach‐speci?c control (bed gradient). We tested the hypothesis that response variables correlate most strongly with local bed gradient because of the segmented nature of mountain channels. Results from simple linear regression analyses indicate that most response variables correlate best with gradient, although channel width and width/depth ratio correlate best with discharge. Multiple regression analyses using Mallow's C_p selection criterion and log‐transformation of all variables produced similar results in that most response variables correlate strongly with gradient. These results suggest that the hypothesis is partially supported: channel bed gradient is likely to be a good predictor for many reach‐scale response variables along mountain rivers, but discharge is also an important predictor for some response variables. Copyright © 2004 John Wiley & Sons, Ltd.     

Crystallization of magmatic iron meteorites: The role of mixing in the molten core

Abstract— The IIIAB group is the largest of the magmatic iron meteorite groups and consequently is commonly used to test models of asteroid core crystallization. Simple fractional crystallization calculations appear to reproduce the general shape of the elemental trends observed in the IIIAB group when these trends are plotted vs. Ni, as is traditionally done. However, when the elemental trends are examined vs. another element (such as Ge vs. Ir), simple fractional crystallization fails to match a significant portion of the trend, specifically meteorites formed during the final stages of crystallization. Our simple mixing model, which attempts to account for the possibility of inhomogeneities in the molten metallic core, is able to reproduce the entire IIIAB trend observed. This model is a variant of simple fractional crystallization and involves mixing between a zone of liquid involved in the crystallization process and a second zone too far from the crystallizing solid to be actively involved in crystallization. This model does not suggest one unique solution for the method by which an asteroidal core crystallizes; rather it demonstrates that including the effects of mixing in the molten core can account for the observed IIIAB elemental trends, particularly the late-stage crystallizing members, which other models have difficulty explaining.     

The significance of the personal within disability geography

Drawing on in-depth qualitative data, this article critically examines disability geography as a subfield where the personal is highly valued. The value and the risks inherent in this personal approach will be evaluated, including the usefulness of being an 'insider' and the difficulties of being reflexive and critically making use of one's positionality. The article concludes with reflections regarding how disability geography can confront its marginal status, appealing to researchers who claim no experience of disability while also supporting and encouraging those with personal experiences of disability to participate in the field.     

Controls on chemistry and diagenesis of naturally occurring iron-oxide phases

The purposes of this study were to (i) document chemical and mineralogical compositions in two naturally acidic drainages over a 1 m soil profile, (ii) document organic and inorganic signatures representative of past chemical or biological processes in the soils, and (iii) determine whether mineralogical and chemical differences are a consequence of differences in original composition, depositional conditions, or diagenesis. Two sites were studied: Paymaster Creek in the Heddleston Mining District near Lincoln, Montana and the New World Mining District near Cooke City, Montana. The oldest deposits at both naturally acidic sites pre-date human mining activity by several thousand years, although there is recent human activity at both sites. Both sites have streams with high dissolved Fe and moderately low pH and actively accumulate schwertmannite on streambeds. Soil deposits away from the streambed at Paymaster Creek contained goethite with adsorbed sulfate, but no schwertmannite, suggesting either that the original conditions precluded schwertmannite precipitation or that diagenesis occurred rapidly converting the schwertmannite to goethite. The New World Mining District site showed the expected profile, which is a gradual transition from schwertmannite- and goethite-bearing soils to goethite-only soils. Concentrations of Cr, As and other trace elements shown to retard diagenesis were higher at the New World site than at the Paymaster site.     

Understanding the dynamics and contamination of an urban aquifer system using groundwater age (14C, 3H,CFCs) and chemistry

The quality of the groundwater supplying drinking water to the Guadalajara metropolitan area has deteriorated due to both endogenic and exogenic processes. Previous studies of this complex neotectonic volcanic environment suggest that the sources of contamination here are underground fluids derived from an active volcanic center and surface wastewater derived from regional land‐use intensification. This study uses isotopic, gaseous, and chemical signatures to more comprehensively characterize this groundwater flow and its contamination paths. Groundwater is mainly recharged at the La Primavera Caldera to the west and is discharged into the Santiago River to the east. The exception to this trend is the Toluquilla area, where groundwater most likely represents rainfall originating from outside the basin limits. Evaporation affects groundwater in these areas, especially waters that have been affected by recycling below urban areas in the Atejamac area and by intensive agricultural activity in the Toluquilla area. Additionally, we present evidence that groundwater flow through alluvial sediments and tuffs in deeper wells mixes with a lower aquifer unit in basaltic‐andesitic rocks, which are in contact with hydrothermal fluids. Groundwater ages range from postbomb in the western and northwestern regions of the study area (i.e., the Atemajac aquifer unit) to Late Pleistocene in the southern and southeastern regions (i.e., the Toluquilla aquifer unit). Recently recharged water records little mixing and is located mostly in or near the La Primavera volcanic system. As groundwater undergoes gravitational flow towards discharge areas, it mixes with older water components. Chloride and sodium concentrations above natural background levels are primarily related to volcanic activity, nitrate is associated with human activities, and sulfate originates from both anthropogenic sources and water–rock interactions. Nitrate originating from land‐use activities (such as sewers, septic tanks, landfills, and agricultural fields) that is introduced into the deeper part of the groundwater system is expected to travel with the groundwater to the discharge areas because oxidizing conditions will prevent microbial reduction. See Supplementary Information.     

Über einen Keuperton von Zaisersweiher bei Maulbronn

Zusammenfassung Durch röntgenographisehe und differentialthermoanalytische Untersuchungen wurde in einem roten Keuperton (km 3) von Zaisersweiher bei Maulbronn ein quellfähiges chloritisches Mineral (Corrensit) als Hauptbestandteil gefunden, das sick durch doppelten Basisabstand (28 Å) auszeichnet. Daneben treten Illit (Glimmer) und Quarz auf. Nebengemengteile sind Hämatit und Feldspat.Herrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet.     

The distribution of Hg, Ba, Cu and Zn in the vicinity of cupriferous sulfide deposits, Troodos complex, Cyprus

A geochemical rock- and soil-sampling program was carried out in the vicinity of eight concealed “Cyprus type” deposits, occurring in marginal mafic to intermediate metapillow lavas of the Troodos Ophiolite Complex. The mineralization of massive and stockwork sulfide ore is characterized by the predominance of pyrite, intergrown with less chalcopyrite and minor amounts of sphalerite.Background values of Hg are in the range of 8–12 ppb for soils and 3–6 ppb for surface rocks. Anomaly/background ratios of 10:1 (soils) and 5:1 (rocks) have been found only, where Hg migrated along channels formed by faults cutting shallow-seated mineralization. Here, Hg sometimes shows significant correlations with Cu, Zn, Ba and exceptionally with Co. However in one case an Hg anomaly in soils and surface rocks was detected directly over a deposit. The use of Hg as indicator element for these types of deposits is therefore limited. Buried mineralization may be delineated more distinctly by Cu, Zn and Ba.