Estimating environmentally relevant fixed nitrogen demand in the 21st century

Human activities affect the impact of the nitrogen cycle on both the environment and climate. The rate of anthropogenic nitrogen fixation from atmospheric N₂ may serve as an indicator to the magnitude of this impact, acknowledging that relationship to be effect-dependent and non-linear. Building on the set of Representative Concentration Pathway (RCP) scenarios developed for climate change research, we estimate anthropogenic industrial nitrogen fixation throughout the 21st century. Assigning characteristic key drivers to the four underlying scenarios we arrive at nitrogen fixation rates for agricultural use of 80 to 172 Tg N/yr by 2100, which is slightly less to almost twice as much compared with the fixation rate for the year 2000. We use the following key drivers of change, varying between scenarios: population growth, consumption of animal protein, agricultural efficiency improvement and additional biofuel production. Further anthropogenic nitrogen fixation for production of materials such as explosives or plastics and from combustion are projected to remain considerably smaller than that related to agriculture. While variation among the four scenarios is considerable, our interpretation of scenarios constrains the option space: several of the factors enhancing the anthropogenic impact on the nitrogen cycle may occur concurrently, but never all of them. A scenario that is specifically targeted towards limiting greenhouse gas emissions ends up as the potentially largest contributor to nitrogen fixation, as a result of large amounts of biofuels required and the fertilizer used to produce it. Other published data on nitrogen fixation towards 2100 indicate that our high estimates based on the RCP approach are rather conservative. Even the most optimistic scenario estimates that nitrogen fixation rate will remain substantially in excess of an estimate of sustainable boundaries by 2100.     

Copper partitioning between olivine and melt inclusions and its content in primitive island-arc magmas of Kamchatka

Melt inclusions and hosting them highly magnesian olivine from rocks of Kamchatka and the Western Aleutian island arc were analyzed for copper content by LA-ICP-MS to determine the copper partition coefficient in primitive island-arc magmas. Based on measurements of 45 olivine–melt pairs, this coefficient was determined to be 0.028 ± 0.009 (2σ), which is the lowest value among previously published data. Mass-balance calculations of copper in a typical mantle peridotite using obtained partition coefficient indicate that its content in peridotite and primary mantle magmas is mainly determined by mantle sulfide. The Cu partition coefficient was also used to calculate the copper content in parental magmas of volcanoes of the Central Kamchatka Depression. Estimates obtained using copper content in phenocrysts of primitive olivine (Fo > 88 mol %) from these rocks are, on average, 139 ± 58 ppm (2σ), which exceed copper contents in primitive basalts (MgO > 8.5 wt %) of mid-ocean ridges (MORB 93 ± 31 ppm). This suggests the primary enrichment of Central Kamchatka magmas in copper and correlates with their more oxidizing conditions of formation as compared to MORB.     

Geochemistry of radioactive elements in the rocks of the Guli Massif,Polar Siberia

The study of radioactive element distribution in the rocks of the Guli Complex revealed an increase of uranium and thorium contents in the final products of magmatic differentiation. In the carbonatite complex, the radioactive elements are mainly accumulated in the early rocks—phoscorites, while their contents in the late phases, dolomitic carbonatites, decrease. The Th/U ratio increases from near-chondritic values in the weakly differentiated highly-magnesian primary magmas to the late rocks—phoscorites, calcitic carbonatites, and dolomitic carbonatites. The majority of radioactive elements are hosted in rare-metal accessory minerals: perovskite, pyrochlore, calzirtite, and apatite. Rock-forming minerals are characterized by extremely low contents of radioactive elements.     

Global stability of the ballooning mode in a cylindrical model

Ballooning disturbances in a finite-pressure plasma in a curvilinear magnetic field are described by the system of coupled equations for the Alfvén and slow magnetosonic modes. In contrast to most previous works that locally analyzed the stability of small-scale disturbances using the dispersion relationship, a global analysis outside a WKB approximation but within a simple cylindrical geometry, when magnetic field lines are circles with constant curvature, is performed in the present work. This model is relatively simple; nevertheless, it has the singularities necessary for the formation of the ballooning mode: field curvature and non-uniform thermal plasma pressure. If the disturbance finite radial extent is taken into account, the instability threshold increases as compared to a WKB approximation. The simplified model used in this work made it possible to consider the pattern of unstable disturbances at arbitrary values of the azimuthal wavenumber (k _y ). Azimuthally large-scale disturbances can also be unstable, although the increment increases with decreasing azimuthal scale and reaches saturation when the scales are of the order of the pressure nonuniformity dimension.     

Late Quaternary ice age climates of tropical Australasia: Interpretations and reconstructions

Paleoecological and paleogeographical evidence is used to mold a framework from which the basic parameters of the late Quaternary glacial-age climate of tropical Australasia can be inferred. The theory of physical circulations, a knowledge of present tropical circulation patterns, and a study of anomalous and extreme events in the present era are used to reemphasize the view of a less pluvial tropical and subtropical zone at that time. Cooler sea-surface temperature, cooler trades, and the effect of the then exposed land areas are indicated as instrumental in producing drier conditions. Tropical areas west of Cape York Peninsula and Torres Strait were subject to fewer tropical disturbances and were similar to the present tropical savannah of the northern interior of Australia. Such effects would exist even without shifts in major climatic zones, although they are shown to be consistent with an equatorward shift of the westerlies brought about by the increased pole to equator temperature gradient. Paleoenvironmental evidence from the New Guinea Highlands and southeastern Australia suggests that their climates were anomalous. Substantial data of the glacial period in New Guinea show snow lines to be 1000 to 1500 m lower than at present which matches a 6 to 8°C lowering of temperature in highland New Guinea. The deep-sea cores of the CLIMAP Project suggest a mere 2°C cooling of the surrounding tropical oceans. It is shown that it is highly unlikely that an upper-level decrease in temperature of 6 to 8°C could be maintained while the surface cools by only 2°C. It is suggested that either the temperature of the tropical oceans of the western Pacific were overestimated by CLIMAP or that cold air incursions from higher latitudes (for which some analogs exist today) were sufficiently frequent to allow the maintenance of a snow line well below the freezing level of the ancient ambient tropical atmosphere. It is shown that in southeastern Australia considerable evidence of aridity cannot be explained by merely displacing the westerlies more equatorward. To account for the aridity, a new circulation pattern is proposed. Noting that there is CLIMAP evidence of preferred equatorward extension of sea ice, a pattern is postulated that displays only small seasonal change and is characterized by an enhanced Indian Ocean trough, marked ridging at eastern Australian longitudes, and a further trough in the western Tasman. Such a basic flow is consistent with (i) a low rainfall over southeastern Australia, (ii) frequent cold outbreak conditions favorable for the maintenance of the New Guinea glaciers, and (iii) considerable precipitation to nourish the ice caps of Tasmania and the Australian and New Zeland Alps.     

Effects of polynuclear aromatic hydrocarbons on lysosomal membranes in molluscs

Lysosomal sequestration of polynuclear aromatic hydrocarbons (PNAHs), a major class of environmental contaminant, is a well-established phenomenon;¹ considerably less is known about their pathological effects on lysosomes. Marine molluscs contain a number of lysosome-rich tissues and PNAHs are known to induce deleterious alterations in lysosomal structure and latency of lysosomal enzymes.² The latter are presumed to involve destabilisation of the lysosomal membrane, resulting in increased permeability and reduced enzyme latency. If lysosomal injury involves derangement of membrane-lipid structure due to the interaction of PNAHs then it would be expected that membrane damage would be closely linked to the structural characteristics of the intruding molecule. Our results show that the effects of the isomeric PNAHs phenanthrene and anthracene on digestive cell lysosomal stability were markedly different in the marine mussel (Mytilus edulis) over the same range of tissue concentrations. Lysosomal membrane stability was determined using a cytochemical test for enzyme latency.³     

The quality of life in Ukraine and in Russia as a factor of socio-economic development

The characteristic features of the socio-geographical approach in analyzing the “quality of life of population” category are highlighted. Experience in assessing the balanced development of Ukraine and Russia is presented; the most important factors that are responsible for the quality of life in these countries are determined.     

Contaminant concentrations and toxicity of sea-surface microlayer near Los Angeles, California

Sea-surface microlayer samples were collected from six nearshore areas receiving different amounts of anthropogenic inputs. The samples were analyzed for selected trace metals, chlorinated hydrocarbons, and polycyclic aromatic hydrocarbons. The relative toxicities of the samples were determined with fish embryo bioassays.Contaminant concentrations generally increased from offshore to the inshore stations. Contaminant concentrations were several orders of magnitude higher in microlayer samples from the highly industrialized Los Angeles and Long Beach harbors compared to samples from a site 15km offshore. Microlayer samples from the inshore stations were significantly more toxic, and induced significantly more developmental abnormalities and chromosome aberrations, than samples from the offshore stations.     

Meadow landscapes of Southern Kurils: Origin,age and development

Data of spore-pollen analysis and radiocarbon dating on soil profiles have been used in reconstructing the development stages of meadow landscapes of Southern Kurils (Kunashir and Iturup Islands, and the Lesser Kuril Chain). The emergence of meadows is due both to anthropogenic impacts and to a cooling in the Late Holocene (the last 1.5–2 thousand years ago). In the southern part of the Lesser Kuril Chain, meadows landscapes have been of widespread occurrence during the last 4–6 thousand years. The fallout of volcanic ashes differing in chemical composition and, in some cases, the entry of aeolian sand altered the soil properties and had a dramatic effect on plant associations.