Typochemistry of rinkite and products of its alteration in the Khibiny Alkaline pluton,Kola Peninsula

The occurrence, morphology, and composition of rinkite are considered against the background of zoning in the Khibiny pluton. Accessory rinkite is mostly characteristic of foyaite in the outer part of pluton, occurs somewhat less frequently in foyaite and rischorrite in the central part of pluton, even more sparsely in foidolites and apatite–nepheline rocks, and sporadically in fenitized xenoliths of the Lovozero Formation. The largest, up to economic, accumulations of rinkite are related to the pegmatite and hydrothermal veins, which occur in nepheline syenite on both sides of the Main foidolite ring. The composition of rinkite varies throughout the pluton. The Ca, Na, and F contents in accessory rinkite and amorphous products of its alteration progressively increase from foyaite and fenitized basalt of the Lovozero Formation to foidolite, rischorrite, apatite–nepheline rocks, and pegmatite–hydrothermal veins.     

The geochemistry of uranium occurrences and speciation in groundwater of Chinnar sub basin,South India

An attempt has been made in Chinnar sub basin of Dharmapuri district, South India to isolate the geochemistry of uranium occurrences in groundwater. The geology of the area is mainly of charnockite and granite gneiss. Groundwater samples were collected for two different seasons post and pre monsoon in two different litho units (granite gneiss and charnockite) and analysed for major, minor and uranium concentrations. Higher uranium (18.45 μg L^?1) has been recorded during pre monsoon season in granite gneiss with increasing pH. The saturation index calculation for the groundwater isolated minerals like uaraninite, coffinite, haiweeite and soddyite to be precipitating and uranium oxides like UO_2.25, UO_2.25beta, UO_2.33beta as oversaturated. The Eh-pH diagram attempted represents solubility of uraninite within the pH range of 6.0 to 8.0. The study isolate uranium in groundwater of the study area is controlled by the presence of (U₄O₉) uranium oxide.     

Factors controlling the adsorption of acid blue 113 dye from aqueous solution by dried <Emphasis Type="Italic">C. edulis</Emphasis> plant as natural adsorbent

Contamination of surface water and groundwater by organic pollutants is a serious problem due to their persistence, bioaccumulation and biomagnification through food webs. Since the removal of dyes from wastewater is considered an environmental challenge and government legislation requires textile wastewater to be treated, therefore there is a constant need to have an effective process that can efficiently remove these dyes. The aim of the present study is to evaluate the potentiality of dried Carpobrotus edulis plant as low-cost adsorbent for the removal of the industrial acid blue 113 dye from aqueous solutions using the batch equilibration technique. The effects of different physicochemical parameters such as adsorbent dose, contact time, initial dye concentration, solution pH and temperature on adsorption rate of anionic AB113 dye on microparticles of dried C. edulis plant were investigated. The experimental data were analyzed by using mathematical models to determine the thermodynamic parameters. The negative values of free energy change indicated the spontaneous nature of the adsorption and negative value of enthalpy change suggested the exothermic nature of the adsorption process. These results indicate that dried C. edulis plant as an environmentally friendly adsorbent could be potentially used for the removal of anionic dyes from aqueous solutions.     

Self-sedimentation of phytoplankton blooms in the geologic record

Understanding the formation of laminated, organic-rich sediments is an essential topic for researchers interested in fossil fuels, biogeochemical cycles, Earth's environmental history and global change. Biologists have very recently demonstrated that some marine phytoplankton blooms actively govern their own sedimentation by the formation of sticky transparent gels that facilitate rapid aggregation, accelerated sinking and efficient export flux. Here we present fossil evidence of unfragmented, low-diversity phytoplankton assemblages preserved as sedimentary laminae and irregular flocs that are attributable to a similar phytoplankton-driven sedimentary mechanism we term ‘self-sedimentation’. The geological evidence suggests that self-sedimentation precludes significant heterotrophic grazing, propels the formation of some conspicuous hemipelagic sedimentary laminae and results in efficient carbon and opal flux to the sediments. We suggest that the self-sedimentation phenomenon may have broad implications for the geological history of biogeochemical cycling, oceanic ecological dynamics, and abrupt atmospheric/environmental change. Broader recognition of the self-sedimentation phenomenon as explicitly defined here is a prerequisite to testing these unconventional hypotheses.     

New data on the present-day active fluid regime of fractured zones of crystalline basement and sedimentary cover in the eastern part of Volga-Ural region

The study area is the South Tatarstan Arch located in the Volgo-Ural Region, which is an enigmatic crustal segment occupying one third of the East European Platform. Monitoring studies have shown that fluid discharge processes are still active and time-dependent. This paper presents an integrated review of the geological, geophysical, hydrochemical and geochemical studies of the crystalline basement of Tatarstan. These studies are based on the stratigraphic and compositional schemes within the crystalline basement, the drilling of deep wells, the geodynamic activity of the fractured zones of the crystalline basement and the presence of fluids therein. Furthermore, the changes in the chemical composition of the basement waters are taken into account.     

Atmospheric Artifact Compensation in Ground-Based DInSAR Applications

In this letter, a coherence-based technique for atmospheric artifact removal in ground-based (GB) zero-baseline synthetic aperture radar (SAR) acquisitions is proposed. For this purpose, polarimetric measurements acquired using the GB-SAR sensor developed at the Universitat Politecnica de Catalunya are employed. The heterogeneous environment of Collserola Park in the outskirts of Barcelona, Spain, was selected as the test area. Data sets were acquired at X-band during one week in June 2005. The effects of the atmosphere variations between successive zero-baseline SAR polarimetric acquisitions are treated here in detail. The need to compensate for the resulting phase-difference errors when retrieving interferometric information is put forward. A compensation technique is then proposed and evaluated using the control points placed inside the observed scene.     

Profligacy and scarcity: an analysis of water management in Australia

Without denying the physical relaity of water shortages during the 1982 Australia drought, it is argued that some of the difficulties arise not from climatic factors but from the way the water resource is managed. An attempt is made to explain why metropolitan Australia can continue to make profligate use of water, while rural Australia suffers scarcity. The system of administration is considered and the capacity planning and pricing policies of supply authorities analysed. Finally, a call is made for the introduction of an effective integrated management system.     

A Spatially-Analytical Scheme for Surface Temperatures and Conductive Heat Fluxes in Urban Canopy Models

In the urban environment, surface temperatures and conductive heat fluxes through solid media (roofs, walls, roads and vegetated surfaces) are of paramount importance for the comfort of residents (indoors) and for microclimatic conditions (outdoors). Fully discrete numerical methods are currently used to model heat transfer in these solid media in parametrisations of built surfaces commonly used in weather prediction models. These discrete methods usually use finite difference schemes in both space and time. We propose a spatially-analytical scheme where the temperature field and conductive heat fluxes are solved analytically in space. Spurious numerical oscillations due to temperature discontinuities at the sublayer interfaces can be avoided since the method does not involve spatial discretisation. The proposed method is compared to the fully discrete method for a test case of one-dimensional heat conduction with sinusoidal forcing. Subsequently, the analytical scheme is incorporated into the offline version of the current urban canopy model (UCM) used in the Weather Research and Forecasting model and the new UCM is validated against field measurements using a wireless sensor network and other supporting measurements over a suburban area under real-world conditions. Results of the comparison clearly show the advantage of the proposed scheme over the fully discrete model, particularly for more complicated cases.     

Variability peculiarities of distribution of transparency and suspended matter content in the northwestern part of the Black Sea in spring caused by large-scale processes in the ocean–atmosphere system

The display is considered of global processes in the ocean-atmosphere system in the variability of hydrophysical and hydrobiological fields of the northwestern part of the Black Sea in spring period of 1978–1995. It is demonstrated that the variability of North Atlantic and Southern oscillations in winter-spring period affects the spring hydrometeorological conditions in catchment areas of European rivers of the Black Sea basin causing the variability of runoff volumes of these rivers and the scales of spreading river waters at the northwestern shelf. Hydrological and hydrobiological characteristics of shelf waters varying in the process influence the formation of distribution of suspended matter content and transparency.     

African Refugee Communities in Southeast Queensland: forces of concentration and dispersion

Black African refugee communities are a relatively recent addition to the Australia landscape. Between 2001 and 2007, over 5000 refugees from various African nations resettled in Queensland. There are very few data about African refugee settlement geography in Australia and no previous study delineating African refugee settlement within the State of Queensland. This research addresses the knowledge gap by examining the geographic distribution and secondary migration patterns of eight African refugee communities in Southeast Queensland. The research adopted a multi-method approach, mapping quantitative data from an existing secondary database and comparing these to qualitative primary data to determine geographical distribution. Additional qualitative data were used to establish secondary migration patterns of the case study communities. Results show noticeable discrepancies between existing secondary datasets and primary data collected from the communities. These inconsistencies are significant because settlement service providers who use the secondary data to budget, plan and deliver essential settlement services might be underestimating the size of the African communities and missing some settlement locations altogether. The results also reveal a tension between the main socio-cultural forces of concentration and housing forces of dispersion that are driving secondary migration in the communities. A policy recommendation to mitigate the potentially negative effects of residential dispersion on settlement outcomes includes the strategic location of service hubs in key suburbs, such as Moorooka, to which the communities are already drawn.