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71.
Three points raised in the paper by Tedesco and Sabroux (1987) are dealt with. (1) The inconsistency between the water partial pressure calculated by Tedesco and Sabroux (1987) and saturation pressure is due to the improper use of the water-gas-shift reaction as a geothermometer. In fact Tedesco and Sabroux (1987) do not take into account the distribution of gas species between the coexisting vapour and liquid phases. (2) The depth of the “steam reservoir” is evaluated by Tedesco and Sabroux (1987) in too simplistic a way. This matter should be treated with greater care owing to the high social impact of any consideration on the Phlegraean Fields system. (3) The reliability of carbon monoxide determination at the concentration level encountered at Solfatara depends on the collection method rather than on the gas-chromatographic technique. 相似文献
72.
A Double Solid Reactant Method was elaborated from a suggestion of Marini (Geological sequestration of carbon dioxide: Thermodynamics,
kinetics, and reaction path modeling. Developments in Geochemistry, Elsevier, Amsterdam, 2007) to simulate the release of
trace elements during the progressive dissolution of solid phases. The method is based on the definition, for each dissolving
solid, of both an entity whose thermodynamic and kinetic properties are known (either a pure mineral or a solid mixture) and
a special reactant, that is, a material of known stoichiometry and unknown thermodynamic and kinetic properties. The special
reactant is utilised to take into account the concentrations of trace elements in the dissolving solid phase. In this communication,
the influence of several trace elements on the ΔG
f
o, ΔG
r
o and log K of the minerals considered by Lelli et al. (Environ Geol, 2007) and Accornero and Marini (Geobasi, 2007a; Proceedings of
IMWA symposium, Cagliari, 27–31 May 2007b) was evaluated assuming ideal mixing in the solid state. These effects were found
to be negligible for albite and the leucite–latitic glass, limited for muscovites and chlorites, and slightly more important
for apatites. These influences become progressively higher with increasing concentration of trace elements in these minerals.
Based on these deviations in thermodynamic parameters, special reactants should not include oxide components with molar fractions
higher than 0.003.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
相似文献
Luigi MariniEmail: |
73.
74.
75.
76.
Prof. Luigi Castoldi 《Pure and Applied Geophysics》1953,25(1):6-12
Riassunto Si prospetta una teoria della comprimibilità di un solido isotropo soggetto a pressione idrostatica, implicante il comportamento plastico ad elevate pressioni. Si ottiene in tal modo un accordo coi risultati sperimentali sensibilmente superiore a quello fin qui conseguito ritenendo il fenomeno di natura puramente elastica ed applicado ad esso la cosìddetta «approssimazione del second'ordine».
Summary A theory of the comprimibility for isotropic solids, whith regard to their plastic properties, is proposed. Check whith experimental data furnishes more satisfactory results than current theory of second approximation.相似文献
77.
Luigi Cavaleri 《Ocean Engineering》1980,7(3):447-455
A system is described which has the capability of maintaining two large structures apart, floating or submerged, but allowing their relative movements due to current, waves and wind.Such a system has been designed and built. The tests carried out show that the developed theory is correct within the specified limits of validity. A practical test in the sea has shown the efficiency of the system and suggested some possible improvements.Its main characteristics are simplicity, reliability and low cost. 相似文献
78.
We present the first fission‐track results from the Grenvillian Oaxacan Complex, southern Mexico. Time–temperature modelling of the data indicates that two significant Mesozoic cooling episodes are recorded in the Oaxacan Complex and these are interpreted as resulting from exhumation. The older cooling event took place from the Late Triassic to Middle Jurassic and is possible linked to the break‐up of Pangea (including the initial opening of the Gulf of Mexico during the Jurassic). The younger exhumation period in the Early Cretaceous is contemporaneous with the final stages of rifting of the Gulf of Mexico. Key stratigraphic records also provide independent evidence for these exhumation episodes. In our view, both Mesozoic rapid exhumation events were controlled by the activity of the Caltepec Fault Zone and the Oaxaca Fault. Our data suggest that both these large fault systems have remained active since, at least, the Late Triassic. 相似文献
79.
80.
Marta Burgay Nanda Rea GianLuca Israel Andrea Possenti Luciano Burderi Tiziana Di Salvo Nichi D’Amico Luigi Stella Elisa Nichelli 《Astrophysics and Space Science》2007,308(1-4):531-534
We have performed deep searches for radio pulsations from four southern anomalous X-ray pulsars (AXPs) to investigate their
physical nature in comparison with the rotation powered pulsars. The data were acquired using the Parkes radio telescope with
the 1.4 GHz multibeam receiver. No pulsed emission with periodicity matching the X-ray ephemeris have been found in the observed
targets down to a limit of ∼0.1 mJy. A blind search has also been performed on all the 13 beams of the multibeam receiver
(the central beam being pointed on the target AXP), leading to the serendipitous discovery of two new radio pulsars and to
the further detection of 18 pulsars. Also a search for single dispersed pulses has been performed in the aim to detect signals
similar to those of the recently discovered rotating radio transients.
相似文献