Shallow and deep aquifer hydrochemistry and chemical variability of water quality at Shariatpur district, Bangladesh

Water quality and hydrochemistry of Shariatpur district were evaluated in terms of hydrochemical composition and some important physico-chemical parameters. The groundwater of the study area is good for drinking, domestic as well as for irrigation purposes. Among the major ions, shallow tube well waters give higher concentration of Ca²⁺ which ranges from 24 to 260 mg/L. The deep tubewell waters show higher concentration of Na⁺ which varies from 74 to 582 mg/L during dry season. Among the trace elements most of the shallow aquifer samples show higher concentration of Fe²⁺, Mn²⁺ and As. Concentration of Fe²⁺ varies from 0.655 to 18.8 mg/L, and Mn²⁺ from trace to 0.868 mg/L during dry period. Hydrochemical analyses reveal significant seasonal variation in water quality of shallow aquifer. Both the shallow aquifer and the surface water of the study area are predominantly of Ca–Mg–HCO₃ type, while the deep aquifer water is mainly of Na–K–Cl–SO₄ type with slight inclination to Ca–Mg–HCO₃ type. The study area is suitable for groundwater development if comprehensive and holistic approaches towards water resource management are taken into consideration.     

A Parametric Study on Stability of Open Excavations in Alluvial Soils of Lahore District, Pakistan

Rapid urbanization and expansion of metropolitans in the developing world is pressing the need of tall structures with multiple basements. In several such projects, open land is available around excavation site and unsupported deep excavations by maintaining appropriate side slopes offer economical solution. In this research, subsoil stratigraphy of Lahore district was established to be comprising of a top clay stratum 1.5–8 m thick, followed by a sand layer. Considering subsoil data from several geotechnical investigation reports, the effect of four key parameters viz., cohesion of clay layer, friction angle of sand layer, thickness of clay layer at the top and slope inclination of underlying sand layer on safety factor of open excavations was studied. Six hundred twenty-five slope stability analyses were conducted by considering different geometries and soil properties. Based on the results of these analyses, a regression model was suggested to estimate safety factor of open excavations in similar stratigraphy which would be useful in feasibility studies and preliminary design of deep excavations. It was established that the clay layer cohesion was the most dominant contributor to safety factor.     

Thermodynamics of accelerating and rotating black holes

Thermodynamics of a large family of black holes from electrovacuum solutions of Einstein’s equations is studied. This family includes rotating and non-accelerating black holes with NUT charge, and rotating and accelerating black holes. The surface gravity, Hawking temperature and the area laws for these black holes are presented. The first law of thermodynamics is also given. An interesting outcome of our analysis is the restriction obtained on the magnitude of acceleration for these black holes.     

An integrated multi-azimuth VSP study for fracture characterization in the vicinity of a well

We present the analysis of a multi-azimuth vertical seismic profiling data set that has been acquired in a tight gas field with the objective of characterizing fracture distributions using seismic anisotropy. We investigate different measurements of anisotropy, which are shear-wave splitting, P-wave traveltime anisotropy and azimuthal amplitude variation with offset. We find that for our field case shear-wave splitting is the most robust measure of azimuthal anisotropy, which is clearly observed over two distinct intervals in the target. We compare the results of the vertical seismic profiling analysis with other borehole data from the same well. Cross-dipole sonic and Formation MicroImager data from the reservoir section suggest that no open fractures intersect the well or are present within half a metre of the borehole wall. Furthermore, a detailed dispersion analysis of the sonic scanner data provides no indication of stress-induced seismic anisotropy along the logged borehole section. We therefore explain the azimuthal anisotropy measured in the vertical seismic profiling data with a model that contains discrete fracture corridors, which do not intersect the well itself but lie within the vertical seismic profiling investigation radius. We show that such a model can reproduce some basic characteristics of azimuthal anisotropy observed in the vertical seismic profiling data. The model is also consistent with well test data that suggest the presence of a fracture corridor away from the well. With this study we demonstrate the necessity of integrating different data types that investigate different scales of rock volume and can provide complementary information for understanding the characteristics of fracture networks in the subsurface.     

Environmental impact assessment on water quality deterioration caused by the decreased Ganges outflow and saline water intrusion in south-western Bangladesh

 This paper deals with an environmental impact assessment of low water flow in the river Ganges during a dry period at the Khulna and Mongla port areas in south-western Bangladesh. Large-scale surface water withdrawal in India after commissioning the Farakka Barrage causes a drastic fall in the Ganges low-flow condition within the Bangladesh territory during every dry period. The average lowest discharge in the Ganges is 552 m³/s, which is about 73% less than that in the pre-Farakka time. This has caused the deterioration of both surface and groundwater quality of the study area. Salinity is the principal cause of water quality degradation in the area. Present observation shows that the surface water of the area is sulphate-chloride dominated, which signifies high salinity whereas the groundwater is categorized as of medium to high salinity. To maintain the Rupsa River's maximum salinity below 1000 μS/cm the discharge in the Ganges should be ∼1500 m³/s, whereas that at Garai basin is ∼10 m³/s. If this present situation continues it will be a crippling blow to the environment of the area in the long term. An integrated multidisciplinary approach to hydrogeological research is urgently required to salvage the area from further deterioration. Received: 9 August 1999 · Accepted: 8 March 2000     

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.     

A long-term trend in precipitation of different spatial regions of Bangladesh and its teleconnections with El Niño/Southern Oscillation and Indian Ocean Dipole

A long-term (1948 to 2012) trend of precipitation (annual, pre-monsoon, monsoon, and post-monsoon seasons) in Bangladesh was analyzed in different regions using both parametric and nonparametric approaches. Moreover, the possible teleconnections of precipitation (annual and monsoon) variability with El Niño/Southern Oscillation (ENSO) episode and Indian Ocean Dipole (IOD) were investigated using both average and individual (both positive and negative) values of ENSO index and IOD. Our findings suggested that for annual precipitation, a significant increasing monotonic trend was found in whole Bangladesh (4.87 mm/year), its western region (5.82 mm/year) including Rangpur (9.41 mm/year) and Khulna (4.95 mm/year), and Sylhet (10.12 mm/year) and Barisal (6.94 mm/year) from eastern region. In pre-monsoon, only Rangpur (2.88 mm/year) showed significant increasing trend, while in monsoon, whole Bangladesh (3.04 mm/year), Sylhet (7.17 mm/year), and Barisal (6.94 mm/year) showed similar trend. In post-monsoon, there was no significant trend. Our results also revealed that the precipitation (annual or monsoon) of whole Bangladesh and almost all of the spatial regions did not show any significant correlation with ENSO events, whereas the average IOD values showed significant correlation only in monsoon precipitation of western region. The individual positive IODs showed significant correlation in whole Bangladesh, western region, and its two divisions (Rajshahi and Khulna). So, in the context of Bangladesh climate, IOD has the more teleconnection to precipitation than that of ENSO. Our findings indicate that the co-occurrence of ENSO and IOD events may suppress their influence on each other.

     

Characterization of carbon monoxide,methane and nonmethane hydrocarbons in emerging cities of Saudi Arabia and Pakistan and in Singapore

We investigate the composition of 63 C₂-C₁₀ nonmethane hydrocarbons (NMHCs), methane (CH₄) and carbon monoxide (CO), in Jeddah, Mecca, and Madina (Saudi Arabia), in Lahore, (Pakistan), and in Singapore. We established a database with which to compare and contrast NMHCs in regions where ambient levels and emissions are poorly characterized, but where conditions are favorable to the formation of tropospheric ozone, and where measurements are essential for improving emission inventories and modeling. This dataset will also serve as a base for further analysis of air pollution in Western Saudi Arabia including, but not limited to, the estimation of urban emissions and long range pollution transport from these regions. The measured species showed enhanced levels in all Saudi Arabian cities compared to the local background but were generally much lower than in Lahore. In Madina, vehicle exhaust was the dominant NMHC source, as indicated by enhanced levels of combustion products and by the good correlation between NMHCs and CO, while in Jeddah and Mecca a combination of sources needs to be considered. Very high NMHC levels were measured in Lahore, and elevated levels of CH₄ in Lahore were attributed to natural gas. When we compared our results with 2010 emissions from the MACCity global inventory, we found discrepancies in the relative contribution of NMHCs between the measurements and the inventory. In all cities, alkenes (especially ethene and propene) dominated the hydroxyl radical (OH) reactivity (k _OH) because of their great abundance and their relatively fast reaction rates with OH.