Kaolin deposits at Melthonnakkal and Pallipuram within Trivandrum block, southern India

The kaolin deposits at Melthonnakkal and Pallipuram mines form part of the Warkalli Formation belonging to the Tertiary sequence in southern Kerala and occur at the boundary between the Tertiary sequence and Precambrian granulite facies metapelites (khondalites). The sedimentary clays are composed mainly of kaolinite, quartz and gibbsite. XRD and SEM studies have revealed that kaolinite is well-crystallized variety and the platy crystals are scarcely broken in the sedimentary clays. These sedimentary kaolins are considered to have been formed by intense tropical weathering of the khondalites, and subsequently transported and deposited with high organic input into lakes near the weathering crust over the basement rock. Besides, the surficial parts of the sedimentary deposits are extensively lateritized with the formation of goethite and hematite by Quaternary tropical weathering processes.     

High-resolution shallow seismic and ground penetrating radar investigations revealing the evolution of the Uemachi Fault system, Osaka, Japan

Abstract Ground penetrating radar (GPR) and high‐resolution shallow reflection seismic surveying were carried out to investigate the subsurface geology in and around the Uemachi Fault zone in the Yamato River area, Osaka, Japan. Shallow drilling in the area showed a major displacement event during the middle Pleistocene. The main Uemachi Fault plane could be clearly imaged on the seismic section, except for the most shallow 200 m. Several shallow normal fault planes with less displacement could be detected on both sides of the fault plane. GPR profiles confirmed the presence of several shallow normal faults within the area near the fault zone. These shallow faults could be followed in all of the GPR profiles crossing the fault zone. The integration of seismic section, GPR profiles and drilling data led to a conceptual model that explains the evolution of the Uemachi Fault system. The proposed model suggests the occurrence of several cycles of small vertical displacement along the deep part of the fault plane caused by the regional east–west compressional stress. The ductile nature of the shallow sedimentary cover and the absence of confining pressure in the shallow part allow for a considerable amount of plastic bending before failing in the shallow sedimentary layers. This bending generates stretching force within the shallow sedimentary cover, which in time, along with gravitational force, gives rise to the formation of the swarm of normal faults within the shallow layers near the fault zone. Some of the detected faults extend to a depth of less than 3 m below the ground surface, suggesting that the last tectonic activity along the fault plane may have occurred recently.     

The hydrogeology of granitic rocks in deep boreholes used for compressed air storage

The compressed air energy storage(CAES) is a much-awaited new system for load leveling power supply. An economical system must be developed, preventing leakage of stored air (with pressures of more than 20 atm) using groundwater pressure surrounding an unlined cavern in hard rock. The air tightness of the rock around the cavern must be confirmed. In this study, the hydrogeology of the test site was examined prior to field air tightness tests in the borehole. The results indicate that, when evaluating the hydrogeology of the test site related to the air tightness of rocks, it is necessary to understand the geological structure and fracture characteristics of the site. This is done by means of a field survey, investigations and tests in and between the boreholes, and the examination of the distribution of permeability and pore water pressures.     

Trace-element characteristics of east–west mantle geochemical hemispheres

Recent statistical analyses on the isotopic compositions of oceanic, arc, and continental basalts have revealed that the Earth's mantle is broadly divided into eastern and western hemispheres. The present study aimed to characterize the isotopically defined east–west geochemical hemispheres using trace-element concentrations. Basalt data with Rb, Sr, Nd, Sm, Pb, Th, and U in addition to the isotopic ratios ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb were selected mostly from the GEOROC and PetDB databases. A total of 4787 samples were used to investigate the global geochemical variations. The results show that the wide trace-element variations are broadly explained by the melting of melt-metasomatized and fluid-metasomatized mantle sources. The larger amount of the fluid component derived from subducted plates in the eastern hemisphere than that in the western hemisphere is inferred from the basalts. These characteristics support the hypothesis that focused subduction towards the supercontinent created the mantle geochemical hemispheres.     

RXTE observation of NGC 6240: a search for the obscured active nucleus

We present new data taken at 850 μm with SCUBA at the James Clerk Maxwell Telescope for a sample of 19 luminous infrared galaxies. Fourteen galaxies were detected. We have used these data, together with fluxes at 25, 60 and 100 μm from IRAS , to model the dust emission. We find that the emission from most galaxies can be described by an optically thin, single temperature dust model with an exponent of the dust extinction coefficient ( k _λ ∝ λ ^{− β} ) of β ≃1.4–2. A lower β ≃1 is required to model the dust emission from two of the galaxies, Arp 220 and NGC 4418. We discuss various possibilities for this difference and conclude that the most likely is a high dust opacity. In addition, we compare the molecular gas mass derived from the dust emission, M _850 μm, with the molecular gas mass derived from the CO emission, M _CO, and find that M _CO is on average a factor 2–3 higher than M _850 μm.     

Enrichment of adsorbed methane in authigenic carbonate concretions of the Japan Trench

Substantial amounts of adsorbed methane were detected in authigenic carbonate concretions recovered from sedimentary layers from depths between 245 and 1,108 m below seafloor during Ocean Drilling Program Leg 186 to ODP sites 1150 and 1151 on the deep-sea terrace of the Japan Trench. Methane contents were almost two orders of magnitude higher in the concretions (291–4,528 nmol/g wet wt) than in the surrounding bulk sediments (5–93 nmol/g wet wt), whereas methane/ethane ratios and stable carbon isotopic compositions were very similar. Carbonate content of surrounding bulk sediments (0.02–3.2 wet wt%) and methane content of the surrounding bulk sediments correlated positively. Extrapolation of the carbonate contents of bulk sediments suggests that 100 wt% carbonate would correspond to 1,886±732 nmol methane per g bulk sediment, which is similar to the average value observed in the carbonate concretions (1,321±1,067 nmol/g wet wt, n = 13). These data support the hypothesis that, in sediments, adsorbed hydrocarbon gases are strongly associated with authigenic carbonates.     

Dissolved and labile particulate Zr,Hf, Nb,Ta, Mo and W in the western North Pacific Ocean

Dissolved and labile particulate Zr, Hf, Nb, Ta, Mo and W were determined at stations K1 (51°N, 165°E), K2 (47°N, 160°E), KNOT (44°N, 155°E) and 35N (35°N, 160°E) in the western North Pacific Ocean. A portion of seawater for dissolved species (D) was passed through a 0.2 μm Nuclepore filter and acidified to pH 2.2 with HCl and HF. A portion of seawater for acid-dissolvable species (AD) was acidified without filtration. Labile particulate (LP) species is defined as AD minus D, which represents a chemically labile fraction of particulate species. D-Zr, Hf and Ta increase with depth, Nb shows a slight depletion in surface water, whereas Mo and W have a conservative vertical profile. The concentration range of D-Zr, Hf, Nb, Ta and W is 31–275, 0.14–0.95, 4.0–7.2, 0.08–0.29 and 40–51 pmol kg⁻¹, respectively, whereas that of Mo is 97–105 nmol kg⁻¹. LP-species of Zr, Hf and Ta account for 10–14% of AD in average and increase up to 25% below 4000 m, whereas those for Mo and W are negligible. In contrast, LP-Nb shows maxima (up to 27%) in surface water. We also found that D-Zr/Hf, Nb/Ta and Mo/W mole ratios generally increase in the order continental crust < river water < coastal sea < open ocean.