The impact of subsurface geological structure on the groundwater occurrence using geophysical techniques in wadi El Kallabiyyah and wadi As Sabil,East Esna,Eastern Desert,Egypt

The present study aims to explain some hydrogeological problems that are related to geological setting in two wadis: El Kallabiyyah and As Sabil East Esna. For this purpose, land magnetic, vertical electrical soundings, and two-dimensional electrical resistivity imaging profiles were measured. The lithological succession comprises Upper Cretaceous to Quaternary deposits that rest on a Precambrian basement rock. The results of the interpretation of the land magnetic measurements in wadi El Kallabiyyah represent the depth to the basement rock which ranges from 260 to 660 m and increases towards the northeast trend, but in wadi As Sabil, there is a large basin at the center of the wadi with the recorded depth to the basement reaching 1,300 m due to the effect of two normal faults (F1 and F2). The results of the interpretation of the vertical electrical sounding and two-dimensional imaging confirmed the presence of these faults in wadi As Sabil. The results of the geoelectrical measurements in wadi El Kallabiyyah represented the water-bearing layer at the third unit that consists of sands, gravels, boulders, and clays. The presence of clay will affect the potentiality of a drilled well. For wadi As Sabil, the results of geoelectrical measurements led to the lower part of the second unit which acts as a water-bearing layer that consists of sands, boulders, gravels, and clays. It can be concluded that the best site for drilling wells in wadi El Kallabiyyah is at vertical electrical sounding no.5 with a total depth of not less than 230 m. In wadi As Sabil, the drilled wells must be concentrated at the center and the downstream.     

Uranium-rich opal from the Nopal I uranium deposit, Peña Blanca, Mexico: Evidence for the uptake and retardation of radionuclides

The Nopal I uranium deposit of the Sierra Peña Blanca, Mexico, has been the focus of numerous studies because of its economic importance and its use as a natural analog for nuclear-waste disposal in volcanic tuff. Secondary uranyl minerals such as uranophane, Ca[(UO₂)(SiO₃OH)]₂(H₂O)₅, and weeksite, (K,Na)₂[(UO₂)₂(Si₅O₁₃)](H₂O)₃, occur in the vadose zone of the deposit and are overgrown by silica glaze. These glazes consist mainly of opal A, which contains small particles of uraninite, UO₂, and weeksite. Close to a fault between brecciated volcanic rocks and welded tuff, a greenish silica glaze coats the altered breccia. Yellow silica glazes from the center of the breccia pipe and from the high-grade pile coat uranyl-silicates, predominantly uranophane and weeksite. All silica glazes are strongly zoned with respect to U and Ca, and the distribution of these elements indicates curved features and spherical particles inside the coatings. The concentrations of U and Ca correlate in the different zones and both elements inversely correlate with the concentration of Si. Zones within the silica glazes contain U and Ca in a 1:1 ratio with maximum concentrations of 0.08 and 0.15 at.% for the greenish and yellow glazes, respectively, suggesting trapping of either Ca₁U₁-aqueous species or -particles in the colloidal silica. X-ray photoelectron spectroscopy (XPS), Fourier-transform infra-red spectroscopy (FTIR), and oxygen-isotope ratios measured by secondary-ion mass spectrometry (SIMS) indicate higher U⁶⁺/U⁴⁺ ratios, higher proportions of Si-OH groups and lower δ¹⁸O values for the greenish silica glaze than for the yellow silica glaze. These differences in composition reflect increasing brecciation, porosity, and permeability from the center of the breccia pipe (yellow silica glaze) toward the fault (green silica glaze), where the seepage of meteoric water and Eh are higher.     

An assessment of Canadian prairie drought: past, present, and future

Within Canada, the Canadian Prairies are particularly drought-prone mainly due to their location in the lee of the western cordillera and distance from large moisture sources. Although previous studies examined the occurrence of Canadian Prairie droughts during instrumental, pre-instrumental and to a lesser extent, future periods, none have specifically focused on all time three scales. Using two different drought indicators, namely the Palmer Drought Severity Index (PDSI) and Standardized Precipitation Index (SPI), this investigation assesses the variability of summer drought duration and intensity over a core region of the Prairies during (a) the pre-instrumental record extending back several centuries (inferred from tree rings), (b) the instrumental record (1901–2005), and (c) the twenty-first century using statistically downscaled climate variables from several Atmosphere–Ocean Global climate models with multiple emission scenarios. Results reveal that observed twentieth century droughts were relatively mild when compared to pre-settlement on the Prairies, but these periods are likely to return (and even worsen) in the future due to the anticipated warming during the course of the twenty-first century. However, future drought projections are distinctly different between the two indices. All PDSI-related model runs show greater drought frequency and severity mainly due to increasing temperatures. Conversely, the precipitation-based SPI indicates no significant changes to future summer drought frequency although there tends to be a higher persistence of multi-year droughts in central and southern portions of Canadian Prairies. These findings therefore stress the importance of considering anticipated warming trends when assessing future regional-scale drought, especially given the uncertainties and lack of consistency in future precipitation signals among climate models. This study can be considered an initial step toward quantifying and understanding Canadian Prairie drought occurrence and severity over several centuries as determined from paleo, instrumental, and climate model data sources.     

Spatial distribution and temporal trends of persistent organochlorine pollutants in sediments from Lake Maryut, Alexandria, Egypt

Organochlorine compounds (OCs) in surface and core sediments collected from Lake Maryut, Egypt, were examined to elucidate their distribution, ecological risk and historical trend. To our knowledge, this is the first study on residue levels of OCs in sediments from Lake Maryut. Concentrations of PCBs and DDTs were higher than other OCs, ranging from 3.06 to 388 and from 0.07 to 106 ng/g dry wt., respectively. The highest concentrations of OCs were found at stations near the discharge point of sewage and close to industrial areas. The distribution of DDT and its metabolites suggest no recent inputs into the lake environment. Contamination levels of sedimentary PCBs and DDTs, can be categorized moderate to high compared to other urbanized regions worldwide. Temporal trends in OCs levels were influenced by input pathways at two sites. Evaluation of ecotoxicological risks suggests that adverse biological effects are expected mainly in the main basin area.