We investigate the importance of selecting two different methodologies for the determination of hydraulic conductivity from
available grain-size distributions on the stochastic modeling of the depth-averaged breakthrough curve observed during a forced-gradient
tracer test experiment. The latter was performed in the Lauswiesen alluvial aquifer, located near the city of Tübingen, Germany,
by injecting NaBr into a well at a distance of about 50 m from a pumping well. We also examine the joint effect of the choice
of the transport model adopted to describe solute transport at the site and the way the spatial distribution of porosity is
assessed. In the absence of direct measurements of porosity, we consider: (a) the model used by Riva et al. (J Contam Hydrol
88:92–118, 2006; J Contam Hydrol 101:1–13, 2008), which relates the natural logarithms of effective porosity and conductivity through an empirical, experimentally-based,
linear relationship derived for a nearby experimental site; and (b) a model based on a commonly used relationship linking
the total porosity to the coefficient of uniformity of grain size distributions. Transport is described in terms of a purely
advective process and/or by including mass exchange processes between mobile and immobile regions. Modeling of flow and transport
is performed within a Monte Carlo framework, upon conceptualizing the aquifer as a random composite medium. Our results indicate
that the model adopted to describe the correlation between conductivity and porosity and the way grain-sieve information are
incorporated to depict the heterogeneous distribution of hydraulic conductivity can have relevant effects in the interpretation
of the data at the site. All the conceptual models employed to describe the structural heterogeneity of the system and transport
features can reasonably reproduce the global characteristics of the experimental depth-averaged breakthrough curve. Specific
details, such as the peak concentration and the time of first arrival, can be better reproduced by a double porosity transport
model when a correlation between conductivity and porosity based on grain size information at the site is considered. The
best prediction of the late-time behavior of the measured breakthrough curves, in terms of the observed heavy tailing, is
offered by directly linking porosity distribution to the spatial variability of particle size information. 相似文献
The Eberswalde crater and its contributing basins have been analyzed in detail in order to reconstruct the geological evolution of the water-related landforms with particular focus on the Eberswalde delta-like feature. Based on a complex strata organization characterized by a topset-foreset-bottomset geometry, typical of delta progradation on Earth, we interpret the Eberswalde feature to be a fan delta associated with a lacustrine system. Depositional sub-environments have been recognized and mapped and the sedimentary processes discussed. A sequence stratigraphy approach has been used to evaluate the system, which we interpret to result from three depositional sequences. These sequences suggest relative water level fluctuations and a longer trend over time towards decreasing water content inside the basin. 相似文献
We calculated the expected impact on the Italian coast of the Adriatic Sea of a large set of tsunamis resulting from potential earthquakes generated by major fault zones. Our approach merges updated knowledge on the regional tectonics and scenario-like calculations of expected tsunami impact. We selected six elongated potential source zones. For each of them we determined a Maximum Credible Earthquake and the associated Typical Fault, described by its size, geometry and kinematics. We then let the Typical Fault float along strike of its parent source zone and simulated all tsunamis it could generate. Simulations are based on the solution of the nonlinear shallow water equations through a finite-difference technique. For each run we calculated the wavefields at specified simulation times and the maximum water height field (above mean sea level), then generated travel-time maps and maximum water height profiles along the target coastline. Maxima were also classified in a three-level code of expected tsunami threat. We found that the southern portion of Apulia facing Albania and the Gargano promontory are especially prone to the tsunami threat. We also found that some bathymetric features are crucial in determining the focalization-defocalization of tsunami energy. We suggest that our results be taken into account in the design of early-warning strategies. 相似文献
This article describes a series of methods developed for the determination of total carbon (CTotal), organic carbon (Corg), hydrogen, nitrogen and sulfur. The following elemental analysers were used: LECO model RC‐412 for the determination of organic carbon, total carbon and hydrogen; LECO model CS‐200 for the determination of total carbon and sulfur; LECO model TN‐400 for the determination of nitrogen; and LECO model TruSpec CHNS for the determination of organic carbon, total carbon, hydrogen, nitrogen and sulfur. Uncertainty and limits of detection and quantification were calculated for each method, as well as the running costs to define the most effective instrument for each material and each analyte. Accuracy was checked by the application of the Sutarno–Steger test. Finally, a compilation of the results obtained in the determination of CTotal, Corg, H, N and S in forty‐nine reference materials is presented. 相似文献
The 14 February, or Valentine's Day, 2016 earthquake located offshore of Christchurch produced a new generation of liquefaction in the coastal environment of Christchurch, an environment of recurrent liquefaction during the 2010–2011 Canterbury Earthquake Sequence. The Valentine's Day earthquake occurred while trenches were open at a site in the coastal environment for studying the 2010–2011 liquefaction features. Observations in the 2016 trenches provided insights into the formation of a suite of surface and subsurface liquefaction features characteristic of the dune deposits, related to the persistent shallow water table, well‐sorted sands within the liquefiable layer and the soil above. Given these conducive conditions, there is a high potential that all earthquakes capable of inducing liquefaction may have been recorded during formation of the dunes near Christchurch. However, overprinting by subsequent generations of liquefaction features may be common and present challenges in unravelling the event history. 相似文献
—The Gran Sasso chain (Central Apennines, Italy) contains one of the largest aquifers of Central Italy. From 1970–1986 the massif was tunnelled through in order to build up a highway and an international underground laboratory for nuclear physics research. These works have strongly modified the hydrogeological situation of the chain, as shown by the decrease in flow rate that occurred in many springs located at the border of the carbonatic structure, along the boundary between the permeable limestone of the massif and the surrounding aquicludes. The analysis of the seismicity (M≥ 3.0) that occurred in the Gran Sasso area from 1956 to 1995 suggests that after the tunnelling works both the number of earthquakes has increased and epicenters have migrated, gathering at the northwestern border zone. The foremost events which occurred in this zone in recent years took place on May 5, 1992 (M = 3.1), August 25, 1992 (M = 3.9) and March 13, 1994 (M = 3.5). The flow rate data of four springs and water level data of an underground karst pool located at the border of the carbonatic structure of the massif show clear anomalies before the occurrence of the quoted earthquakes. Regardless, these anomalies can be explained by the rapid melting of the thick mantle of snow on the Gran Sasso chain, due to sudden increases of mean temperatures. In this paper we present and discuss the possibility that the quoted earthquakes are induced by the irregular variations of the Gran Sasso aquifer, evidenced by the quoted anomalies in the flow rate and water level. 相似文献
The granulites of the Juiz de Fora complex occur within thick basement thrust slices associated with the Pan-African shortening process in the central segment of the Ribeira belt. Five lithological units of the Intermediate tectonic domain of the belt can be identified on the basis of detailed geological mapping: a) orthogranulites, b) orthogneisses; c) kinzigite; d) intrusive garnet charnockite and e) amphibolite facies metasediments of probable Meso to Neoproterozoic age, correlated to the cover of the belt. Petrological data indicate high temperatures and intermediate to low lithostatic pressure conditions for the Paleoproterozoic granulite facies metamorphism. Textures and CO2-rich fluid inclusions are probably related to an IBC path. Geochemical data do not show relevant compositional change as a result of the granulite metamorphism. Two calc-alkaline suites and tholeiitic to alkaline basic rocks can be related to compressional and extensional settings, respectively. The overall composition of the granulites, the lack of substantial LILE depletion as well as the composition of the fluid inclusion points to granulitization process driven by CO2-rich fluids. Orthogranulites gave rise to banded gneisses as a result of the Pan-African retrograde metamorphism and intense deformation. The U and Th depletion detected in few rocks is possibly related with the hydrated conditions of the retrograde reactions. 相似文献
Green manuring of legume crops can improve soil fertility and sustainability. To evaluate its agronomic and environmental effectiveness, gaseous losses of ammonia (NH3) in the surface layer need to be quantified by direct measurements in the field. However, the application of the eddy-covariance technique to atmospheric NH3 is challenging: its high reactivity, water solubility, and low background concentrations all hinder the response time of closed-path sensors for fast measurements of NH3 concentration. Ammonia emissions following green manuring were measured for 21 days using a flux system equipped with a fast-pulsed quantum-cascade tunable-infrared-laser spectrometer. The noisy cross-covariance function for this configuration indicates flux measurements are close to the limit of detection; the low signal-to-noise ratio further increases the uncertainties, introducing a mirroring effect on the fluxes, which results in the rapid alternation between emission and deposition, within the limit of detection (around 13 and 20 ng m?2 s?1, at the 95 and 99% confidence limits, respectively). An evaluation of the measurement errors is presented, focussing on three technical aspects of the eddy-covariance system: (1) time lag, (2) random error, and (3) limit of detection. The NH3 fluxes measured by the spectrometer are close to its limit of detection, with a random error of the same order as the flux.