Flame Atomic Absorption Spectrometry Determination of Trace Amounts of Cadmium and Zinc in Water Samples after Preconcentration onto Modified Amberlite XAD‐4 Resin

In the present article, a procedure for the simultaneous separation and preconcentration of trace amounts of cadmium and zinc is proposed. It is based on the adsorption of cadmium and zinc ions onto a column of Amberlite XAD‐4 resin loaded with aluminon reagent. Cadmium and zinc ions are quantitatively retained on the column in the pH range from 6.5–7.5, at a flow rate of 2 mL min^–1. The cadmium and zinc ions are eluted with 5.0 mL of 5 mol L^–1 HNO₃ solution. Cadmium and zinc are measured by flame atomic absorption spectrometry (FAAS). In the present case, 0.1 μg of cadmium and 0.5 μg of zinc can be concentrated in the column from 1000 mL of aqueous sample, where their concentrations are as low as 0.1 and 0.5 ng mL^–1, respectively. The relative standard deviations, for seven replicated determinations of 1.0 μg mL^–1 of cadmium and zinc, are 1.2 and 1.1%, respectively. The detection limits for cadmium and zinc in the original solution are 0.02 and 0.11 ng mL^–1, respectively. The interference of a large number of anions and cations has been studied and the optimized conditions are utilized for the determination of trace amounts of cadmium and zinc in different environmental and standard samples.     

Assessing hydrochemical evolution of groundwater in limestone terrain via principal component analysis

This paper describes the use of multivariate statistical analysis to trace hydrochemical evolution in a limestone terrain at Zagros region, Iran. The study area includes a deep confined aquifer, overlaid by an unconfined aquifer. The method involves the use of principal component analysis (PCA) to assess and evaluate the hydrochemical evolution based on chemical and isotope variables of 12 piezometers drilled in both the unconfined and confined aquifers. First PCA on all variables shows that water–rock interaction under different conditions with respect to the atmospheric CO₂ is the main process responsible for chemical constituents. As a result, combinations of several ratios such as Ca/TDS, SO₄/TDS and Mg/TDS with physico-chemical and isotope variables reveal different hydrochemical evolution trend in the aquifers. Second PCA on the selective samples and variables reveals that displacement of the unconfined samples from dry to wet season follows a refreshing trend towards river samples that is characterized by reducing electrical conductivity and increasing sulphate and tritium contents. However, the refreshing trend cannot be traced in the confined aquifer samples suggesting no recharge from river to the confined aquifer. Third PCA reveals that, chemical composition of water samples in the unconfined aquifer tends to have considerable difference from each other in the end of recharge period. In contrast, the confined aquifer samples have a tendency to show similar chemical composition during recharge period in comparison to end of dry period. This difference is caused by different mechanism of recharge in the unconfined aquifer (through the whole aquifer surface) and the confined aquifer (through the limited recharge area).     

Association between cloudiness and rainfall over Fars province in Iran

Relationship between precipitation sum and cloud properties over Fars province in Iran was analyzed for the cases of light (4 mm), moderate (17 mm), and heavy (62 mm) precipitation. The cloud properties (temperature and pressure at the top, cloud optical thickness and cloud water path) were obtained from satellite data of spectoradiometer MODIS (MODO6). The spatial distribution of rainfall was obtained from the 3-hourly data of TRMM (3B42). The multivariate regression model was developed to predict the spatial distribution of rainfall. A strong significant positive association between the spatial distribution of cloud characteristics and heavy precipitation was found, while no clear correlation was revealed between light precipitation and cloud properties. The developed regression model comprised 64, 47, and 24% of spatial variance of heavy, moderate, and light rainfall, respectively. The influence of cloud water path on the spatial distribution of rainfall dominates.     

A comprehensive VIKOR method for integration of various exploratory data in mineral potential mapping

The central Iranian volcanic-sedimentary belt in Kerman province of Iran that is located within the Urumieh-Dokhtar magmatic arc zone is chosen to integrate diverse evidential layers for mineral potential mapping. The studied area has high potential of mineral occurrences especially porphyry copper, and the prepared potential maps aim to outline new prospect zones for further investigation. Two evidential layers including the downward continued map and the analytic signal of filtered magnetic data are generated to be used as geophysical plausible traces of porphyry copper occurrences. The low values of the resistivity layer acquired from airborne frequency domain electromagnetic data are also used as an electrical criterion in this study. Four remote sensing evidential layers including argillic, phyllic, propylitic, and hydroxyl alterations are extracted from Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) images in order to map the altered areas associated with porphyry copper deposits. The Enhanced Thematic Mapper Plus (ETM+) images are used as well to prepare iron oxide layer. Since potassic alteration is generally the mainstay of copper ore mineralization, the airborne potassium radiometry data is used to explore both phyllic and potassic alteration. Finally, the geochemical layers of Cu/B/Pb/Zn elements and the main geochemical component responsible for ore mineralization extracted from principal component analysis are included in the integration process to prepare final potential maps. The conventional and the extended version of VIKOR method (as a well-known algorithm in multi-criteria decision making problems) produced two mineral potential maps, and the results were compared with the ones acquired from prevalent methods of the index overlay and fuzzy logic operators of sum and gamma. The final mineral potential maps based upon desired geo-data set indicate adequately matching of high potential zones with previous working and active mines of copper deposits.