Production of gas from coal seams in the Upper Silesian Coal Basin in Poland in the post-injection period of an ECBM pilot site

A pilot site for CO₂ storage in coal seams was set-up in the Upper Silesian Coal Basin in Poland in the scope of the RECOPOL project, funded by the European Commission. About 760 tons CO₂ were injected into the reservoir from August 2004 to June 2005. Breakthrough of the injected CO₂ was established, which resulted in the production of about 10% of the injected CO₂ in this period. This paper reports on activities performed under the European Commission project MOVECBM that aimed at the assessment of the storage performance of the reservoir in the follow-up period, i.e. whether the injected CO₂ was adsorbed onto the coal or whether it was still present as free gas in the pore space. The injection well was used for this purpose, as the production well had to be abandoned for permitting reasons. Several operational periods can be defined between the last injection in June 2005 and the abandonment of the well in October 2007. In the first period the well was shut-in to observe the pressure fall-off, from about 15.0 MPa at the wellhead after the last injection until about 4.5 MPa at the end of 2005. This pressure fall-off curve showed that the reservoir permeability was very low. This seemed to confirm the observed swelling of the coal during the injection period. In the first months of 2006 the pressure at the wellhead was decreased by releasing gas in a controlled way. The amount and composition of the gas were measured. As a result of the pressure reduction, the well flooded with water. A production pump was placed on the former injection well, enabling active production from the coal from March to September 2007. Results of these operations showed that whereas the gas production rates were as expected based on the experience with the production well, the water production was remarkably low. This could be related to permeability issues or, alternatively, indicate a drying effect of the CO₂ in the reservoir. Further, the gas composition showed a predominance of CO₂ over CH₄ during the gas release that changed gradually into a predominance of CH₄ over CO₂ during the production phase. Although stabilization was not reached within the given production period, the composition approached a 60% methane, 40% CO₂ ratio. This indicates that the exchange of these gases is more complex than often envisaged. After removal of the pump the well was filled with water, which ceased the gas release. This indicates that the pressure in the reservoir was back to its original, hydrostatic, state. As the total volume of CO₂ produced was only a fraction of the amount that was injected, it can be concluded that the CO₂ was taken up by the coal and is currently adsorbed. This gives confidence in the long-term stability of the injected CO₂.     

Two-phase, partially miscible flow and transport modeling in porous media; application to gas migration in a nuclear waste repository

We derive a compositional compressible two-phase, liquid and gas, flow model for numerical simulations of hydrogen migration in deep geological repository for radioactive waste. This model includes capillary effects and the gas high diffusivity. Moreover, it is written in variables (total hydrogen mass density and liquid pressure) chosen in order to be consistent with gas appearance or disappearance. We discuss the well possedness of this model and give some computational evidences of its adequacy to simulate gas generation in a water-saturated repository.     

Response of North American Great Basin Lakes to Dansgaard–Oeschger oscillations

We correlate oscillations in the hydrologic and/or cryologic balances of four Great Basin surface-water systems with Dansgaard–Oeschger (D–O) events 2–12. This correlation is relatively strong at the location of the magnetic signature used to link the lake records, but becomes less well constrained with distance/time from the signature. Comparison of proxy glacial and hydrologic records from Owens and Pyramid lakes indicates that Sierran glacial advances occurred during times of relative dryness. If our hypothesized correlation between the lake-based records and the GISP2 δ¹⁸O record is correct, it suggests that North Atlantic D–O stades were associated with relatively cold and dry conditions and that interstades were associated with relatively warm and wet conditions throughout the Great Basin between 50,500 and 27,000 GISP2 yr B.P. The Great Basin lacustrine climate records reinforce the hypothesis that D–O events affected the climate throughout much of the Northern Hemisphere during marine isotope stages 2 and 3. However, the absolute phasing between lake-size and ice-core δ¹⁸O records remains difficult to determine.     

New investigations or recent vertical movements in the Carpatho-Balkan region

Recent work concerning the investigation of vertical movements in the Carpatho-Balkan Region is reported, based on the “Explanatory Text to the Map of Recent Vertical Movements in the Carpatho-Balkan Region”.For this investigation, the following countries supplied information: Bulgaria, Czechoslovakia, GDR, Hungary, Poland, Romania, USSR, Austria, and Italy. The activities were coordinated by the Hungarian Geodetic Service. Hungary undertook the task of collecting the data, their preparation for adjustment, and the adjustment of the investigation network, as well as the compilation and publication of the map of vertical movement. The authors present the algorithm of the rigorous adjustment: the height differences of the second leveling have been adjusted jointly with the velocities derived from the first and second levelings.In this paper the applied geodetic and oceanographic data, as well as the main character of the investigation network are presented. The interpretation of the adjustment is outlined.The map of Recent Vertical Movements in the Carpatho-Balkan Region (CBR) is printed at the scale of 1:1,000,000.In general, it is claimed that due to the new methods of investigation, the new CBR map of vertical movements provides a better tool to help with further investigations.     

Reliability of short seismic links in shear

This paper presents the results of research in reliability of short seismic links in shear based on tests. Four types of short links were analysed, each having the same cross section and the same length, but with different number of web stiffeners. The main purpose of the stiffeners is to preserve buckling of the seismic link web, i.e. to achieve plastification of the cross section by shear. The design model of shear resistance according to Eurocode 8 is applicable only to short links without web stiffeners. By adding the web stiffeners nonlinear inelastic behaviour of short seismic links differs depending on the number of stiffeners, so that the calculation model of shear resistance according to Eurocode 8 for short seismic link with stiffeners should be improved. This fact is considered by introducing the improve factors that were determined from the laboratory tests conducted on 16 specimens. On the base of tests in the second part of this paper the reliability of short seismic link is performed by forming limit state equations. These equations are formed by using the stochastic model, i.e. by describing the statistical nature of basic variables calculating the reliability index as an operational value of failure probability. The reliability level was determined by using the probabilistic analysis based on the first order reliability method which resulted with the conclusion that the short seismic links with two and three couples of web stiffeners designed according to requirements of Eurocode 8 have enough reliability for the reliability class RC2 and the mean recurrence interval of 50 years.     

On persistent primary variables for numerical modeling of gas migration in a nuclear waste repository

Numerical simulation of gas migration driven by compressible two-phase partially miscible flow in porous media is of major importance for safety assessment of deep geological repositories for long-lived high-level nuclear waste. We present modeling of compositional liquid and gas flow for numerical simulations of hydrogen migration in deep geological radioactive waste repository based on persistent primary variables. Two-phase flow is considered, with incompressible liquid and compressible gas, which includes capillary effects, gas dissolution, and diffusivity. After discussing briefly the existing approaches to deal with phase appearance and disappearance problem, including a persistent set of variables already considered in a previous paper (Bourgeat et al., Comput Geosci 13(1):29–42, 2009), we focus on a new variant of the primary variables: dissolved hydrogen mass concentration and liquid pressure. This choice leads to a unique and consistent formulation in liquid saturated and unsaturated regions, which is well adapted to heterogeneous media. We use this new set of variable for numerical simulations and show computational evidences of its adequacy to simulate gas phase appearance and disappearance in different but typical situations for gas migration in an underground radioactive waste repository.     

Source potential and palynofacies of Late Jurassic “Lemeš facies”, Croatia

Laminated limestone and calcareous shale outcrop samples from the Late Jurassic “Leme?” facies (Croatia) were investigated to characterize their organic facies and palynofacies and their hydrocarbon generative potential. The results indicate that the organic rich sediments of “Leme?” facies were deposited within a relatively shallow marine environment at low redox potential, characterized as an oxygen depleted depositional setting with stratified bottom waters of the carbonate platform (Adriatic Carbonate Platform). The organic rich samples contain a high portion of lipid rich amorphous kerogen of algal/phytoplankton origin, enriched by bacterial biomass. Most of the analyzed samples have total organic carbon contents (TOC) greater than 3%, Rock-Eval S2 >20 mg HC/g rock, yielding Hydrogen Index (HI) values ranging from 509–602 mg HC/g TOC. According to these results, the analyzed samples have very good to excellent oil generative potential. Relatively high sulfur content suggests that the kerogen is best described as Type II-S. Biomarker maturity parameters, as well as the fluorescence of the isolated kerogen, show that the organic matter is at early to peak oil thermal maturity. The observed level of thermal maturity indicates that these samples were once buried to depths of ～5.5–5.8 km before being uplifted in the late Tertiary. The surface outcrops of the “Leme?” facies suggest that these strata have significant source potential and are the likely source of oil in the Croatian External Dinarides.     

滇东扬子板缘犁式冲断带的发现及其意义

滇东扬子板块南缘圭山煤田近年来的煤炭资源勘查工作证实，作为扬子板块与华南地体边界的师宗一弥勒大断裂，其中段与北东段及两侧为一北东向展布的大型犁式冲断带？扼要叙述了该断裂带规模、主干断裂与分支主断裂基本特征及其对煤资源的破坏程度，初步分析了断带形成的力学机制。以期引起煤炭勘查工作者和地学界特别是区域地质工作者的关注，促进下一步研究工作的深入开展。     

The problems of the Italo-Croato-Slovene border delimitation in the Northern Adriatic

The Adriatic Sea, and its northern part in particular, is a highly illustrative example of the changing political geography of the sea. In the 1990's the changing political map was influenced by the break-up of Yugoslavia. As a consequence two successor states, Croatia and Slovenia, started delimitation of their common and new international border. In spite of the fact that a joint boundary commission managed to resolve disputes along almost the entire length of the land border, there are several disputed points remaining as well as unresolved issues of maritime delimitation. The authors analysed the existing claims of the two countries and suggested a possible solution. Regardless of existing problems, there are favourable conditions to develop intensive cross-border cooperation.     

Mechanisms of land–sea interactions – the distribution of metals and sedimentary organic matter in sediments of a river-dominated Mediterranean karstic estuary

This paper examines disposal of metals and the origin, characteristics, and distribution of sedimentary organic matter (SOM) in a Mediterranean karstic estuary in the north-eastern Adriatic. This environment offers a real-time, small model system for studies of geochemical processes in microtidal Mediterranean estuaries that are infilling with sediments and classified as river-dominated disequilibrium estuaries. The results have shown that the longitudinal distribution of heavy metals in sediments follows the sedimentation dynamics and deposition pattern of river-borne, clay mineral particles. The highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter, and decreases toward the open sea. The vertical distribution of metals in sediment cores depends on the prevailing pH and Eh conditions. Significant increases of the concentrations of metals in the uppermost strata are the result of recent anthropogenic inputs. The share of the terrestrial component in SOM, estimated by N/C_org atomic ratios and δ¹³C values, decreases with distance from the river mouth. The small vertical variation in δ¹³C values of SOM indicates that a fast sedimentation rate overrides the diagenetically determined decomposition. The results obtained indicate that river-borne inorganic particles, natural terrigenous organic material, and anthropogenic metal loads are trapped in sediments of the estuarine system. Under the prevailing conditions, there is negligible transport towards the open sea.