Capillary hysteresis and gravity segregation in two phase flow through porous media

We study the gravity driven flow of two fluid phases in a one dimensional homogeneous porous column when history dependence of the pressure difference between the phases (capillary pressure) is taken into account. In the hyperbolic limit, solutions of such systems satisfy the Buckley-Leverett equation with a non-monotone flux function. However, solutions for the hysteretic case do not converge to the classical solutions in the hyperbolic limit in a wide range of situations. In particular, with Riemann data as initial condition, stationary shocks become possible in addition to classical components such as shocks, rarefaction waves and constant states. We derive an admissibility criterion for the stationary shocks and outline all admissible shocks. Depending on the capillary pressure functions, flux function and the Riemann data, two cases are identified a priori for which the solution consists of a stationary shock. In the first case, the shock remains at the point where the initial condition is discontinuous. In the second case, the solution is frozen in time in at least one semi-infinite half. The predictions are verified using numerical results.

     

Structural and Hydrogeological Controls on Hydrocarbon and Brine Migration into Drinking Water Aquifers in Southern New York

Environmental concerns regarding the potential for drinking water contamination in shallow aquifers have accompanied unconventional energy development in the northern Appalachian Basin. These activities have also raised several critical questions about the hydrogeological parameters that control the naturally occurring presence and migration of hydrocarbon gases in shallow aquifers within petroliferous basins. To interrogate these factors, we analyzed the noble gas, dissolved ion, and hydrocarbon gas (molecular and isotopic composition) geochemistry of 98 groundwater samples from south‐central New York. All samples were collected ?1km from unconventional drilling activities and sample locations were intentionally targeted based on their proximity to various types of documented fault systems. In agreement with studies from other petroliferous basins, our results show significant correlations between elevated levels of radiogenic [⁴He], thermogenic [CH₄], and dissolved ions (e.g., Cl, Br, Sr, Ba). In combination, our data suggest that faults have facilitated the transport of exogenous hydrocarbon‐rich brines from Devonian source rocks into overlying Upper Devonian aquifer lithologies over geologic time. These data conflict with previous reports, which conclude that hydrodynamic focusing regulates the occurrence of methane and salt in shallow aquifers and leads to elevated levels of these species in restricted flow zones within valley bottoms. Instead, our data suggest that faults in Paleozoic rocks play a fundamental role in gas and brine transport from depth, regulate the distribution of their occurrence in shallow aquifers, and influence the geochemistry of shallow groundwater in this petroliferous basin.     

Comprehensive Analysis of Fish Assemblages in Relation to Seasonal Environmental Variables in an Estuarine River of Indian Sundarbans

Fish distribution in relation to environmental variables was investigated in the Matla River of Sundarban estuarine system. A total of 64 brackish water species belonging to 38 families showing tropical and subtropical affinities were obtained upon monthly sampling of 1 year. The most abundant species were Harpadon nehereus, Gudusia chapra, Coilia neglecta, Coilia ramcarati and Liza parsia. Fish assemblages showed significant seasonal variation as was revealed from MANOVA. MDS ordination plot based on similarity in the fish assemblages revealed that premonsoonal season was distinguishable from the monsoonal and postmonsoonal seasons. Notable differences were also evident between monsoon and postmonsoon. Canonical correspondence analysis indicated that salinity, acidity, inorganic phosphate concentration and dissolved oxygen were the most important environmental variables in determining the observed variation in fish assemblages. Seasonal succession of fish populations may be related to differences in life cycle and adaptation to prevalent ecological conditions. The study therefore suggests that environmental variations in terms of changing salinity and dissolved oxygen have significant influence in structuring estuarine piscine community in this region.     

Crystal chemical and 57Fe Mössbauer study of chromite from the Nuggihalli schist belt (India)

Summary In the Nuggihalli schist belt (India), chromite bodies were affected by intense serpentinization followed by weathering. In spite of the strong oxidation of the chromite grains, some unaltered cores were preserved, and they were characterised using electron probe microanalysis, single-crystal X-ray diffraction and low temperature ⁵⁷Fe Mössbauer spectroscopy. Results of such investigations revealed that chromite cores from the Nuggihalli schist belt are effectively not oxidised, and their study revealed that chromite was not affected by greenschist-facies metamorphism. The apparently highly ordered cation distribution of the chromites, which would suggest low equilibration temperature, is just caused by the very high Cr contents, which prevent Mg–Al exchange between T and M sites. Using Fabries (1979) geothermometer a temperature of about 1180°C was retrieved (Mitra and Bidyananda, 2003), which therefore corresponds to the quenched-in igneous equilibrium.     

Microtremor survey in Talchir, India to ascertain its basin characteristics in terms of predominant frequency by Nakamura's ratio technique

The Talchir Basin, one of India's oldest basins, has been a subject of interest because of its rich coal deposits. The maximum thickness of the basin is about 1500 m. Beyond the basin is the hard metamorphic rocks of Precambrian age. The ambient noise survey data have been analyzed for the Talchir Basin using Nakamura's technique of horizontal–vertical-spectral-ratio (HVSR) to ascertain the basin structure in terms of the predominant frequency. The predominant frequency varies from 0.25 Hz to 7.8 Hz but a major portion of the basin comes under the range of 0.3 Hz–2.4 Hz while on the metamorphic rocks it is as high as 7.8 Hz. The variation in predominant frequency shows a good correlation with the sediment thickness of the basin. The results have been compared with the previous studies by other researchers and it shows consistency with the northerly dip of the basin. The present study has also been compared with the results of the synthetic seismogram that was performed for the Talchir Basin. The predominant frequency obtained from HVSR technique complements well with the frequency at which the peak response spectra ratio is observed. The present study of the predominant frequency identifies quite well the characteristics of Talchir Basin and is in good agreement with the synthetic ground motion modeling of the region.     

Homogeneous freezing of single sulfuric and nitric acid solution drops levitated in an acoustic trap

The freezing temperatures of single supercooled drops of binary and ternary sulfuric and nitric acid solutions were measured while varying the acid concentration. An acoustic levitator was used which allows to freely suspend single solution drops in air without electrical charges thereby avoiding any electrical influences which may affect the freezing process. The drops of typically 500 µm in radius were monitored by a video camera during cooling cycles down to − 85 °C to simulate the upper tropospheric and stratospheric temperature range. The present data confirm that liquid solution droplets can be supercooled far below the equilibrium melting point by approximately 35 °C. They follow the general trend of the expected freezing temperatures for homogeneous ice nucleation.     

Laboratory studies about the interaction of ammonia with ice crystals at temperatures between 0 and −20°C

In laboratory experiments the interactions of ammonia with ice crystals were studied within the temperature range between 0 and −20°C. In a first series of experiments dendritic ice crystals were grown from water vapor in presence of ammonia gas in various concentrations between 4 and 400 ppbv. In a second series of experiments pure ice crystals were exposed to a humidified ammonia–air mixture inside a horizontal flow tube. The influence of temperature, ammonia gas concentration (0.6, 1.5, and 10 ppmv), exposure time, and the presence of impurities such as sulfate on the ammonia uptake by the ice surface was investigated by determining the ammonium content in the melt water of the ice crystals by ion chromatography. During the growth of ice crystals significant amounts of ammonia (around 200 μg/l) were taken up even at small gas concentrations. In contrast, even at high gas concentrations the uptake of ammonia by non-growing ice crystals was lower by approximately one order of magnitude. The presence of sulfate on the ice surface affected an enhanced uptake of ammonia by a factor of 5–10. A model is presented which describes the uptake of ammonia by ice considering the chemical processes occurring in the ice surface layer and simultaneous diffusion of ammonia into bulk ice. Even the increased uptake of ammonia by growing ice is rather small compared to the uptake by water droplets; thus, the major process for scavenging of ammonia from the atmosphere via the ice phase might not be the direct uptake by ice crystals but the riming involving super-cooled droplets containing ammonia.     

Impact of Farakka barrage on the hydrology and fishery of Hoogly estuary

Construction of the Farakka barrage on the Ganga River in April 1975 to augment water supply to the Calcutta port has brought about a significant increase in freshwater discharge in its distributary, the Hoogly estuary. This has naturally resulted in major changes in the ecology of this estuary, causing modifications in the structure of its fishery resources, fishing pattern, and fish production. This paper presents observations on salinity, plankton, bottom biota, fishery resource, and fish production of different zones of the Hooghly estuary during the period 1982–1992. Comparison with similar studies made before and immediately after commissioning of the Farakka barrage (1975–1977) has revealed that the increased freshwater discharge has resulted in considerable decrease in salinity throughout the estuary. The freshwater zone now extends toward the mouth of the estuary. The true estuarine zone has moved seaward and the marine zone has been restricted to the area near the mouth of the estuary. This has effected major changes in plankton dynamics, sharp decline in the fishery of marine and neritic species in the upper estuary, caused a significant increase in catch ofTenualosa ilisha and an over twofold increase in the average annual fish landings from the estuary as a whole. New zonations have been proposed based on the presently, observed salinity values, which are the most significant factor in determining the fishery of any estuary. An interdisciplinary study of the ecology of the new zones is needed to establish their correct biological characteristics.     

Chromitites of komatiitic affinity from the Archaean Nuggihalli greenstone belt in South India

Summary Mineral chemistry and petrological data of chromites from chromitite bands in the N–S trending schist belt of Nuggihalli (southern Karnataka, India), belonging to the Dharwar craton of South India, are presented in this paper. Crystal chemical data indicate a komatiitic affinity of the chromitite. P–T calculations of the chromite-hosting peridotites yielded a pressure range of 13 to 28 kbar and temperatures ranging from 775 to 1080 °C; the oxygen fugacity (log fO₂) varies from +0.5 to +1.6 above the QFM buffer. The P, T and fO₂ data indicate that Nuggihalli chromitites crystallized in an environment akin to the upper mantle. The studied samples also show partial resetting; the lower temperatures ranging from 515 to 680 °C are ascribed to subsequent metamorphism of the area.