Estimation of trace element concentrations in the lunar magma ocean using mineral‐ and metal‐silicate melt partition coefficients

This study uses experimentally determined plagioclase‐melt D values to estimate the trace element concentrations of Sr, Hf, Ga, W, Mo, Ru, Pd, Au, Ni, and Co in a crystallizing lunar magma ocean at the point of plagioclase flotation. Similarly, experimentally determined metal‐silicate partition experiments combined with a composition model for the Moon are used to constrain the concentrations of W, Mo, Ru, Pd, Au, Ni, and Co in the lunar magma ocean at the time of core formation. The metal‐silicate derived lunar mantle estimates are generally consistent with previous estimates for the concentration of these elements in the lunar mantle. Plagioclase‐melt derived concentrations for Sr, Ga, Ru, Pd, Au, Ni, and Co are also consistent with prior estimates. Estimates for Hf, W, and Mo, however, are higher. These elements may be concentrated in the residual liquid during fractional crystallization due to their incompatibility. Alternatively, the apparent enrichment could reflect the inappropriate use of bulk anorthosite data, rather than data for plagioclase separates.     

Improving SST reconstructions from coral Sr/Ca records: multiple corals from Tahiti (French Polynesia)

We reconstruct SST from coral Sr/Ca ratios measured at three coral cores taken from the lagoon of Tahiti (French Polynesia). Two coral cores were drilled from the same coral colony (one horizontally and one vertically), and a third core was drilled vertically from another coral growing at a different site. We evaluate several Sr/Ca records as proxies for regional SST variations: (1) the three single-core records from Tahiti, (2) an average Sr/Ca record computed from the two cores drilled from the same coral colony, (3) an average Sr/Ca record computed from all three Tahiti cores, and (4) an average Sr/Ca record computed from the three Tahiti cores and a fourth core taken from a different island (Rarotonga). On a monthly scale, the average Sr/Ca record including the four coral cores from Tahiti and Rarotonga shows the best correlation with regional SST. The variance of the SST reconstruction is very realistic and the residual SST is low. This suggests that reconstructing SST from average proxy records gives a better representation of regional SST variations. Of the three Tahiti cores, the one that was drilled horizontally shows the best correlation with grid-SST on an annual mean scale. All three Tahiti corals show much larger interannual SST variations than that indicated by grid-SST.     

Evidence for current-controlled morphology along the western slope of Hatton Bank (Rockall Plateau, NE Atlantic Ocean)

A multibeam bathymetric and high- (airgun and sparker) to very high-resolution (Topas) seismic study of the western slope of Hatton Bank (NE Atlantic), located between 600 m and 2,000 m water depth, has revealed a highly variable range of current-controlled morphological features. Two major seabed areas can be distinguished: (1) a non-depositional area corresponding to the top of the bank and (2) a depositional area in which the Hatton Drift has developed. Both areas are characterised by distinct morphologies associated either with rock outcrops and rocky ridges or with smooth surfaces, slides and bedforms controlled mainly by bottom currents interacting with the topography of the bank. The water depth separating the morphological areas probably coincides with the boundary of the Labrador Sea Water and the Lower Deep Water. Morphological features identified in the study area include contourite channels (moats, furrows and scours), fields of sediment waves, edges of contourite deposits, ponded deposits, scarps, gullies, ridges, depressions, slides and slide scars. These morphological features do not necessarily reflect present-day conditions but may have been associated with past current events, consistent with earlier interpretations.     

Fate of Pesticides and Their Transformation Products: First Flush Effects in a Semi‐Arid Catchment

Although it is known for many years, that transformation products (TPs) of pesticides are often more persistent, mobile, and sometimes more toxic than the parent compound, former catchment scale studies of substance release and flushing effects focused only on the parent compound. In this study, four river points were sampled in the Hula Valley, Israel, and samples were analyzed in the lab for chlorpyrifos (CP) and endosulfan residues (including transformation products; TPs). Sampling results of the first rainfall in autumn 2009 identified a strong release of most substances to the rivers. First flush effects of these substances were assessed regarding the risk for drinking water supply and ecology, like fresh water invertebrates and fish. Although, these substances were found in Jordan River water during the first significant rainfall the observed levels are below international drinking water guideline values with no adverse effects on human health in the region. However, the observed CP and chlorpyrifos oxon (CPO) levels are above the acute toxicity for fresh water invertebrates and fish. The study shows that the Hula Valley was an important source of pesticides and TPs at the Upper Jordan River basin and that substance flushing is extremely important for pesticides‐monitoring campaigns.     

Landscape and climatic changes during the end of the Late Prehistory in the Amblés Valley (Ávila, central Spain), from 1200 to 400 cal BC

Correlations between ecological and cultural changes occurred during a short period between the end of Subboreal and the beginning of Subatlantic in the Amblés Valley (Ávila, central Spain) are analyzed, taking into account palaeopalynological and archaeological data. Plant dynamics from pollen analyses, both from archaeological sites and peat bogs, have been interpreted in relation to human settlements and the transformation of economic practices. These provided a comprehensive hypothesis on human/climate interactions at the beginning of the 1st millennium cal BC. There was an ecological crisis in the region that lasted for a century (ca. 850–760 cal BC). This was especially sharp due to both the geographical constraints of the area and its previous agrarian history. This event implied a sudden and abrupt climatic change from xeric and warm conditions (Subboreal) to more humid and cooler ones (Subatlantic). Environmental stress derived from climatic crisis could be an important factor in the explanation of the historical process, whose main consequences were both the origin of the Iron Age peasant villages and the end of the ‘dehesa’ type landscape.     

Evidence of field-scale shifts in transpiration dynamics following bark beetle infestation: Stomatal conductance responses

Amplified eruptive outbreaks of bark beetles as a consequence of climate change can cause tree mortality that significantly affects terrestrial water and carbon fluxes. However, the lack of field-scale observations of underlying physiological mechanisms currently hampers the expression of such ecosystem disturbances in predictive modelling. Based on a unique flux tower dataset from a subalpine forest located in the Rocky Mountains, mechanisms of stomatal response to an extensive bark beetle outbreak were investigated using various models and parametrizations. The datasets cover a decade, including the periods of pre-infestation, infestation, and post-infestation. Field measurements showed considerable decreases in evapotranspiration (ET), transpiration (T), and leaf area index (LAI) during the two-year infestation period compared to the pre-infestation period. Model interpretations of observed water and carbon fluxes indicated that the overall reductions in T were not solely due to decreased LAI, but also to changes in physiological behaviours. The summer season's canopy-scale stomatal conductance was significantly reduced during the infestation period, from 0.0018 to 0.0011 m s⁻¹. One primary reason for the observed variations is likely that the bark beetle infestation hampers the water transport in the xylem. The damage of xylem has important implications for water use efficiency (WUE), which also significantly influences the parameterization of stomatal conductance. When using stomatal conductance models to forecast ecosystem dynamics, it is crucial to recalibrate the model's parameters to ensure the accurate depiction of stomatal dynamics during various infestation periods. The neglect of the temporal variability of canopy-scale stomatal conductance under ecosystem disturbances (e.g., bark beetle infestations) in current earth system models, therefore, requires specific attention in assessments of large-scale water and carbon balances.     

HHSMT observations of the Venusian mesospheric temperature, winds, and CO abundance around the MESSENGER flyby

We present submillimeter observations of ¹²CO J=3-2 and 2-1, and ¹³CO J=2-1 lines of the Venusian mesosphere and lower thermosphere with the Heinrich Hertz Submillimeter Telescope (HHSMT) taken around the second MESSENGER flyby of Venus on 5 June 2007. The observations cover a range of Venus solar elongations with different fractional disk illuminations. Preliminary results like temperature and CO abundance profiles are presented.These data are part of a coordinated observational campaign in support of the ESA Venus Express mission. Furthermore, this study attempts to contribute to cross-calibrate space- and ground-based observations, to constrain radiative transfer and retrieval algorithms for planetary atmospheres, and to a more thorough understanding of the global patters of circulation of the Venusian atmosphere.     

Metal speciation in rivers affected by enhanced soil erosion and acidity

Dissolved (<1 kDa), colloidal (1 kDa–0.45 μm) and particulate (>0.45 μm) size fractions of 30 elements were determined for four rivers (Sirppujoki, Laajoki, Mynäjoki and Paimionjoki), including 12 low-order inflow streams, largely affected by soil erosion and acidity in SW Finland. In addition, geochemical modelling was used to predict the formation of free ions and complexes in these rivers. Total metal concentrations were relatively high but most of the elements occurred mainly in a colloidal or particulate form and even elements expected to be very soluble occurred to a large extent in colloidal form. According to geochemical modelling these patterns could be explained by in-stream metal complexation/adsorption only to a limited extent. Instead there were strong indications that the high metal concentrations and dominant solid fractions were largely caused by erosion of metal bearing phyllosilicates. A strong influence of acid sulphate (AS) soils, known to exist in the catchment, could be clearly distinguished in Sirppujoki river as it had very high concentrations of dissolved metals, while in the two nearby rivers (Laajoki and Mynäjoki) the influence of AS soils was largely masked by eroded phyllosilicates. In Paimionjoki river the colloidal and particulate fractions dominated very strongly, indicating that total metal concentrations are almost solely controlled by erosion of phyllosilicates. Consequently, rivers draining clay plains sensitive to erosion, like those in SW Finland, have generally high “background” metal concentrations due to erosion of relatively non-toxic colloidal/particulate phyllosilicates. Thus, relying on only semi-dissolved (<0.45 μm) concentrations obtained in routine monitoring and/or speciation modelling can lead to a great overestimation of the water toxicity in this environment.