Graphite–sulfide deposits in Ronda and Beni Bousera peridotites (Spain and Morocco) and the origin of carbon in mantle-derived rocks

This paper describes unusual graphite–sulfide deposits in ultramafic rocks from the Serranía de Ronda (Spain) and Beni Bousera (Morocco). These deposits occur as veins, stockworks and irregular masses, ranging in size from some centimeters to a few meters in thickness. The primary mineral assemblage mainly consists of Fe–Ni–Cu sulfides (pyrrhotite, pentlandite, chalcopyrite and cubanite), graphite and chromite. Weathering occurs in some sulfide-poor deposits that consist of graphite (up to 90%), chromite and goethite. Texturally, graphite may occur as flakes or clusters of flakes and as rounded, nodule-like aggregates. Graphite is highly crystalline and shows light carbon isotopic signatures (δ¹³C≈− 15‰ to − 21‰). Occasionally, some nodule-like graphite aggregates display large isotopic zoning with heavier cubic forms (probably graphite pseudomorphs after diamond with δ¹³C up to − 3.3‰) coated by progressively lighter flakes outwards (δ¹³C up to − 15.2‰).Asthenospheric-derived melts originated the partial melting (and melt–rock reactions) of peridotites and pyroxenites generating residual melts from which the graphite–sulfide deposits were formed. These residual melts concentrated volatile components (mainly CO₂ and H₂O), as well as S, As, and chalcophile elements. Carbon was incorporated into the melts from the melt–rock reactions of graphite-bearing (formerly diamonds) garnet pyroxenites with infiltrated asthenospheric melts. Graphite-rich garnet pyroxenites formed through the UHP transformation of subducted kerogen-rich crustal material into the mantle. Thus, graphite in most of the studied occurrences has light (biogenic) carbon signatures. Locally, reaction of the light carbon in the melts with relicts of ¹³C-enriched graphitized diamonds (probably generated from hydrothermal calcite veins in the subducting oceanic crust) reacted with the partial melts to form isotopically zoned nodule-like graphite aggregates.     

Energy efficiency potentials for global climate change mitigation

Energy efficiency is one of the main options for mitigating climate change. An accurate representation of various mechanisms of energy efficiency is vital for the assessment of its realistic potential. Results of a questionnaire show that the EMF27 models collectively represent known channels of energy efficiency reasonably well, addressing issues of energy efficiency barriers and rebound effects. The majority of models, including general equilibrium models, have an explicit end-use representation for the transportation sector. All participating partial equilibrium models have some capability of reflecting the actual market behavior of consumers and firms. The EMF27 results show that energy intensity declines faster under climate policy than under a baseline scenario. With a climate policy roughly consistent with a global warming of two degrees, the median annual improvement rate of energy intensity for 2010–2030 reaches 2.3 % per year [with a full model range of 1.3–2.9 %/yr], much faster than the historical rate of 1.3 % per year. The improvement rate increases further if technology is constrained. The results suggest that the target of the United Nations’ “Sustainable Energy for All” initiative is consistent with the 2-degree climate change target, as long as there are no technology constraints. The rate of energy intensity decline varies significantly across models, with larger variations at the regional and sectoral levels. Decomposition of the transportation sector down to a service level for a subset of models reveals that to achieve energy efficiency, a general equilibrium model tends to reduce service demands while partial equilibrium models favor technical substitution.     

Pin‐supported walls for enhancing the seismic performance of building structures

An application of a pin‐supported wall‐frame system in retrofitting an eleven‐story steel reinforced concrete frame is introduced. The retrofit aims at enhancing integrity and avoiding weak story failure in an existing moment‐resisting frame. Seismic performance of the building before and after the retrofit is assessed through nonlinear dynamic analysis. The results show that the pin‐supported walls are effective in controlling the deformation pattern of the ductile frame and hence in avoiding weak story failure. With the well‐controlled deformation pattern, carefully arranged energy dissipating devices are able to concentrate energy dissipations so that damage to the rest of the structure can be significantly reduced. Copyright © 2012 John Wiley & Sons, Ltd.     

Mineralogical and geochemical characteristics of hydrothermal alteration of basalt in the Kuroko mine area, Japan: implications for the evolution of a Back Arc Basin hydrothermal system

Basalt in the Furutobe District of the Kuroko mine area in Japan is characterized by abundant chlorite and epidote. Fluid inclusion studies indicate that chlorite is formed at lower temperatures (230–250°C) than epidote (250–280°C). The seawater/basalt mass ratio for the early chlorite-rich alteration was high (max. 40), but that for the later alteration was low (0.1–1.8). The CaO, Na₂O and SiO₂ of the bulk rock correlate negatively with MgO, while FeO and Σ Fe correlate positively with MgO. These changes in the characteristic features of hydrothermal alteration from early to late are generally similar to those for a mid-ocean ridge geothermal system accompanying basalt alteration.The MgO/FeO ratios of chlorite and actinolite and the Fe₂O₃ concentration of epidote from the basalt are greater than those of mid-ocean ridge basalt probably owing to the differences in the Fe₂O₃/FeO and MgO/FeO ratios of the parent rocks. The lower CaO concentration and the higher Na₂O concentration of the bulk rock compared with altered mid-ocean ridge basalt can be interpreted in terms of the difference in original bulk rock compositions.The Furutobe basalt, as well as other submarine back arc basalts, contains more vesicles filled with hydrothermal minerals (epidote, calcite, quartz, chlorite, pyrite) than do the mid-ocean ridge basalts. The abundance of vesicles plays an important role in controlling the secondary mineralogy and geochemistry of hydrothermally altered submarine back arc basin basalts.     

Organic models of interstellar grains

A number of experimental studies have been carried out to verify the claim that interstellar grains largely consist of organic material, including biological cells. Our spectroscopic studies on biological cells and organic extracts from carbonaceous compounds have failed to identify the well-known 2200 Å interstellar extinction peak with the organic material.     

The role of the grain boundary at chemical and isotopic fronts in marble during contact metamorphism

Carbon and oxygen isotopic profiles around a low pressure metasomatic wollastonite reaction front in a marble of the Hida metamorphic terrain, central Japan, display typical metamorphic fluid-enhanced isotopic zonations. Isotopic profiles obtained from detailed microscale analyses perpendicular to the chemical reaction front in calcite marble show that diffusion-enhanced isotopic exchange may control these profiles. Carbon and oxygen isotopic behaviour in grain boundaries is remarkably different. Oxygen isotopic troughs (¹⁸O depleted rims) around the calcite-grain boundaries are widely observed in this contact aureole, demonstrating that diffusion of oxygen in calcite grain boundary dominates over lattice diffusion in calcite. In contrast, no difference is observed in carbon isotopic profiles obtained from grain cores and rims. There is thus no specific role of the grain boundary for diffusion of carbonic species in the metamorphic fluid during transportation. Carbon chemical species such as CO₂ and CO₃ ions in metamorphic fluid migrate mainly through lattice diffusion. The carbon and oxygen isotope profiles may be modelled by diffusion into a semi-infinite medium. Empirically lattice diffusion of oxygen isotopes is almost six times faster than that of carbon isotopes, and oxygen grain-boundary diffusion is ten times faster than oxygen lattice diffusion. Oxygen isotopic results around the wollastonite vein indicate that migration of the metamorphic fluid into calcite marble was small and was parallel to the aquifer. From the stability of wollastonite and the attainment of oxygen isotopic equilibrium, we suggest that diffusion of oxygen occurred through an aqueous fluid phase. The timescale of formation of the oxygen isotopic profile around the wollastonite vein is calculated to be about 0.76 × 10⁶ years using the experimentally determined diffusion constant. Received: 14 January 1997 / Accepted: 23 April 1998     

Organic model of interstellar grains

Extinction efficiency of grains is calculated from the Mie formula on the premise that the grains are of organic composition. The optical constants adopted for the calculations are those ofE. coli, polystyrene and bovine albumin. The grain radiusa is assumed to obey a distribution of the formN(a) a ^– and the value of is chosen so as to make the calculated extinction curve match the observed interstellar extinction curve. Although the calculated curve gives a reasonably good fit to the observed extinction curve for wavelength less than 2100 Å, at longer wavelength region agreement is poor. It is concluded that another component is required for the organic model to be viable.     

A pollution history of Chesapeake Bay

Present day anthropogenic fluxes of some heavy metals to central Chesapeake Bay appear to be intermediate to those of the southern California coastal region and those of Narragansett Bay. The natural fluxes, however, are in general higher. On the bases of Pb-210 and Pu-239 + 240 geochronologies and of the time changes in interstitial water compositions, there is a mixing of the upper 30 or so centimeters of the sediments in the mid-Chesapeake Bay area through bioturbation by burrowing mollusks and polychaetes. Coal, coke and charcoal levels reach one percent or more by dry weight in the deposits, primarily as a consequence of coal mining operations.