Identification and geochemical significance of some aromatic components of coal

The aromatic fraction of a Homestead, Kentucky, coal extract was analyzed by combined gas chromatography-mass spectrometry using glass capillary columns. The aromatic fraction was further analyzed by gas chromatography using sulfur specific flame photometric detection. Seventy-eight compounds were identified, some of which have been traced to their possible biological origins. Sulfur-containing aromatic compounds are thought to originate from reaction of elemental sulfur or pyrite with hydrocarbons.     

Directed dispersal of Opuntia species in the Karoo, South Africa: are crows the responsible agents?

The densities of self-established non-indigenous prickly pears (Opuntia ficus-indica) in rangelands of the Karoo recorded on 3434 km of road transects, were on average 800 times greater below telegraph and transmission poles than away from poles, and 200 times greater next to wire fences along roads than in open rangelands. We suggest that this uneven establishment pattern is mainly due to the dispersal of Opuntia ficus-indica seeds by crows and other vertebrates (chiefly primates). Cape (Corvus capensis) and pied crows (C. albus) feed on fruits of Opuntia ficus-indica in the Karoo, and regurgitate pellets containing viable seeds of these plants below nest sites, roosts and occasional perch sites. Crows use man-made structures such as wire fences, telegraph and transmission poles and windmills for perching, roosting and nesting. Crow pellets, containing regurgitated bones and viable seeds of Opuntia spp., and other alien and indigenous plants, are most common around such perch sites. Crows are frequently associated with roads in the Karoo because they scavenge on road kills in the Karoo as well as feeding on fruits, insects and reptiles in road verges. We suggest that dispersal of seeds by crows is important for range extension and establishment of new Opuntia populations.     

Estimation of an optimal mixed-phase inverse filter

Inverse filtering is applied to seismic data to remove the effect of the wavelet and to obtain an estimate of the reflectivity series. In many cases the wavelet is not known, and only an estimate of its autocorrelation function (ACF) can be computed. Solving the Yule-Walker equations gives the inverse filter which corresponds to a minimum-delay wavelet. When the wavelet is mixed delay, this inverse filter produces a poor result.
By solving the extended Yule-Walker equations with the ACF of lag α on the main diagonal of the filter equations, it is possible to decompose the inverse filter into a finite-length filter convolved with an infinite-length filter. In a previous paper we proposed a mixed-delay inverse filter where the finite-length filter is maximum delay and the infinite-length filter is minimum delay.
Here, we refine this technique by analysing the roots of the Z -transform polynomial of the finite-length filter. By varying the number of roots which are placed inside the unit circle of the mixed-delay inverse filter, at most 2 ^α different filters are obtained. Applying each filter to a small data set (say a CMP gather), we choose the optimal filter to be the one for which the output has the largest L ^p -norm, with p =5. This is done for increasing values of α to obtain a final optimal filter. From this optimal filter it is easy to construct the inverse wavelet which may be used as an estimate of the seismic wavelet.
The new procedure has been applied to a synthetic wavelet and to an airgun wavelet to test its performance, and also to verify that the reconstructed wavelet is close to the original wavelet. The algorithm has also been applied to prestack marine seismic data, resulting in an improved stacked section compared with the one obtained by using a minimum-delay filter.     

Space-time variability of the Amazon River plume based on satellite ocean color

Satellite ocean color images were used to determine the space-time variability of the Amazon River plume from 2000–2004. The relationship between sea-surface salinity (SSS) and the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) absorption coefficient for dissolved and detrital material (a_dg) (r²=0.76, n=30, rmse=0.4) was used to identify the Amazon River plume low-salinity waters (<34 psu). The plume's spatial information was extracted from satellite bi-weekly time series using two metrics: plume area and plume shape. These metrics identified the seasonal variability of plume dimensions and dispersion patterns. During the study period, the plume showed the largest areas from July to August and the smallest from December to January. The mean annual amplitude and the mean, maximum and minimum plume areas were 1020×10³ km², 680×10³ km², 1506×10³ km² and 268×10³ km², respectively. Three main shapes and dispersion pattern periods were identified: (1) flow to the northeastern South American coast, in a narrow band adjacent to the continental shelf, from January to April; (2) flow to the Caribbean region, from April to July; and (3) flow to the Central Equatorial Atlantic Ocean, from August to December. Cross-correlation techniques were used to quantify the relationship between the plume's spatial variability and environmental forcing factors, including Amazon River discharge, wind field and ocean currents. The results showed that (1) river discharge is the main factor influencing plume area variability, (2) the wind field regulates the plume's northwestward flow velocity and residence time near the river mouth, and (3) surface currents have a strong influence over river plume dispersion patterns.     

Reconstructing basin evolution from sedimentary thickness; the importance of palaeobathymetric control, with reference to the North Sea

Abstract The structural evolution of a basin cannot be reconstructed from sedimentary thicknesses alone without data on palaeobathymetry. Two classes of geological horizons, are defined, profiles and traces. Profiles are time-lines and bound depositional units. Traces were formed at a known water depth and contain implicit palaeobathymetric data.
Rock units bounded by traces are diachronous lithostratigraphic units, and the thicknesses of such units are controlled directly by subsidence, while the thicknesses of profile-bounded units may be unaffected by the subsidence or even the palaeotopography of the basin.
Dating fault movement from thickness variations in profile-bounded units is difficult without prior knowledge of the palaeobathymetry, and it is impossible to distinguish between synsedimentary fault movement and onlap to a pre-existing fault scarp from thickness alone.
Reconstruction of the basin history of the North Sea is difficult due to the lack of trace-bounded units in the post-Jurassic. The validity of previously published studies depends largely on the quality and quantity of palaeobathymetric data included. An alternative basin history is proposed based on the few trace-bounded units in the North Viking Graben. This includes rifting episodes in the Triassic and Late Jurassic, and a period of uplift in the Palaeocene.     

Fused rock from Köfels,Tyrol

The vesicular glass from Köfels, Tyrol, contains grains of quartz that have been partially melted but not dissolved in the matrix glass. This phenomenon has been observed in similar glasses formed by friction along a thrust fault and by meteorite impact, but not in volcanic glasses. The explosion of a small nuclear device buried behind a steep slope produced a geologic structure that is a good small-scale model of that at Köfels. Impact of a large meteorite would have an effect analogous to that of a subsurface nuclear explosion and is the probable cause of the Köfels feature.

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Zusammenfassung Der Bimsstein von Köfels, Tirol, enthält Körner von Quarz, welche teilweise geschmolzen, aber nicht im Mutterglas gelöst sind. Diese Erscheinung wurde in ähnlichen Gläsern beobachtet, welche durch Reibung entlang von Rutschverwerfungen und durch Meteoriteneinschläge entstanden, aber nicht in vulkanischen Gläsern. Die Explosion eines kleinen nuklearen Gerätes, eingegraben in einem steilen Abhang, brachte eine geologische Struktur hervor, welche ein gutes Modell im kleinen Maßstab des Vorganges bei Köfels darstellt. Der Einschlag eines großen Meteoriten würde einen Effekt hervorrufen, der analog ist einer unterirdischen nuklearen Explosion, und ist wahrscheinlich der Grund für die Bildungen von Köfels.

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Wit 4 Figures

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Publication authorized by the Director, U. S. Geological Survey.