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101.
Cüneyt Akal Osman Candan O. Ersin Koralay Roland Oberhänsli Fukun Chen Dejan Prelević 《International Journal of Earth Sciences》2012,101(1):177-194
Afyon Zone, which was derived from the Anatolide–Tauride platform during closure of the Neo-Tethys, is made up of pre-Mesozoic
basement and unconformably overlying Triassic–Early Tertiary cover series. The Afyon Zone contains widespread metavolcanic
rocks, which are dominated by rhyolite, dacite, and trachyandesite. They form a distinct volcanic succession, which is separated
from the underlying Silurian–Lower Carboniferous metacarbonates and meta-siliciclastics by a regional unconformity. Trachyandesitic
metavolcanics are made up of massive lava flows, pyroclastics and epiclastics, less frequently, domes and dikes, which were
developed on a deeply eroded subaerial landmass. U/Pb and Pb/Pb zircon geochronology yielded Lower Triassic (~250 Ma) ages,
which are interpreted as extrusion age of trachyandesitic volcanics. Based on the stratigraphic, geochronological, and geochemical
data, we suggest that these Lower Triassic magmatic rocks represent an extensional tectonic setting on the northern active
margin of the Gondwana, which led to the development of the northern branch of the Neo-Tethys. 相似文献
102.
Eugen Vujić Giuliana Verbanac Stanislav Francisković-Bilinski Vladis Vujnović Antun Marki 《Studia Geophysica et Geodaetica》2011,55(1):175-190
Based on the ground survey of total-field magnetic data at 53 sites, which recorded a time-series over the interval 2003–2005,
the core field + long wavelength lithospheric field over the middle-northern Croatia region was calculated. The area of the
survey was 18900 km2, an average distance between the neighbouring sites being 12 km. The results were reduced to 2004.5 epoch. This “normal”
total-field was estimated using the firstorder Taylor polynomial as a function of geographic coordinates, and the polynomial
coefficients were calculated with three methods of adjustment: simple and weighted least squares fits and adjustment according
to the most frequent value. The stability of the normal field was tested using the Monte Carlo-type test, by decreasing the
input data set in each adjustment (up to 90%). All obtained field residuals (measured-“normal”) were mutually compared, as
well as fit coefficients of the Taylor polynomials. The residual values indicate the presence of shorter-wavelength anomalies,
specifically three major residual anomalies were found (−106 nT, 74 nT and 57 nT). The geostatistical analysis of the ground
survey data and the normal field residuals (respectively), using the median absolute deviation method, was further conducted
in order to evaluate the calculated anomalies. The geological situation around the anomalies derived by the median absolute
deviation method, and around the normal field residual anomalies, is given. The correlation was found between higher value
anomalies of the normal field residuals, and shallow volcanic rocks and oil field, respectively. 相似文献
103.
A. Šajnović K. Stojanović V. Simić G. S. Pevneva A. K. Golovko B. Jovančiećević 《Geochemistry International》2011,49(10):1022-1034
Liquid thermolysis products of various types of immature kerogen from sedimentary lacustrine rocks from the Valjevo-Mionica
basin in Serbia were studied to evaluate the generation potential of kerogen contained in the organic matter (OM) of the rocks,
determine the composition of the biomarkers and alkylaromatics in the liquid thermolysis products, and elucidate the effect
of Pt4+ and Ru3+ ions (which were added in the form of inorganic salts) on the yield and hydrocarbon composition of the liquid thermolysis
products. For this purpose, representative bitumen-free samples A and B of the sedimentary rocks were subjected to thermolysis
under various conditions. Rock A contains high amount of immature organic matter, which is dominated by kerogen type I/II
and was generated under strongly reduced sedimentation conditions at a high salinity. Sample B is poorer in immature OM than
sample A, and the OM of the former contains kerogen type II/III and was generated predominantly in a reduced environment.
The content of the liquid products and the concentrations of hydrocarbons obtained in the course of thermolysis of bitumen-free
sample A and the typical oil distribution of the biomarkers and alkylaromatics in the thermolysis products confirm a high
generation potential of OM in this rock. In all of our experiments on the thermolysis of bitumen-free sample B, the yield
of liquid products and hydrocarbons is low. According to the kerogen type, the thermolysis of this rock generates much gases.
The Pt4+ and Ru3+ ions (added in the form of simple inorganic salts) increased the yield of liquid (kerogen type I/II) and gaseous (kerogen
type II/III) products. During the thermolysis of various type of immature kerogen in the lacustrine sedimentary rocks at a
temperature of 400°C, the OM attained maturation corresponding to the early catagenesis level. Saturated biomarkers and alkylaomatics
in the thermolysis products of both samples display typical oil distributions. The type of the source OM most strongly affects
the composition of n-alkanes and alkylnaphthalenes. The metal ions used in this research served as catalysts for the methylation process during
the thermolysis of immature kerogen, regardless of its type. The effect of the Pt4+ and Ru3+ ions on other transformations of the hydrocarbons, for example, the destruction of high-molecular n-alkanes to low-molecular ones and on isomerization reactions in molecules of polycyclic biomarkers and alkylaromatics to
thermodynamically more stable isomers in the thermolysis products is controlled, first of all, by the type of the source OM. 相似文献
104.
Robert Šajn Josip Halamić Zoran Peh Lidija Galović Jasminka Alijagić 《Journal of Geochemical Exploration》2011
The objectives of this study are as follows: (a) an assessment of the geochemical background signature of the Drava Valley before the industrial revolution; (b) an evaluation of anthropogenic geochemical influences on the alluvial plains and river terraces in the valley; and (c) a determination of the spatial distribution of trace elements in the alluvial soils of the Drava River downstream of the Austrian–Slovenian border to the confluence of Mura and Drava Rivers. 相似文献
105.
The geothermal waters of the first and the shallowest groundwater system of the Province of Vojvodina in northern Serbia, south part of the Pannonian Basin, are characterized by elevated temperatures (between 25 and 85 °C) and elevated gas content (above 1 Nm3/m3) with a high methane content (average about 94% of total gases). These methane-containing waters are particularly abundant in the Central part of the province between Danube and Tisa rivers. Dominant ions in these waters are sodium and bicarbonate, but the waters also contain significant amounts of calcium, magnesium, potassium, chloride, and ammonium. Components that are of balneological significance include iodine, bromine, fluorine, strontium, lithium, barium, and metasilicic and metaboric acids. Based on statistical analysis, a strong positive correlation is generally observed in about 9.2% cases. A slightly lower correlation appears in about 42.2%, and negative correlation coefficient appears in about 48.6% cases. The dendrogram of the cluster analysis built on the wells shows three main groups. There is the cluster of (Na+)aq, (Cl−)aq and (HCO3−)aq. The second aggregation is (NH4+)aq/(NH3)aq. The third group includes (Mg2+)aq, (Ca2+)aq, (Fe3+)aq, (Sr2+)aq, (Pb2+)aq, and (Zn2+)aq. 相似文献
106.
Stanislav Frančišković-Bilinski Mladen Juračić Darko Tibljaš 《Environmental Earth Sciences》2011,64(7):1755-1761
Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in
Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by
ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in
the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and
in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite
is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in
bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the
most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na,
B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with
sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments
in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the
restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic
matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the
Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples
at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was
also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta
correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below
toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as
a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically
introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles. 相似文献
107.
Dubravka Relić Dragana Đorđević Aleksandar Popović 《Environmental Earth Sciences》2011,63(6):1303-1317
We used elemental carbon, nitrogen, hydrogen and sulfur as well as ratios of hydrogen and nitrogen with total organic carbon
for investigation of source and conditions of organic matter in alluvial Danube sediments. We also determined the pseudo total
concentrations of metals presented as a sum of extracted concentration after five sequential extraction steps. The pseudo
total metal concentrations were found to be (mg kg−1) for Mn, 666; Fe, 25,852; Mg, 16,193; K, 2,063; Ni, 32.4; Zn, 72.2; Pb, 15.0; Cu, 26.0 and for Cr, 15.9. Correlation analysis
and two multivariate analysis methods (principal component and cluster analysis) were helpful in determining the associations
between the pseudo total extracted fractions of metals and with elemental carbon, hydrogen, nitrogen, sulfur, total inorganic
and organic carbon. These correlations will help us to identify substrates of trace metals in different oxic/anoxic conditions.
The correlation results of the trace metals and Fe, K, Mg and Mn suggest their adsorption, mainly onto Fe and Mn (hydro)oxides
and K alumosilicates, whereas correlations of metals with sulfur indicate that they were precipitated as Fe-sulfides. 相似文献
108.
John Davenport Daria Ezgeta-Balić Melita Peharda Sanda Skejić Živana Ninčević-Gladan Slavica Matijević 《Estuarine, Coastal and Shelf Science》2011
The endangered fan shell Pinna nobilis is a large bivalve mollusc (<120 cm shell length) endemic to the Mediterranean that lives one-third buried in soft substrata, generally in shallow coastal waters. We hypothesised that P. nobilis of different sizes would ingest different food sources, because small fan shells will inhale material from closer to the substratum than do large fan shells. We studied stomach contents and faeces of 18 fan shells, 6 small (mean 23.0 cm length), 6 medium-sized (mean 41.5 cm length) and 6 large (mean 62.7 cm length) living in a small area of a low-energy coastal detritic bottom characterised by mud, sand and macroalgae at Mali Ston Bay, Croatia. We found that all P. nobilis ingested copious quantities of undetermined detritus (probably at least 95% of ingested material), phytoplankton, micro and mesozooplankton and pollen grains. Large P. nobilis stomach contents showed a preponderance of water column calanoid copepods, while small fan shells had higher numbers of bivalve larvae. All fan shells took in high numbers of harpacticoid copepods that are benthonic, feeding on microbial communities of detritus and benthic vegetation. There was also a significant selection of phytoplankton species, some apparently occurring between inhalation and ingestion. The stomach contents of small P. nobilis had a higher organic matter content than either medium-sized or large fan shells; this indicated that small fan shells ingested detritus of higher organic content than did larger P. nobilis. As the faeces of all P. nobilis had similar organic matter content, this also indicates higher assimilation efficiencies in small fan shells. The demonstration of differential dietary selectivity by different sized animals has implications for future trophic studies of this endangered species. This study also provides the first demonstration of predation on zooplankton by P. nobilis. 相似文献
109.
Kirsten Linnow Michael Steiger Christine Lemster Hilde De Clercq Maja Jovanović 《Environmental Earth Sciences》2013,69(5):1609-1620
Several double salts have been detected in building materials and most of these salts are incongruently soluble compounds. In contrast to single salts, however, no systematic investigations of the crystallization behavior and deleterious effects of incongruently soluble double salts exist. To assess the damage potential of these salts, a systematic investigation of their highly complex behavior is desirable. This paper deals with the crystallization behavior of various solids in the ternary mixed NaNO3–Na2SO4 system including the formation of the double salt darapskite, Na3NO3SO4·H2O. The crystallization sequence during droplet evaporation experiments at room conditions was determined using Raman and polarization microscopy. The basic idea of this research is to use deviations of the crystallization sequence of a salt or a mixed salt solution from the equilibrium pathway as an indicator to detect the degree of supersaturation. The observed crystallization pathway includes the formation of the metastable phases Na2SO4(III), Na2SO4(V) and darapskite. The experimental observations are discussed on the basis of the NaNO3–Na2SO4–H2O phase diagram and the results provide evidence for crystal growth from highly supersaturated solutions in both systems. If the crystals growing under these conditions are confined, these supersaturations result in substantial crystallization pressures. 相似文献
110.