Mössbauer milliprobe studies of small mineral samples with a silicon drift detector

Analysis of ⁵⁷Fe transmission Mössbauer spectra collected on a system where the proportional counter has been replaced with a silicon drift detector (SDD) to test milliprobing of mineral samples is described. In the region of the 14.4 keV Mössbauer line the detector has about 70% efficiency and is capable of delivering spectroscopic information with a high energy resolution and high counting rate. Satisfactory results are obtained from a phase analysis of mixtures of olivine and ilmenite in the proportion 97:3, 99:1 wt%, where in the latter case 2.4 μg of Fe³⁺ in the form of hematite was found in the ilmenite. New perovskite-type minerals (Pb_1.33Ba_0.67Fe₂O₅, Pb_1.33Sr_0.67Fe₂O₅ and Pb_1.33Ba_0.33Sr_0.33Fe₂O₅), synthesised by a combustion method, were studied by X-ray diffraction and Mössbauer spectroscopy as well. The advantage of the system with SDD compared to a conventional Mössbauer spectrometer equipped with a proportional counter as a detector is demonstrated for the perovskite samples. The Mössbauer set-up with the silicon drift detector may be successfully used for a wide range of materials containing a negligible amount of iron.     

Kenya's regional ambitions or China's Belt‐and‐Road? News media representations of the Mombasa‐Nairobi Standard Gauge Railway

Kenya's Standard Gauge Railway (SGR), and its construction and financing by China, exemplifies the prominence accorded to mega‐infrastructural projects in contemporary economic development, as well as the dependence this has engendered on external loans. Alongside, multiple geographies intertwine in the SGR which is both a component of China's global ‘Belt and Road Initiative’ (BRI), as well as an East African regional link between coastal Kenya and neighbouring landlocked countries. In most popular and academic analyses, the role of China is emphasized over the SGR's positioning within East Africa. Does this then lead to an undermining of the meanings that are attached to the SGR within Kenya? This article seeks to add Kenyan perspectives to the debate over China's infrastructural loans by examining the range of news media discourses that have emerged around the SGR. Utilizing the theoretical lens of South‐South cooperation and African agency, this study analyzes how material infrastructure becomes meaningful within the context of a political superstructure. For Kenya, this political superstructure is shaped not only by Kenya‐China relations, but also by infrastructural competitions within East Africa, as well as within Kenya itself.     

Mass balance of mercury in the Mediterranean Sea

The Mediterranean Basin is rich in mercury from natural and anthropogenic sources. During an extensive research from 2002–2005, measurements of different mercury forms were carried out in the Mediterranean Sea by the Italian research vessel Urania as a part of the Med Oceanor and MERCYMS projects funded by the EU Framework programme. Further on, transport and fate of mercury forms was simulated in water and air compartments by two different models, and an approximate coupling of both models was performed. The new 3-dimensional model PCFLOW3D was completed with the first version of a biogeochemical module which deals with various mercury species in dissolved and particulate forms. Exchange with the bottom and the atmosphere, methylation, demethylation, reduction and oxidation were taken into account. Based on the integrated hydrodynamic-atmospheric model and results of field measurements the mass balance of total mercury in the Mediterranean Sea was determined in order to estimate main sources and sinks and simulate future trends of mercury contamination in the Mediterranean. The following terms were taken into account: sources of mercury from major rivers and from point sources, exchange with the Atlantic Ocean and the Black Sea, estimated natural sources from geotectonic active areas in the sea, exchange with bottom sediments, and evasion to and deposition from the atmosphere.     

Soil aggregation estimates in CZO-Fuchsenbigl

The study presents results on the informativity and spatial variation of soil aggregation characteristics in one of the Critical Zone Observatories (CZO) in Europe – Fuchsenbigl, Austria. Water stable aggregates of different size were measured, and strong relationships between soil aggregation estimates were found. The horizontal variation of water stable aggregates at particular depths can be explained by certain vertical heterogeneity of the soil profiles in space. The water stable aggregates in 1–3 mm size dry aggregates in the upper layer vary from 44% to 76% under native vegetation, drop to 1% under intensive cultivation, and comprise 19% in land not tilled for 5 years. The results allow linking the characteristics of soil structure with other biotic and chemical properties for better estimation of the driving forces for soil aggregate formation.     

Direct Formation of Burkeite in the Geothermal Waters at Vranjska Banja,Serbia

Natural Resources Research - There are no available data about direct burkeite formation on the geothermal waters pipelines in Europe. Data about accompanying minerals of burkeite are also scarce....     

DNA damage and apoptosis in the mussel Mytilus galloprovincialis

The effects of known genotoxic substances (4-nitroquinoline-N-oxide, benzo[a]pyrene, teniposide, etoposide, cycloheximide, tributyltin) on human cells (FLC, HL-60) and on mussels were investigated. The correlations between formation of DNA strand breaks and DNA fragmentation characteristic for the process of apoptosis were estimated. Strand breaks induced by 4-nitroquinoline-N-oxide and benzo[a]pyrene did not correlate with DNA fragmentation detected in the process of apoptosis. Induction of internucleosomal DNA fragmentation in HL-60 cells was initiated by teniposide, etoposide and tributyltin, while in the gills of mussels this was detected only with tributyltin. Levels of DNA strand breaks in natural mussel populations, living at locations under the influence of urban and industrial wastes, do not mirror the apoptotic processes.     

Geo–ecology and management of sensitive montane landscapes

Montane (alpine) areas are generally of high value for nature conservation. Such environments and the habitats they support are dynamic and often fragile. They are vulnerable to disturbance from a range of human activities and are responsive to climate changes over short and long timescales. Biodiversity and conservation values are closely linked to geological history, geomorphological processes and soils, and it is crucial that management systems are based on understanding these links.
There are many similarities between the Cairngorm Mountains (Scotland), the Giant Mountains (Czech Republic) and Abisko Mountains (Sweden) in terms of geology, geomorphology, ecology, links with biodiversity and high conservation importance. Comparable pressures and management issues involve, to varying degrees, a history of human use and impacts from deforestation, pasturing, grazing, recreation and atmospheric pollution. Landscape change therefore involves a complex interplay between natural and anthropogenic factors. Managing such change requires better understanding of the geo–ecological processes involved and the factors that determine landscape sensitivity. This is illustrated through a simple framework and examples from the three areas. Comparison of landscape sensitivity between similar montane areas, but in different geographic locations and climatic environments, should allow more informed management planning and a precautionary approach in advance of further changes in human activity and from predicted global warming scenarios.