Trophic cascades and future harmful algal blooms within ice-free Arctic Seas north of Bering Strait: A simulation analysis

Within larger ice-free regions of the western Arctic Seas, subject to ongoing trophic cascades induced by past overfishing, as well as to possible future eutrophication of the drainage basins of the Yukon and Mackenzie Rivers, prior very toxic harmful algal blooms (HABs) – first associated with ∼100 human deaths near Sitka, Alaska in 1799 – may soon expand. Blooms of calcareous coccolithophores in the Bering Sea during 1997–1998 were non-toxic harbingers of the subsequent increments of other non-siliceous phytoplankton. But, now saxitoxic dinoflagellates, e.g. Alexandrium tamarense, were instead found by us within the adjacent downstream Chukchi Sea during SBI cruises of 2002 and 2003. A previous complex, coupled biophysical model had been validated earlier by ship-board observations from the Chukchi/Beaufort Seas during the summer of 2002. With inclusion of phosphorus as another chemical state variable to modulate additional competition by recently observed nitrogen-fixers, we now explore here the possible consequences of altered composition of dominant phytoplankton functional groups [diatoms, microflagellates, prymnesiophyte Phaeocystis colonies, coccolithophores, diazotrophs, and dinoflagellates] in relation to increases of the toxic A. tamarense, responding to relaxation of grazing pressure by herbivores north of Bering Strait as part of a continuing trophic cascade. Model formulation was guided by validation observations obtained during 2002–2004 from: cruises of the SBI, CHINARE, and CASES programs; moored arrays in Bering Strait; other RUSALCA cruises around Wrangel Island; and SBI helicopter surveys of the shelf-break regions of the Arctic basin. Our year-long model scenarios during 2002–2003 indicate that post bloom silica-limitation of diatoms, after smaller simulated spring grazing losses, led to subsequent competitive advantages in summer for the coccolithophores, dinoflagellates, and diazotrophs. Immediate top-down control is exerted by imposed grazing pressures of the model’s herbivores and bottom-up control is also effected by light-, nitrate-, ammonium-, silicate-, and phosphate-modulated competition among the six functional groups of the simulated phytoplankton community. Similar to the history of the southern North Sea adjacent to the Rhine River, possible farming of northwestern Alaska and Canada, in conjunction with other human activities of ice retreat and overfishing, may lead to future exacerbations of poisonous phytoplankton. These potential killers include both toxic dinoflagellate and diazotroph HABs, deadly to terrestrial and marine mammals, as well as those of prymnesiophytes, some of which have already foamed beaches, while others have killed fishes of European waters.     

The thermo-tectonic history of the Song-Kul plateau, Kyrgyz Tien Shan: Constraints by apatite and titanite thermochronometry and zircon U/Pb dating

The Song-Kul Basin sits on a plateau at the Northern and Middle Kyrgyz Tien Shan junction. It is a lacustrine basin, occupied by Lake Song-Kul and predominantly developed on igneous basement. This basement was targeted for a multi-method chronological study to identify the different magmatic episodes responsible for basement formation and to constrain the timing of the development of its present-day morphology. Zircon U/Pb dating by LA-ICP-MS revealed four different magmatic episodes: a Late Cambrian (~ 500 Ma) island arc system, a Late Ordovician (~ 450 Ma) subduction related intrusion, an Early Permian (~ 290 Ma) collisional stage, and a Middle to Late Permian (~ 260 Ma) post-collisional magmatic pulse. Middle to Late Triassic (~ 200–230 Ma) titanite fission-track ages and Late Triassic – Early Jurassic (~ 180–210 Ma) apatite fission-track ages and thermal history modeling indicate the Song-Kul basement was already emplaced in the shallow crust at that time. An exhumed fossil apatite fission-track partial annealing zone is recognized in the bordering Song-Kul mountain ranges. The area experienced only minor post-Early Mesozoic denudation. The igneous basement was slowly brought to apatite (U–Th)/He retention temperatures in the Late Cretaceous–Palaeogene. Miocene to present reactivation of the Tien Shan does not manifestly affect this part of the orogen.     

Thermo-tectonic history of the Issyk-Kul basement (Kyrgyz Northern Tien Shan,Central Asia)

Lake Issyk-Kul occupies a large Late Mesozoic–Cenozoic intramontane basin between the mountain ranges of the Northern Kyrgyz Tien Shan. These ranges are often composed of granitoid basement that forms part of a complex mosaic assemblage of microcontinents and volcanic arcs. Several granites from the Terskey, Kungey, Trans-Ili and Zhetyzhol Ranges were dated with the zircon U/Pb method (SHRIMP, LA-ICP-MS) and yield concordant Late Ordovician–Silurian (~ 456–420 Ma) emplacement ages. These constrain the “Caledonian” accretion history of the Northern Kyrgyz Tien Shan in the amalgamated Palaeo-Kazakhstan continent. The ancestral Tien Shan orogen assembled in the Early Permian when final closure of the Turkestan Ocean ensued collision of Palaeo-Kazakhstan and Tarim. A Late Palaeozoic structural basement fabric formed and Middle–Late Permian post-collisional magmatism added to crustal growth of the Tien Shan. Permo‐Triassic cooling (~ 300–220 Ma) of the ancestral Tien Shan was unraveled using ⁴⁰Ar/³⁹Ar K-feldspar and titanite fission-track (FT) thermochronology on the Issyk-Kul granitoids. Apatite thermochronology (FT and U–Th–Sm/He) applied to the broader Issyk-Kul region elucidates the Meso-Cenozoic thermo-tectonic evolution and constrains several tectonic reactivation episodes in the Jurassic, Cretaceous and Cenozoic. Exhumation of the studied units occurred during a protracted period of intracontinental orogenesis, linked to far-field effects of Late Jurassic–Cretaceous accretion of peri-Gondwanan blocks from the Tethyan realm to Eurasian. Following a subsequent period of stability and peneplanation, incipient building of the modern Tien Shan orogen in Northern Kyrgyzstan started in the Oligocene according to our data. Intense basement cooling in distinct reactivated and fault-controlled sections of the Trans-Ili and Terskey Ranges finally pinpoint important Miocene–Pliocene (~ 22–5 Ma) exhumation of the Issyk-Kul basement. Late Cenozoic formation of the Tien Shan is associated with ongoing indentation of India into Eurasia and is a quintessential driving force for the reactivation of the entire Central Asian Orogenic Belt.     

Thermodynamic constraints on fayalite formation on parent bodies of chondrites

Abstract— Thermochemical equilibria are calculated in the multicomponent gas‐solution‐rock system in order to evaluate the formation conditions of fayalite, (Fe_0.88–1.0Mg_0.12–0)₂SiO₄, Fa_88–100, in unequilibrated chondrites. Effects of temperature, pressure, water/rock ratio, rock composition, and progress of alteration are evaluated. The modeling shows that fayalite can form as a minor secondary and transient phase with and without aqueous solution. Fayalite can form at temperatures below ?350 °C, but only in a narrow range of water/rock ratios that designates a transition between aqueous and metamorphic conditions. Pure fayalite forms at lower temperatures, higher water/rock ratios, and elevated pressures that correspond to higher H₂/H₂O ratios. Lower pressure and water/rock ratios and higher temperatures favor higher Mg content in olivine. In equilibrium assemblages, fayalite usually coexists with troilite, kamacite, magnetite, chromite, Ca‐Fe pyroxene, and phyllosilicates. Formation of fayalite can be driven by changes in temperature, pressure, H₂/H₂O, and water/rock ratios. However, in fayalite‐bearing ordinary and CV3 carbonaceous chondrites, the mineral could have formed during the aqueous‐to‐metamorphic transition. Dissolution of amorphous silicates in matrices and/or silica grains, as well as low activities of Mg solutes, favored aqueous precipitation of fayalite. During subsequent metamorphism, fayalite could have formed through the reduction of magnetite and/or dehydration of ferrous serpentine. Further metamorphism should have caused reductive transformation of fayalite to Ca‐Fe pyroxene and secondary metal, which is consistent with observations in metamorphosed chondrites. Although bulk compositions of matrices/chondrites have only a minor effect on fayalite stability, specific alteration paths led to different occurrences, quantities, and compositions of fayalite in chondrites.     

A combined-water-system approach for tackling water scarcity: application to the Permilovo groundwater basin,Russia

The suitability of a combined water system (CWS) is assessed for meeting drinking-water demand for the city of Arkhangelsk (northwestern Russian Federation), instead of using the polluted surface water of the Northern Dvina River. An appropriate aquifer system (Permilovo groundwater basin) was found and explored in the 1980s, and there were plans then to operate an abstraction scheme using traditional pumping methods. However, the 1980s planned water system was abandoned due to projected impermissible stream depletion such that complete interception of the cone of depression with the riverbed would cause the riverbed to become dry. The design of a CWS is now offered as an approach to addressing this environmental problem. Several sets of major pumping wells associated with the CWS are located on the banks of Vaymuga River and induce infiltration from the stream. The deficiency of the stream flow in dry seasons is compensated for by pumping from aquifer storage. A numerical model was constructed using MODFLOW-2000. The results of the simulation showed the efficiency of the compensation pumping. The streamflow depletion caused by the CWS is equal to the minimum permissible stream flow and is lower than the depletion projected by the abandoned plan. Application of the CWS in the Permilovo groundwater basin makes it possible to meet water demands during water-limited periods and to avoid environmental problems.     

阿尔泰—萨彦山的新构造运动和区域控震断裂的再活化

阿尔泰—萨彦山系和新构造结构的形成被认为是印度-欧亚板块碰撞带来的远程陆内变形的结果。在本次构造模型中,我们对地质、地震活动数据和地形资料进行了联合分析,认为中亚山带北部地形和地震活动的最大变化仅限于晚古生代区域断层的交叉地带。断层的交叉和接合处应被视为增加基底破碎程度、影响局部应力场变化和预先定位M≥5级的地震震源的最重要的构造因素之一。由此,结合Charysh Terekta和Kurai区域断层交叉带出现的氦和钙华,本次研究获得了发震前兆的一些判断规律。     

Dhofar 225 and Dhofar 735: Relationship to CM2 chondrites and metamorphosed carbonaceous chondrites,Belgica‐7904 and Yamato‐86720

Abstract– Dhofar (Dho) 225 and Dho 735 are carbonaceous chondrites found in a hot desert and having affinities to Belgica‐like Antarctic chondrites (Belgica [B‐] 7904 and Yamato [Y‐] 86720). Texturally they resemble CM2 chondrites, but differ in mineralogy, bulk chemistry and oxygen isotopic compositions. The texture and main mineralogy of Dho 225 and Dho 735 are similar to the CM2 chondrites, but unlike CM2 chondrites they do not contain any (P, Cr)‐sulfides, nor tochilinite 6Fe_0.9S*5(Fe,Mg)(OH)₂. H₂O‐contents of Dho 225 and Dho 735 (1.76 and 1.06 wt%) are lower than those of CM2 chondrites (2–18 wt%), but similar to those in the metamorphosed carbonaceous chondrites of the Belgica‐like group. Bulk compositions of Dho 225 and Dho 735, as well as their matrices, have low Fe and S and low Fe/Si ratios relative to CM2 chondrites. X‐ray powder diffraction patterns of the Dho 225 and Dho 735 matrices showed similarities to laboratory‐heated Murchison CM2 chondrite and the transformation of serpentine to olivine. Dho 225 and 735’s oxygen isotopic compositions are in the high ¹⁸O range on the oxygen diagram, close to the Belgica‐like meteorites. This differs from the oxygen isotopic compositions of typical CM2 chondrites. Experimental results showed that the oxygen isotopic compositions of Dho 225 and Dhofar 725, could not be derived from those of typical CM2 chondrites via dehydration caused by thermal metamorphism. Dho 225 and Dho 735 may represent a group of chondrites whose primary material was different from typical CM2 chondrites and the Belgica‐like meteorites, but they formed in an oxygen reservoir similar to that of the Belgica‐like meteorites.     

UV observations of sdB stars and prospects of WSO–UV mission for such studies

The hot subdwarf B (sdB) stars are considered to be core He-burning stars with surface temperatures T _eff up to 40?000 K and log?g≥5. They are UV bright and ultraviolet observatories have a significant impact on studies of these objects. Using the technical characteristics of the instruments of the World Space Observatory–Ultraviolet (WSO–UV) mission and data from previous UV studies of sdBs we estimate the limiting apparent magnitudes for these stars that can be observed with the signal-to-noise ratio required in fine spectroscopic analysis. WSO–UV is an international space observatory for observation in UV spectral range 100–350 nm, that is beyond the reach of ground-based instruments but where most of astrophysical processes can be efficiently studied with unprecedented capability. The WSO–UV project is currently funded by national space agencies of Russia and Spain with participation of Germany, Ukraine and China. The WSO–UV consists of a 1.7 m aperture telescope (under responsibility of Russia) with instrumentation designed to carry out high resolution spectroscopy, long-slit low resolution spectroscopy and direct sky imaging. The WSO–UV Ground Segment is under development by Spain and Russia. They will coordinate the Mission and Science Operations and provide the satellite tracking stations for the project. The WSO–UV will work as a targeted scientific observatory. The scientific program of the observatory is open to excellent scientific projects from the world-wide community and occupies up to 40% of total observational time.     

EPR and magnetism of the nanostructured natural carbonaceous material shungite

The X-band EPR and magnetic susceptibility in the temperature range 4.2–300 K study of the shungite-I, natural nanostructured material from the deposit of Shunga are reported. Obtained results allow us to assign the EPR signal to conduction electrons, estimate their number, N _P, and evaluate the Pauli paramagnetism contribution to shungite susceptibility. A small occupation (~5%) of the localized nonbonding π states in the zigzag edges of the open-ended graphene-like layers and/or on σ (sp ^2+x ) orbitals in the curved parts of the shungite globules has been also revealed. The observed temperature dependence of the EPR linewidth can be explained by the earlier considered interaction of conduction π electrons with local phonon modes associated with the vibration of peripheral carbon atoms of the open zigzag-type edges and with peripheral carbon atoms cross-linking different nanostructures. The relaxation time T ₂ and diffusion time T _D are found to have comparable values (2.84 × 10⁻⁸ and 1.73 × 10⁻⁸ s at 5.2 K, respectively), and similar dependence on temperature. The magnetic measurements have revealed the suppression of orbital diamagnetism due to small amount of large enough fragments of the graphene layers.