Occupational health and safety hazards in Atlantic Canadian aquaculture: Laying the groundwork for prevention

The growing aquaculture industry is projected to feature ever more prominently in the lives and economies of rural coastal communities in Atlantic Canada and around the world. Both private industry and government have a responsibility to ensure employment opportunities created in aquaculture take place in healthy, safe environments. However, systematic occupational health and safety (OHS) research within this industry, an important prevention tool, is still in its infancy. With particular emphasis on marine aquaculture in Atlantic Canada, we provide a detailed outline of the structure of the industry from feed production through to processing, identify potential OHS hazards associated with each of these activities and make recommendations for future research and action.     

Asian monsoon climate during the Last Glacial Maximum: palaeo‐data–model comparisons

The Last Glacial Maximum (LGM) (23–19 ka BP) in the Asian monsoon region is generally described as cool and dry, due to a strong winter monsoon. More recently, however, palaeo‐data and climate model simulations have argued for a more variable LGM Asian monsoon climate with distinct regional differences. We compiled, evaluated, and partly re‐assessed proxy records for the Asian monsoon region in terms of wet/dry climatic conditions based on precipitation and effective moisture, and of sea surface temperatures. The comparison of the palaeo‐data set to LGM simulations by the Climate Community System Model version 3 (CCSM3) shows fairly good agreement: a dry LGM climate in the western and northern part due to a strengthened winter monsoon and/or strengthened westerly winds and wetter conditions in equatorial areas, due to a stronger summer monsoon. Data–model discrepancies are seen in some areas and are ascribed to the fairly coarse resolution of CCSM3 and/or to uncertainties in the reconstructions. Differences are also observed between the reconstructed and simulated northern boundaries of the Intertropical Convergence Zone (ITCZ). The reconstructions estimate a more southern position over southern India and the Bay of Bengal, whereas CCSM3 simulates a more northern position. In Indochina, the opposite is the case. The palaeo‐data indicate that climatic conditions changed around 20–19 ka BP, with some regions receiving higher precipitation and some experiencing drier conditions, which would imply a distinct shift in summer monsoon intensity. This shift was probably triggered by the late LGM sea‐level rise, which led to changes in atmosphere–ocean interactions in the Indian Ocean. The overall good correspondence between reconstructions and CCSM3 suggests that CCSM3 simulates LGM climate conditions over subtropical and tropical areas fairly well. The few high‐resolution qualitative and quantitative palaeo‐records available for the large Asian monsoon region make reconstructions however still uncertain.     

Ni/S/Cl systematics and the origin of impact‐melt glasses in Martian meteorite Elephant Moraine 79001

Martian meteorite Elephant Moraine A79001 (EET 79001) has received considerable attention for the unusual composition of its shock melt glass, particularly its enrichment in sulfur relative to the host shergottite. It has been hypothesized that Martian regolith was incorporated into the melt or, conversely, that the S‐enrichment stems from preferential melting of sulfide minerals in the host rock during shock. We present results from an electron microprobe study of EET 79001 including robust measurements of major and trace elements in the shock melt glass (S, Cl, Ni, Co, V, and Sc) and minerals in the host rock (Ni, Co, and V). We find that both S and major element abundances can be reconciled with previous hypotheses of regolith incorporation and/or excess sulfide melt. However, trace element characteristics of the shock melt glass, particularly Ni and Cl abundances relative to S, cannot be explained either by the incorporation of regolith or sulfide minerals. We therefore propose an alternative hypothesis whereby, prior to shock melting, portions of EET 79001 experienced acid‐sulfate leaching of the mesostasis, possibly groundmass feldspar, and olivine, producing Al‐sulfates that were later incorporated into the shock melt, which then quenched to glass. Such activity in the Martian near‐surface is supported by observations from the Mars Exploration Rovers and laboratory experiments. Our preimpact alteration model, accompanied by the preferential survival of olivine and excess melting of feldspar during impact, explains the measured trace element abundances better than either the regolith incorporation or excess sulfide melting hypothesis does.     

Metal distribution in sediment cores from São Paulo State Coast, Brazil

Ten sediment core samples with lengths ranging from 35 to 100 cm were collected in the Baixada Santista region and analyzed to determine As, Br, Co, Cr, Cs, Fe, Rb, Sb, Ta, Th, U, Zn and rare earths (Sc, Ce, Eu, La, Lu, Nd, Sm, Tb and Yb) level concentrations using instrumental neutron activation analysis (INAA). The studied region is located in the southeastern coast of São Paulo State and is comprised of a densely urbanized area, the largest industrial complex of the country, with a predominance of petrochemical and fertilizer plants. It is also home to Brazil’s most important and busiest port. The conclusions found that the As, La, Sm, Ne, Ce, Eu, Hf, Ta, Th, and U elements have a high background level in the region and that Fe and Zn were the main indicators of anthropogenic contribution in the sediments.     

Arsenic in sediments, groundwater, and streamwater of a glauconitic Coastal Plain terrain, New Jersey, USA—Chemical “fingerprints” for geogenic and anthropogenic sources

Glauconite-bearing deposits are found worldwide, but As levels have been determined for relatively few. The As content of glauconites in sediments of the Inner Coastal Plain of New Jersey can exceed 100 mg/kg, and total As concentrations (up to 5.95 μg/L) found historically and recently in streamwaters exceed the State standard. In a major watershed of the Inner Coastal Plain, chemical “fingerprints” were developed for streambed sediments and groundwater to identify contributions of As to the watershed from geologic and anthropogenic sources. The fingerprint for streambed sediments, which included Be, Cr, Fe and V, indicated that As was predominantly of geologic origin. High concentrations of dissolved organic C, nutrients (and Cl⁻) in shallow groundwater indicated anthropogenic inputs that provided an environment where microbial activity released As from minerals to groundwater discharging to the stream. Particulates in streamwater during high flow constituted most of the As load; the chemical patterns for these particulates resembled the geologic fingerprint of the streambed sediments. The As/Cr ratio of these suspended particles likely indicates they derived not only from runoff, but from groundwater inputs, because As contributed by groundwater is sequestered on streambed sediments. Agricultural inputs of As were not clearly identified, although chemical characteristics of some sediments indicated vehicle-related inputs of metals. Sediment sampling during dry and wet years showed that, under differing hydrologic conditions, local anthropogenic fingerprints could be obscured but the geologic fingerprint, indicating glauconitic sediments as an As source, was robust.     

Shifts in an epibenthic trophic web across a marine frontal area in the Southwestern Atlantic (Argentina)

Marine benthic trophic relationships and food web structures may be influenced by benthic–pelagic coupling processes, which could also be intensified by the physical dynamics of marine fronts. In this work, we employed stable isotope (δ¹³C and δ¹⁵N) analysis to investigate the influence of the Southwest (SW) Atlantic shelf-break front (SBF; 38–39°S, 55–56°W; Argentina) on an epibenthic trophic web. Epibenthic organisms were sampled, at depths of ~ 100 m, with a non-selective dredge from a sandy bottom community located in frontal (F) and marginal (M) areas. The SBF position and the chlorophyll-a (chl-a) concentrations were inferred using satellite data of the sea surface temperature (SST) and satellite chl-a concentration, respectively. The most noticeable shifts in stable isotopes between the sampled areas were those of the Patagonian scallop, Zygochlamys patagonica (δ¹³C), and those of the sea urchin, Sterechinus agassizi (δ¹⁵N). Diet analyses inferred from stable isotopes and mixing models demonstrated that the dominant component of this community, Z. patagonica, had variable contributions to higher trophic levels between areas. More importantly, the epibenthic assemblage in F areas showed δ¹³C-enriched and δ¹⁵N-depleted isotopic signatures with respect to the M areas. Collectively, this evidence suggests that frontal dynamics promotes the accumulation of δ¹³C-enriched phytoplankton in the seabed in F areas, while in M areas the more degraded organic matter becomes more important in the trophic web, decreasing the δ¹⁵N isotopic signature of the assemblage. Therefore, the trophic web was sustained by fresher food in F areas than in M areas, demonstrating the role of frontal dynamics in the shaping of these communities.     

Towards improving ambient noise tomography using simultaneously curvelet denoising filters and SEM simulations of seismic ambient noise

The aim of this article is to investigate a possible way to improve ambient noise tomography by expanding the data base of useful cross-correlation measurements. We show that the curvelet transform makes it possible to compute synthetic noise correlations by simulating directly seismic ambient noise using the spectral element method. These synthetic correlations can in turn be used to identify surface waves and overtones even on correlations having a signal to noise ratio much lower than one. We hope that the possibility to compute SEM synthetic correlations and to extract more information from correlations will be useful to improve ambient noise tomography and monitoring.     

Turbidity as a proxy for total suspended solids (TSS) and particle facilitated pollutant transport in catchments

Transport of hydrophobic organic pollutants in rivers is mainly coupled to transport of suspended particles. Turbidity measurements are often used to assess the amount of suspended solids in water. In this study, a monitoring campaign is presented where the total concentration of polycyclic aromatic hydrocarbons (PAHs), the amount of total suspended solids (TSS), and turbidity was measured in water samples from five neighboring catchments in southwest Germany. Linear correlations of turbidity and TSS were obtained which were in close agreement to the literature data. From linear regressions of turbidity versus total PAH concentrations in water, mean concentrations of PAH on suspended particles could be calculated and these varied by catchment. These values furthermore comprise a robust measure of the average sediment quality in a given catchment. Since in the catchments investigated in this study, PAH concentrations on suspended particles were stable over a large turbidity range (1–114 Nephelometric Turbidity Units), turbidity could be used as a proxy for total PAHs and likely other highly hydrophobic organic pollutants in river water if the associated correlations are established. Based on that, online monitoring of turbidity (e.g., by optical backscattering sensors) seems very promising to determine annual pollutant fluxes.