Possible detection of an old bipolar shell associated with η Carinae

Continuum-subtracted dereddened images in the light of several atomic lines show the presence of an extended bipolar nebula surrounding η Carinae with size ∼100×45 arcsec² (1.3×0.5 pc²). This feature is best delineated in [O  iii ] 5007. The geometrical disposition and mass of the shell suggest that it was formed by mass ejections from η Carinae. The dynamic age of the nebula is ∼13 000/ V ₇ yr, where V ₇ is the mean expansion velocity in 100 km s⁻¹, and its mass is between 5 and 10 M_⊙. The nebula is photoionized and composed of unprocessed material. The major axes of the nebula and of the Homunculus are nearly perpendicular. We also report the discovery of elongated emission knots prominent in [N  ii ] located 64 to 100 arcsec away from η Carinae, which implies that they were ejected either centuries ago or at a more recent date but with extremely large velocities.     

Sensitivity and uncertainty analysis of mesoscale model downscaled hydro‐meteorological variables for discharge prediction

Precipitation and Reference Evapotranspiration (ETo) are the most important variables for rainfall–runoff modelling. However, it is not always possible to get access to them from ground‐based measurements, particularly in ungauged catchments. This study explores the performance of rainfall and ETo data from the global European Centre for Medium Range Weather Forecasts (ECMWF) ERA interim reanalysis data for the discharge prediction. The Weather Research and Forecasting (WRF) mesoscale model coupled with the NOAH Land Surface Model is used for the retrieval of hydro‐meteorological variables by downscaling ECMWF datasets. The conceptual Probability Distribution Model (PDM) is chosen for this study for the discharge prediction. The input data and model parameter sensitivity analysis and uncertainty estimations are taken into account for the PDM calibration and prediction in the case study catchment in England following the Generalized Likelihood Uncertainty Estimation approach. The goodness of calibration and prediction uncertainty is judged on the basis of the p‐factor (observations bracketed by the prediction uncertainty) and the r‐factor (achievement of small uncertainty band). The overall analysis suggests that the uncertainty estimates using WRF downscaled ETo have slightly smaller p and r values (p= 0.65; r= 0.58) as compared to ground‐based observation datasets (p= 0.71; r= 0.65) during the validation and hence promising for discharge prediction. On the contrary, WRF precipitation has the worst performance, and further research is needed for its improvement (p= 0.04; r= 0.10). Copyright © 2013 John Wiley & Sons, Ltd.     

Fluvial transport of suspended sediment and organic carbon during flood events in a large agricultural catchment in southwest France

Water draining from a large agricultural catchment of 1 110 km² in southwest France was sampled over an 18‐month period to determine the temporal variability in suspended sediment (SS) and dissolved (DOC) and particulate organic carbon (POC) transport during flood events, with quantification of fluxes and controlling factors, and to analyze the relationships between discharge and SS, DOC and POC. A total of 15 flood events were analyzed, providing extensive data on SS, POC and DOC during floods. There was high variability in SS, POC and DOC transport during different seasonal floods, with SS varying by event from 513 to 41 750 t; POC from 12 to 748 t and DOC from 9 to 218 t. Overall, 76 and 62% of total fluxes of POC and DOC occurred within 22% of the study period. POC and DOC export from the Save catchment amounted to 3090 t and 1240 t, equivalent to 1·8 t km^?2 y^?1 and 0·7 t km^?2 y^?1, respectively. Statistical analyses showed that total precipitation, flood discharge and total water yield were the major factors controlling SS, POC and DOC transport from the catchment. The relationships between SS, POC and DOC and discharge over temporal flood events resulted in different hysteresis patterns, which were used to deduce dissolved and particulate origins. In both clockwise and anticlockwise hysteresis, POC mainly followed the same patterns as discharge and SS. The DOC‐discharge relationship was mainly characterized by alternating clockwise and anticlockwise hysteresis due to dilution effects of water originating from different sources in the whole catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

Probabilistic radar rainfall nowcasts using empirical and theoretical uncertainty models

Weather radar has a potential to provide accurate short‐term (0–3 h) forecasts of rainfall (i.e. radar nowcasts), which are of great importance in warnings and risk management for hydro‐meteorological events. However, radar nowcasts are affected by large uncertainties, which are not only linked to limitations in the forecast method but also because of errors in the radar rainfall measurement. The probabilistic quantitative precipitation nowcasting approach attempts to quantify these uncertainties by delivering the forecasts in a probabilistic form. This study implements two forms of probabilistic quantitative precipitation nowcasting for a hilly area in the south of Manchester, namely, the theoretically based scheme [ensemble rainfall forecasts (ERF)‐TN] and the empirically based scheme (ERF‐EM), and explores which one exhibits higher predictive skill. The ERF‐TN scheme generates ensemble forecasts of rainfall in which each ensemble member is determined by the stochastic realisation of a theoretical noise component. The so‐called ERF‐EM scheme proposed and applied for the first time in this study, aims to use an empirically based error model to measure and quantify the combined effect of all the error sources in the radar rainfall forecasts. The essence of the error model is formulated into an empirical relation between the radar rainfall forecasts and the corresponding ‘ground truth’ represented by the rainfall field from rain gauges measurements. The ensemble members generated by the two schemes have been compared with the rain gauge rainfall. The hit rate and the false alarm rate statistics have been computed and combined into relative operating characteristic curves. The comparison of the performance scores for the two schemes shows that the ERF‐EM achieves better performance than the ERF‐TN at 1‐h lead time. The predictive skills of both schemes are almost identical when the lead time increases to 2 h. In addition, the relation between uncertainty in the radar rainfall forecasts and lead time is also investigated by computing the dispersion of the generated ensemble members. Copyright © 2013 John Wiley & Sons, Ltd.     

Determination of the Concentration of Carbonic Species in Natural Waters: Results from a World‐Wide Proficiency Test

The results of an international interlaboratory proficiency test for the determination of carbonic species are presented. Eight laboratories analysed twelve water samples (four synthetic waters, one lake water, four geothermal waters, one seawater and two petroleum waters) by two methods: (a) individual laboratory analytical procedure and (b) acid–base titration curves in tabular form following a standardised protocol. In case (b), the concentrations of carbonic species were calculated by the organiser using the (1) Hydrologists' method, (2) Geochemists' method and/or (3) initial pH and total alkalinity method. For synthetic waters, the averaged % trueness and precision of measurement of the two methods were (trueness = 7.6, precision = 9.4) and (9.0, 3.4) for total alkalinity, and (6.6, 31.0) and (7.8, 6.1) for carbonic alkalinity, respectively. This indicates that the total alkalinity calculation procedure is in general correct in the individual laboratory method, but the carbonic alkalinity calculation procedure has serious problems. The measurements of total alkalinity for lake and seawaters were in agreement in both the methods; however, the individual laboratory measurement method for geothermal and petroleum waters was conceptually incorrect. Thus, the analytical procedures for the determination of carbonic species were reviewed. To apply the Hydrologists' and/or Geochemists' methods, the location of NaHCO₃EP and H₂CO₃EP is necessary, even for samples with pH lower than that of NaHCO₃EP, and a backward titration curve after complete removal of CO₂ must be performed. The initial pH and total alkalinity method is appropriate where a complete analysis of species that contribute to the alkalinity is known.     

LavAtmos: An open-source chemical equilibrium vaporization code for lava worlds

To date, over 500 short-period rocky planets with equilibrium temperatures above 1500 K have been discovered. Such planets are expected to support magma oceans, providing a direct interface between the interior and the atmosphere. This provides a unique opportunity to gain insight into their interior compositions through atmospheric observations. A key process in doing such work is the vapor outgassing from the lava surface. LavAtmos is an open-source code that calculates the equilibrium chemical composition of vapor above a dry melt for a given composition and temperature. Results show that the produced output is in good agreement with the partial pressures obtained from experimental laboratory data as well as with other similar codes from literature. LavAtmos allows for the modeling of vaporization of a wide range of different mantle compositions of hot rocky exoplanets. In combination with atmospheric chemistry codes, this enables the characterization of interior compositions through atmospheric signatures.     

Climate controls on rainfall isotopes and their effects on cave drip water and speleothem growth: the case of Molinos cave (Teruel,NE Spain)

The interpretation of stable isotopes in speleothems in terms of past temperature variability or precipitation rates requires a comprehensive understanding of the climatic factors and processes that influence the δ¹⁸O signal in the way through the atmosphere to the cave, where carbonate precipitates acquiring its final isotopic composition. This study presents for the first time in the Iberia Peninsula an integrated analysis of the isotopic composition of rainfall (δ¹⁸O_p) during 2010–2012 years and, through a detailed monitoring survey, the transference of the primary isotopic signal throughout the soil and epikarst into the Molinos cave (Teruel, NE Spain). Both air temperature and amount of precipitation have an important effect on δ¹⁸O_p values, clearly imprinting a seasonal variability modulated by an amount effect when rainfall events are more frequent or intense. Air mass history and atmospheric circulation influences are considered through the study of weather types, synoptic-scale climate patterns and large-scale atmospheric circulation indexes (North Atlantic Oscillation and Western Mediterranean Oscillation) revealing a dominant source effect on δ¹⁸O_p values in this region where tropical North Atlantic and Western Mediterranean are the two moisture source regions. A delay of 2–3 months occurs between the dripwater oxygen isotopic composition (δ¹⁸O_d) respect to δ¹⁸O_p values as a consequence of large residence time in the epikarst. Limited calcite precipitates are found from winter to spring when δ¹⁸O_d values are less negative and dripwater rates are constant. This study suggests that NE Iberian δ¹⁸O_calcite proxy records are best interpreted as reflecting a combination of parameters, not just paleotemperature or paleorainfall and, if extending present-day situation towards the recent past, a biased signal towards winter values should be expected in Molinos speleothem records.