Multivariate analysis of contamination in the mining district of Linares (Jaén, Spain)

Historically, a significant level of mining activity has taken place in the batholite-related metalogenic enclave of Linares (Jaén province, Spain), associated with Pb–Ag, Cu, Zn and Fe sulphides and Ba sulphate mineralization, though mining here has now been abandoned. Additionally, the area features a significant amount of urban, industrial and agricultural activities. These considerations, taken together, explain the need to assess the levels of concentration of trace elements and to determine their relationship with geogenic and anthropogenic factors. For geochemical characterisation of the soil, the region has been divided into 126 grid squares with an area of 1 km². For each grid square, 32 trace elements have been analysed. Elemental concentrations of Cu, Pb, Zn, As and Mn have been included in statistical analyses. According to the reference levels established by the Regional Government (Junta de Andalucía), soils in a large part of the study area require amendment applications. The comparison of the mean content for each grid square with the reference levels reveals a significant degree of contamination of the soil by Cu (719 mg kg⁻¹), Pb (22,964 mg kg⁻¹) and As (100 mg kg⁻¹) in those grid squares affected by metallurgic activities. By means of factor analysis, four scores have been identified which together account for 80% of the variance observed. The first score is highly correlated with the logarithms of the variables Fe, Th, La, Ti, Al, Na, K, Zr, Y, Nb, Be and Sc. It is a “natural” factor that indicates the type of soil matrix (fundamentally granites and, to a lesser degree, Triassic materials). The second score shows high correlation with the logarithms of the variables Mo, Cu, Pb, Zn, Ag, Co, Mn, As, Cd, Sb, Ba, W and Sn, and is the “metallization” factor related to the mineralization that has been exploited. The third score is mainly determined by the logarithms of the variables Sr, Ca and Mg. This is a “natural” factor that indicates a type of carbonate soil matrix (Miocene). Finally, the fourth factor groups the logarithms of the variables Ni, V and Cr, elements that are associated with the combustion of fossil fuels. Analysis of the patterns of each of the factors identified enabled achieving a global characterisation of the study area. Cluster analysis of the observations showed there to be five clusters relating to the grid squares, differentiated by lithologies and degrees of contamination. These clusters are used to determine the background of granite and to calculate the anomalous load.     

Influence of surface heterogeneities of building granite on its thermal response and its potential for the generation of thermoclasty

Surface properties, especially albedo, and aspect are widely accepted as strong influences on the surface thermal response of building stone to insolation. However, the influence that adjacent areas of stone with very different surface properties may have on the thermal response of a patch of stonework, and the ways in which spatial variation in thermal characteristics might enhance stone decay has received relatively little attention. This paper examines the differential thermal response of granite used in construction that results from the presence of dark coloured micro-granular enclaves within a leucocratic host. Surface temperatures and temperature differences between enclaves exhibiting mico-spalling, enclaves with no spalling and the surrounding stone were measured for different aspects and seasons on a 20th century building in Madrid. These data were used to calculate a number of “indices” related to short-term temperature cycling and temperature gradients that have the theoretical capability of generating irreversible deformation of the stone. These indices suggest that micro-spalling of enclaves, compared to a lack of similar decay on the host-rock, is related to their differential thermal response to insolation, most importantly the lower albedo and thermal conductivity values of the enclaves. However, these factors are not sufficient on their own to trigger spalling, and breakdown was only observed where enclaves also experienced repeated, short-term surface temperature cycling caused by, for example, temporary shading by adjacent vegetation. These rapid temperature reversals are identified as a key contributory factor to the thermally driven decay observed on some of the enclaves.     

Linking sedimentation rates and large‐scale architecture for facies prediction in nonmarine basins (Paleogene,Almazán Basin,Spain)

This article focuses on the relationships between the large‐scale stratigraphic architecture of the Almazán basin infill and the sedimentation rates (SR) calculated for precise time intervals. Our aim was to improve the understanding of the timing and causes of the architectural changes, their significance in terms of accommodation space and sediment supply and their relationship with climate and tectonics. The study area includes the Gómara fluvial fan, the main sediment transfer system of the Almazán basin during Paleogene times. Its large‐scale architecture shifted through time between a stacking pattern of low density ribbon‐like and high density sheet‐like channel fills. Laterally to the fluvial system, mudstone and evaporitic mudstone units represented evaporitic mudflats which passed laterally into palustrine/lacustrine limestone units interpreted as lakes and ponds. Stacked calcretes occurred in distal alluvial and distal floodplain settings. A magnetostratigraphy encompassing 2600 m guided by available fossil mammal biochronology has provided a temporal framework that spans the complete Paleogene infill of the basin, from Late Lutetian to Late Oligocene, filling a gap in the Cenozoic chronostratigraphy of Spanish basins. This permits to constrain the kinematics of the structures both in the basin and in its margins, and to provide the timing for the depositional sequences. These data, combined with a magnetostratigraphic map, where magnetic reversals were traced through the Gómara monocline, allow a detailed analysis of the SR variability across the fluvial system and its adjacent depositional environments. The results show that high sedimentation rates (around 30–40 cm kyr^?1) are related to fluvial environments with low density ribbon‐shaped channels, while low SR (around or below 10 cm kyr^?1) are related to high density sheet‐like channels. Laterally, mud dominated environments with high SR (15–20 cm kyr^?1) grade into palustrine/lacustrine carbonated environments with low SR (around 9 cm ky^?1). The lowest SR (about 3 cm kyr^?1) are related to the development of stacked calcrete profiles in distal floodplain and in the connection of distal alluvial and palustrine/lacustrine units.     

Nonlinear magneto-acoustic waves in the solar atmosphere

The weakly nonlinear evolution of quasi-isentropic magnetoacoustic waves in the solar atmosphere is analyzed. The plasma is assumed to be initially homogeneous, in thermal equilibrium and with a straight and homogeneous magnetic field frozen in. Additionally, the plasma is assumed to be cooled by the standard cooling function in the range of 10⁴ K<T<10⁷ K and heated by a mechanism which is proportional to the density and temperature. The range of temperature where the plasma is isentropically unstable, the e-folding time for thermal instability and the corresponding time and length-scale for wave breaking are found.     

Galileo Constellation Design

A significant effort has been carried out in Europe to define the European Global Navigation Satellite System (GNSS), named Galileo Satellites flying in Medium Earth Orbits (MEO) will compose the system (according to the most recent architecture definition baseline); a regional complement of geosynchronous satellites may be required to increase performances over Europe and maybe also to provide some specific communication services. Nominal medium performances are envisaged, but they will be increased by means of augmentation systems (local or wide area), or even by using simultaneously other GNSSs such as GPS. All the involved requirements make the design process quite complex. A powerful software tool, Elcano, has been developed for this purpose; its capabilities will be outlined, and the results of the design process will be presented. ? 2001 John Wiley & Sons, Inc.     

The coral communities of the Islas Marias archipelago,Mexico: structure and biogeographic relevance to the Eastern Pacific

Various authors have suggested that the Islas Marias archipelago, Mexico, may play a significant biogeographic role in the dispersal of Indo Pacific coral species into the Eastern Pacific; however, the coral communities of this archipelago have received scarce attention to date. Here, we first addressed coral community structure across the islands and, by employing ordination analysis, minimum spanning tree and particle‐tracking experiments, used this information to evaluate the relevance of the archipelago for coral dispersal. Twenty‐four coral communities were recorded in the archipelago. Coral cover varied significantly among islands: Maria Cleofas had large values (38.5%), intermediate values were observed for Maria Madre (26.5%) and Maria Magdalena (22.84%), and relatively low values were recorded for San Juanito (18.5%). Coral communities mainly consisted of Pocillopora (57.3%) and Porites (25.5%) species, while species of Pavona (16%) and Psammocora (0.6%) made relatively minor contributions. Thirteen stony coral species were identified in the archipelago; of these Psammocora profundacella and Pavona duerdeni represent new records. Ordination analysis, minimum spanning tree and particle‐tracking experiments suggested similar connecting paths in the studied area; in general, the Islas Marias stands as a route for coral dispersal of Indo Pacific species into the Northeastern Pacific. In a regional context, the Islas Marias has three major biogeographic implications to coral dispersal: (i) the archipelago stands as a major stepping stone for the transport of species and individuals among the Revillagigedo archipelago, the Gulf of California and the tropical Mexican Pacific; (ii) the Islas Marias may play a seminal role in maintaining the genetic connectivity between southern and northern coral populations along the Mexican Pacific and (iii) because of its relatively pristine status and low levels of human impact, the archipelago may potentially serve as a source of coral propagules for ecosystem recovery in the Gulf of California and along the Pacific coast of the Mexican mainland following natural and/or human induced perturbations.     

Sobre un volcán de Verita recientemente descubierto en el Mioceno de Barqueros. — (Murcia)

While working to construct a geological map. A.Almela, an Engineer of Mines, discovered in Alhama de Murcia a previously unknown volcanic crater. This volcano erupted through the miocene layers and extended above them, thus establishing the date of this eruption as being post-miocene. Since there are no sedimentary rocks in this region of a more recent date it is impossible to fix the date of the eruption any more exactly. The crater is about 1Km. In the surface of the crater one finds slag, scoriaceous lava and compact rocks. The rock is composed of phlogopite, olivine and diopside in phenocrysts in a hyaloid cement with tiny grains of sanidine, olivine and diopside; and a thin layer of phlogopite in a glassy brownish black. A study was made of the chemical constituency of the rocks on the basis of three complete analyses and a comparison was made with the findings already made by Vera-Garrucha and those of Fortuna. All of the data as compiled in the five tables and four diagrams graphically represents the obtained results. The volcanic rocks have a close analogy to those ofOsann’s « Verita » type, which are shown not only by the analytical value of the magmatic parameters but also by the positions of the points shown in diagramsK-mg andLs-Fs-Ks of the three types already analized. In all the samples which have been studied from Barqueros the value of the K₂O is superior to that of Na₂O; it is also greater than that of Vera-Garrucha and less than in that of Fortuna.