Fluxes and sources of suspended organic matter in an estuarine turbidity maximum region during low discharge conditions

Water column concentrations of total suspended solids (TSS), particulate organic carbon (POC) and particulate nitrogen (PN) were measured at three different depths in four different locations bracketing the estuarine turbidity maximum (ETM) along the main channel of a temperate riverine estuary (Winyah Bay, South Carolina, USA). Measurements were carried out over full tidal cycle (over 24 h). Salinity, temperature, current magnitude and direction were also monitored at the same time throughout the water column. Tidally averaged net fluxes of salt, TSS, POC and PN were calculated by combining the current measurements with the concentration data. Under the extreme low river discharge conditions that characterized the study period, net landward fluxes of salt were measured in the lower part of the study area, suggesting that the landward transport through the main channel of the estuary was probably balanced by export out through the sides. In contrast, the net fluxes of salt in the upper reaches of the study area were near zero, indicating a closed salt balance in this part of the estuary. In contrast to salt, the net fluxes of TSS, POC and PN in the deeper parts of the water column were consistently landward at all four sites in Winyah Bay indicating the non-conservative behavior of particulate components and their active transport up the estuary in the region around the ETM.The carbon contents (%POC), carbon:nitrogen ratios (org[C:N]a) and stable carbon isotopic compositions (δ¹³C_POC) of the suspended particles varied significantly with depth, location and tidal stage. Tidally averaged compositions showed a significant increase up the estuary in the %POC and org[C:N]a values of suspended particles consistent with the preferential landward transport of carbon-rich particles with higher vascular plant debris content. The combination of tidal resuspension and flood-dominated flow appeared to be responsible for the hydrodynamic sorting of particles along the estuary that resulted in denser, organic-poor particles being transported landward less efficiently. The elemental and isotopic compositions indicated that vascular C₃ plants and estuarine algae were the major sources of the particulate organic matter of all the samples, without any significant contributions from salt marsh C₄ vegetation (Spartina alterniflora) and/or marine phytoplankton.     

Sources and distribution of organic matter in a river-dominated estuary (Winyah Bay, SC, USA)

The sources and distribution of organic matter (OM) in surface waters and sediments from Winyah Bay (South Carolina, USA) were investigated using a variety of analytical techniques, including elemental, stable isotope and organic biomarker analyses. Several locations along the estuary salinity gradient were sampled during four different periods of contrasting river discharge and tidal range. The dissolved organic carbon (DOC) concentrations of surface waters ranged from 7 mg l⁻¹ in the lower bay stations closest to the ocean to 20 mg l⁻¹ in the river and upper bay samples. There was a general linear relationship between DOC concentrations and salinity in three of the four sampling periods. In contrast, particulate organic carbon (POC) concentrations were significantly lower (0.1–3 mg l⁻¹) and showed no relationship with salinity. The high molecular weight dissolved OM (HMW DOM) isolated from selected water samples collected along the bay displayed atomic carbon:nitrogen ratios ([C/N]a) and stable carbon isotopic compositions of organic carbon (δ¹³C_OC) that ranged from 10 to 30 and from −28 to −25‰, respectively. Combined, such compositions indicate that in most HMW DOM samples, the majority of the OM originates from terrigenous sources, with smaller contributions from riverine and estuarine phytoplankton. In contrast, the [C/N]a ratios of particulate OM (POM) samples varied significantly among the collection periods, ranging from low values of 5 to high values of >20. Overall, the trends in [C/N]a ratios indicated that algal sources of POM were most important during the early and late summer, whereas terrigenous sources dominated in the winter and early spring.In Winyah Bay bottom sediments, the concentrations of the mineral-associated OM were positively correlated with sediment surface area. The [C/N]a ratios and δ¹³C_OC compositions of the bulk sedimentary OM ranged from 5 to 45 and from −28 to −23‰, respectively. These compositions were consistent with predominant contributions of terrigenous sources and lesser (but significant) inputs of freshwater, estuarine and marine phytoplankton. The highest terrigenous contents were found in sediments from the river and upper bay sites, with smaller contributions to the lower parts of the estuary. The yields of lignin-derived CuO oxidation products from Winyah Bay sediments indicated that the terrigenous OM in these samples was composed of variable mixtures of relatively fresh vascular plant detritus and moderately altered soil OM. Based on the lignin phenol compositions, most of this material appeared to be derived from angiosperm and gymnosperm vascular plant sources similar to those found in the upland coastal forests in this region. A few samples displayed lignin compositions that suggested a more significant contribution from marsh C₃ grasses. However, there was no evidence of inputs of Spartina alterniflora (a C₄ grass) remains from the salt marshes that surround the lower sections of Winyah Bay.     

Diagnosis of trace metal contamination in sediments: the example of Ensenada and El Sauzal, two harbors in Baja California, Mexico

Total metal concentrations in sediments from within Ensenada and El Sauzal Harbors are generally higher than at the mouths. Grain-size analyses suggested that this enrichment could be due to the presence of fine-grained sediments in the inner part of the harbors rather than to anthropogenic perturbations. The (Me/Al)(sample) ratios for Pb, Co, Ni and Fe were significantly higher for Ensenada Harbor relative to El Sauzal Harbor, whereas the ratios for Cd, Mn, Zn and Cu were statistically equivalent for both harbors. Calculated enrichment factors [EF(Me)=(Me/Al)(sample)/(Me/Al)(shale)] indicated that the metals showing slight enrichment were those associated with anthropogenic contamination (Pb, Zn), or probably related to primary productivity in the water column (Cd, Co). The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake.     

Possible pingo fields in the Utopia basin, Mars: Geological and climatical implications

The presence of pingos on Mars has been hypothesized since the period of the Viking mission. In fact, a diverse range of pingo-like features has been found at various martian sites including Elysium, Chryse and Utopia Planitiae in the northern lowlands. Due to the morphology and the geological setting, some of those features were interpreted in different ways, creating some controversies, as happened in Athabasca Valles. This reflects the complexity of interpreting these features by remote sensing and multiple plausible interpretations of the same feature. With the objective of identifying new possible pingos or rootless cones on Mars, we selected a study area in Utopia Planitia (10-55° N, 210-260° W) where the presence of both features is possible due to its geological history (volcanic and hydrological). We analyzed more than 2100 Mars Orbiter Camera (MOC)-narrow angle images in addition to Viking, Thermal Emission Imaging System (THEMIS), and High Resolution Stereo Camera (HRSC) images, together with Mars Orbiter Laser Altimeter (MOLA)-derived Digital Elevation Models (DEMs) with a Geographic Information System (GIS). We found in 94 MOC-narrow angle images dome, cone, and ring-shaped features. We analyzed them from morphological and morphometrical points of view in order to compare them with relevant features on Mars and Earth. We tested different possible origins for those features following the approach of multiple working hypotheses. We conclude that the dome, cone, and ring-shaped features could be pingos, which is in agreement with their geological settings. Regarding the driving heat source for the formation of the purported pingos, we propose the existence of a heat source, possibly a magma chamber, underneath the surface of the Utopia basin. Together with possible climatic shifts, the past activities of the heat source may have caused melting of ground ice. The pingo growth due to freezing of the water would have occurred during the following cold climatic conditions.     

A note on climate change adaptation for seaports: a challenge for global ports, a challenge for global society

With 80 % of world trade carried by sea, seaports provide crucial linkages in global supply-chains and are essential for the ability of all countries to access global markets. Seaports are likely to be affected directly and indirectly by climatic changes, with broader implications for international trade and development. Due to their coastal location, seaports are particularly vulnerable to extreme weather events associated with increasing sea levels and tropical storm activity, as illustrated by hurricane “Sandy”. In view of their strategic role as part of the globalized trading system, adapting ports in different parts of the world to the impacts of climate change is of considerable importance. Reflecting the views of a diverse group of stakeholders with expertise in climate science, engineering, economics, policy, and port management, this essay highlights the climate change challenge for ports and suggests a way forward through the adoption of some initial measures. These include both “soft” and “hard” adaptations that may be spearheaded by individual port entities, but will require collaboration and support from a broad range of public and private sector stakeholders and from society at large. In particular, the essay highlights a need to shift to more holistic planning, investment and operation.     

Assessment of soil factors controlling ephemeral gully erosion on agricultural fields

The soil factor is crucial in controlling and properly modeling the initiation and development of ephemeral gullies (EGs). Usually, EG initiation has been related to various soil properties (i.e. sealing, critical shear stress, moisture, texture, etc.); meanwhile, the total growth of each EG (erosion rate) has been linked with proper soil erodibility. But, despite the studies to determine the influence of soil erodibility on (ephemeral) gully erosion, a universal approach is still lacking. This is due to the complex relationship and interactions between soil properties and the erosive process. A feasible soil characterization of EG erosion prediction on a large scale should be based on simple, quick and inexpensive tests to perform. The objective of this study was to identify and assess the soil properties – easily and quickly to determine – which best reflect soil erodibility on EG erosion. Forty‐nine different physical–chemical soil properties that may participate in establishing soil erodibility were determined on agricultural soils affected by the formation of EGs in Spain and Italy. Experiments were conducted in the laboratory and in the field (in the vicinity of the erosion paths). Because of its importance in controlling EG erosion, five variables related to antecedent moisture prior to the event that generated the gullies and two properties related to landscape topography were obtained for each situation. The most relevant variables were detected using multivariate analysis. The results defined 13 key variables: water content before the initiation of EGs, organic matter content, cation exchange capacity, relative sealing index, two granulometric and organic matter indices, seal permeability, aggregates stability (three index), crust penetration resistance, shear strength and an erodibility index obtained from the Jet Test erosion apparatus. The latter is proposed as a useful technique to evaluate and predict soil loss caused by EG erosion. Copyright © 2018 John Wiley & Sons, Ltd.