Twenty years of progresses in oceanic rogue waves: the role played by weakly nonlinear models

Here we discuss some of the progresses that have been made in the last 20 years in the field of oceanic rogue waves, focusing on the role played by leading order equations such as the nonlinear Schrödinger and the Korteweg-De Vries equations. For such equations, it is possible, as shown in Onorato et al. (Origin of heavy tail statistics in equations of the nonlinear Schrödinger type: an exact result, 2016. arXiv:1601.04317), to derive a very simple relation in which the variation of the third (for the KdV) and fourth (for the NLS) moment of the probability density function of the wave field can be related to the variation of the spectral bandwidth. These relations give some new perspectives on the formation of rogue waves in a random sea state.     

Regional retrograde alteration of sub-greenschist facies chlorite to smectite

Dioctahedral smectite is present as a retrograde alteration product of chlorite in Permian-Triassic red slates of the Malaguide Complex in Sierra de Espuña (Betic Cordillera). Mineral assemblages and textures, illite crystallinity indices, and fluid inclusion data indicate sub-greenschist facies conditions that reached at least 180°C in the higher-grade tectonic unit of the Malaguide Complex, preceding formation of smectite. Smectite, having K as the dominant interlayer cation, occurs ubiquitously intercalated with trioctahedral chlorite as thin packets of layers and as individual layers that commonly change to chlorite along layers. Although some chlorite is typically homogeneous and trioctahedral, much chlorite shows signs of alteration and has compositions corresponding to different degrees of smectite contaimination. The incompatibility of metamorphic grade with the occurrence of smectite, the general association of chlorite and smectite, and the textural relations collectively show that dioctahedral smectite is derived through replacement of trioctahedral chlorite. Such replacement occurs on a regional basis and demonstrates that caution must be used in interpreting the occurrence of smectite in pelites as being due to prograde processes. Alteration of trioctahedral chlorite under oxidizing conditions due to introduction of phreatic water after uplift of the Betic Cordillera is proposed as the cause of formation of smectite.     

A New Appraisal of Sri Lankan BB Zircon as a Reference Material for LA‐ICP‐MS U‐Pb Geochronology and Lu‐Hf Isotope Tracing

A potential zircon reference material (BB zircon) for laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U‐Pb geochronology and Hf isotope geochemistry is described. A batch of twenty zircon megacrysts (0.5–1.5 cm³) from Sri Lanka was studied. Within‐grain rare earth element (REE) compositions are largely homogeneous, albeit with some variation seen between fractured and homogeneous domains. Excluding fractured cathodoluminescence bright domains, the variation in U content for all analysed crystals ranged from 227 to 368 μg g^?1 and the average Th/U ratios were between 0.20 and 0.47. The Hf isotope composition (0.56–0.84 g/100 g Hf) is homogeneous within and between the grains – mean ¹⁷⁶Hf/¹⁷⁷Hf of 0.281674 ± 0.000018 (2s). The calculated alpha dose of 0.59 × 10¹⁸ g^?1 for a number of BB grains falls within the trend of previously studied, untreated zircon samples from Sri Lanka. Aliquots of the same crystal (analysed by ID‐TIMS in four different laboratories) gave consistent U‐Pb ages with excellent measurement reproducibility (0.1–0.4% RSD). Interlaboratory assessment (by LA‐ICP‐MS) from individual crystals returned results that are within uncertainty equivalent to the TIMS ages. Finally, we report on within‐ and between‐grain homogeneity of the oxygen isotope systematic of four BB crystals (13.16‰ VSMOW).     

Geochemistry of groundwater in the alluvial plain of Tucumán province, Argentina

The Salí River hydrogeological basin is one of the most productive artesian basins in Argentina. It is located in the southeastern part of the province of Tucumán, northwestern Argentina, and its groundwater resources are developed for water supply and irrigation. The chemical composition of the water is strongly influenced by the interaction with the basinal sediments and by hydrologic characteristics such as the flow pattern and time of residence. Three hydrochemical zones are defined in the study area and the processes that control the chemical composition of the water are manifestly different in each zone. The dissolution of halite, sodium sulphate, and gypsum explains part of the contained Na⁺, K⁺, Cl^–, SO₄ ^2–, and Ca²⁺, but other processes, such as cation exchange, calcite precipitation, weathering of aluminosilicates, and gas exchange with the atmosphere, also contribute to the water composition. The assessment of contamination indicators, such as pH, dissolved organic matter, dissolved oxygen, phosphate, and nitrate, indicates that the groundwater is suitable for human consumption. However, biological contamination has been detected in samples from some wells, especially those near the Salí River. Electronic Publication     

Surface dynamic deformation estimates from local seismicity: the Itoiz reservoir,Spain

We analyze the ground motion time histories due to the local seismicity near the Itoiz reservoir to estimate the near-source, surface 3D displacement gradients and dynamic deformations. The seismic data were obtained by a semipermanent broadband and accelerometric network located on surface and at underground sites. The dynamic deformation field was calculated by two different methodologies: first, by the seismo-geodetic method using the data from a three-station microarray located close to the dam, and second, by single station estimates of the displacement gradients. The dynamic deformations obtained from both methods were compared and analyzed in the context of the local free-field effects. The shallow 1D velocity structure was estimated from the seismic data by modeling the body wave travel times. Time histories obtained from both methods result quite similar in the time window of body wave arrivals. The strain misfits between methods vary from 1.4 to 35.0 % and rotational misfits vary from 2.5 to 36.0 %. Amplitudes of displacement gradients vary in the range of 10^?8 to 10^?7 strains. From these results, a new scaling analysis by numerical modeling is proposed in order to estimate the peak dynamic deformations for different magnitudes, up to the expected maximum M _w in the region (M5.5). Peak dynamic deformations due to local M _w5.5 earthquakes would reach amplitudes of 10^?5 strain and 10^?3 radians at the Itoiz dam. The single station method shows to be an adequate option for the analysis of local seismicity, where few three-component stations are available. The results obtained here could help to extend the applicability of these methodologies to other sites of engineering interest.     

Geostrophic Adjustment Problems in a Polar Basin

The geostrophic adjustment of a homogeneous fluid in a circular basin with idealized topography is addressed using a numerical ocean circulation model and analytical process models. When the basin is rotating uniformly, the adjustment takes place via excitation of boundary propagating waves and when topography is present, via topographic Rossby waves. In the numerically derived solution, the waves are damped because of bottom friction, and a quasi-steady geostrophically balanced state emerges that subsequently spins-down on a long time scale. On the f-plane, numerical quasi-steady state solutions are attained well before the system's mechanical energy is entirely dissipated by friction. It is demonstrated that the adjusted states emerging in a circular basin with a step escarpment or a top hat ridge, centred on a line of symmetry, are equivalent to that in a uniform depth semicircular basin, for a given initial condition. These quasi-steady solutions agree well with linear analytical solutions for the latter case in the inviscid limit.

On the polar plane, the high latitude equivalent to the β-plane, no quasi-steady adjusted state emerges from the adjustment process. At intermediate time scales, after the fast Poincaré and Kelvin waves are damped by friction, the solutions take the form of steady-state adjusted solutions on the f-plane. At longer time scales, planetary waves control the flow evolution. An interesting property of planetary waves on a polar plane is a nearly zero eastward group velocity for the waves with a radial mode higher than two and the resulting formation of eddy-like small-scale barotropic structures that remain trapped near the western side of topographic features.

RÉSUMÉ?Traduit par la rédaction] Nous étudions l'ajustement géostrophique d'un fluide homogène dans un bassin circulaire ayant une topographie idéalisée à l'aide d'un modèle numérique de circulation océanique et de modèles analytiques de processus. Quand le bassin est en rotation uniforme, l'ajustement se fait par l'excitation d'ondes de propagation aux limites, et en présence de topographie, par des ondes de Rossby topographiques. Dans la solution numériquement dérivée, les ondes sont amorties à cause frottement contre le fond, et un état quasi-stable géostrophiquement équilibré s’établit pour ensuite décélérer sur une longue période de temps. Sur le plan f, les solutions numériques d’états quasi-stables sont atteintes bien avant que l’énergie du système mécanique soit entièrement dissipée par le frottement. Nous démontrons que les états ajustés apparaissant dans un bassin circulaire avec un accore en forme de marche ou une crête en forme de merlon, centrés sur une ligne de symétrie, sont équivalents à ceux d'un bassin semi-circulaire de profondeur uniforme pour une condition initiale donnée. Les solutions quasi-stables s'accordent bien avec les solutions analytiques linéaires pour le dernier cas dans la limite de la non-viscosité.

Sur le plan polaire, la haute latitude équivalente au plan β, le processus d'ajustement n'aboutit à aucun état ajusté quasi-stable. Aux échelles de temps intermédiaires, après l'amortissement des ondes rapides de Poincaré et Kelvin par le frottement, les solutions prennent la forme de solutions ajustées d’états stables sur le plan f. Aux échelles de temps plus longues, les ondes planétaires déterminent l’évolution de l’écoulement. Une propriété intéressante des ondes planétaires sur un plan polaire est une vitesse de groupe presque nulle vers l'est pour les ondes ayant un mode radial plus grand que deux et la formation résultante de structures barotropiques de petite échelle de type remous qui demeurent emprisonnées près du bord ouest des caractéristiques topographiques.     

The ionosphere: effects,GPS modeling and the benefits for space geodetic techniques

The main goal of this paper is to provide a summary of our current knowledge of the ionosphere as it relates to space geodetic techniques, especially the most informative technology, global navigation satellite systems (GNSS), specifically the fully deployed and operational global positioning system (GPS). As such, the main relevant modeling points are discussed, and the corresponding results of ionospheric monitoring are related, which were mostly computed using GPS data and based on the direct experience of the authors. We address various phenomena such as horizontal and vertical ionospheric morphology in quiet conditions, traveling ionospheric disturbances, solar flares, ionospheric storms and scintillation. Finally, we also tackle the question of how improved knowledge of ionospheric conditions, especially in terms of an accurate understanding of the distribution of free electrons, can improve space geodetic techniques at different levels, such as higher-order ionospheric effects, precise GNSS navigation, single-antenna GNSS orientation and real-time GNSS meteorology.     

Early contamination of European flounder (Platichthys flesus) by PCDD/Fs and dioxin-like PCBs in European waters

Contamination levels and profiles of 7 polychlorinated-p-dioxins, 10 polychlorinated furans (PCDD/Fs) and 12 dioxin-like polychlorinated biphenyls (dl-PCBs) were investigated in juvenile European flounder (Platichthys flesus) captured in different nursery areas in the northeastern Atlantic coast across its geographical distribution range. The toxic equivalent concentrations (WHO-TEQ_fish) were also determined in order to evaluate which P. flesus population was more exposed to dioxin-like toxicity. Juveniles caught in the Sørfjord (Norway) showed the lowest WHO-TEQ_fish concentration (0.052 pg WHO-TEQ_fish g⁻¹ wet weight) whereas the highest value was observed in fish from the Wadden Sea (The Netherlands; 0.291 pg WHO-TEQ_fish g⁻¹ ww), mainly due to the greater contribution of 2,3,7,8-tetrachlorodibenzo-p-dioxin, the most toxic congener. Nonetheless, when comparing the results with existent tissue residue-based toxicity benchmarks, no adverse effects resulting from PCDD/Fs and dl-PCBs are expected to occur in flounder from the studied systems.     

Investigating the presence of organochlorine pesticides and polychlorinated biphenyls in wild and farmed gilthead sea bream (Sparus aurata) from the Western Mediterranean sea

The presence of organochlorine pesticides and polychlorinated biphenyls in wild and farmed gilthead sea bream (Sparus aurata) from the Western Mediterranean, Spain, is investigated. These pollutants were determined in white and red muscle and liver by gas chromatography coupled to tandem mass spectrometry. Contaminant profiles present in both wild and farmed fish tissues include DDTs, PCBs and HCB. The highest concentrations of contaminants were found in liver, and an increase in pollutant levels was observed in autumn, before spawning. This fact is explained in light of increased food intake when sea water temperatures increase. Gilthead sea bream from Western Mediterranean populations showed significantly higher concentrations of DDTs and PCBs than farmed fish from the same area. This fact is attributed to the low level of organochlorine contaminants present in fish feed supplied to the cultured fish. The diet is highlighted as an important factor in understanding differences observed in organochlorine pollutants levels of fish tissues.     

Model prediction capacity of ephemeral gully evolution in conservation tillage systems

Ephemeral gully (EG) erosion has an important impact on agricultural soil losses and increases field surface hydrology connectivity and transport of pollutants to nearby water bodies. Watershed models including an EG component are scarce and not yet properly evaluated. The objective of this study is to evaluate the capacity of one such tool, AnnAGNPS, to simulate the evolution of two EG formed in a conservation tillage system. The dataset for model testing included runoff measurements and EG morphological characteristics during 3 years. Model evaluation focused on EG evolution of volume, width, and length model outputs, and included calibration and testing phases and a global sensitivity analysis (GSA). While the model did not fully reproduce width and length, the model efficiency to simulate EG volume was satisfactory for both calibration and testing phases, supporting the watershed management objectives of the model. GSA revealed that the most sensitive factors were EG depth, critical shear stress, headcut detachment exponent coefficient b, and headcut detachment leading coefficient a. For EG outputs the model was additive, showing low sensitivity to interactions between the inputs. Prediction of EG spatial evolution on conservation tillage systems requires improved development of gully erosion components, since many of the processes were developed originally for traditional tillage practices or larger channel systems. Our results identify the need for future research when EG form within conservation tillage systems, in particular to study gully headcut, soil erodibility, and width functions specific to these practices.