Soil–Water Characteristic Curves Obtained for a Colluvial and Lateritic Soil Profile Considering the Macro and Micro Porosity

This study aims to determine and to model the relationship of matric suction versus water content, known as soil?Cwater characteristic curve (SWCC), for a tropical soil profile at the southeastern Brazil. This soil profile consists of a colluvial, lateritic silty clay, with thickness of about 6.5?m. The filter paper and pressure plate techniques were used to determine the SWCC. Specimens were trimmed from the undisturbed soil samples collected along soil profile depth and submitted to drying paths. Impregnated thin-layer plates and a petrographic microscope were used to examine the structure and mineralogical composition of the soil samples. Mercury intrusion porosimetry tests were performed on some soil samples to obtain the frequency histogram of the pores. SWCC with bimodal pore-size distribution were obtained by the filter paper technique and SWCC with unimodal pore-size distribution were obtained by the pressure plate technique. The SWCC showed values of air-entry ranging from 1 to 3?kPa, depending on the technique used, resembling soils with macroporosity, as the lateritic soils. Combining both techniques, the SWCC could be fitted by a model that takes into consideration soils with macro and microporosity.     

EVA: GPS-based extended velocity and acceleration determination

In this work, a new GPS carrier phase-based velocity and acceleration determination method is presented that extends the effective range of previous techniques. The method is named ‘EVA’, and may find applications in fields such as airborne gravimetry when rough terrain or water bodies make difficult or impractical to set up nearby GPS reference receivers. The EVA method is similar to methods such as Kennedy (Precise acceleration determination from carrier phase measurements. In: Proceedings of the 15th international technical meeting of the satellite division of the Institute of Navigation. ION GPS 2002, Portland pp 962–972, 2002b) since it uses L1 carrier phase observables for velocity and acceleration determination. However, it introduces a wide network of stations and it is independent of precise clock information because it estimates satellite clock drifts and drift rates ‘on-the-fly’, requiring only orbit data of sufficient quality. Moreover, with EVA the solution rate is only limited by data rate, and not by the available precise satellite clocks data rate. The results obtained are more robust for long baselines than the results obtained with the reference Kennedy method. An advantage of being independent of precise clock information is that, beside IGS Final products, also the Rapid, Ultra-Rapid (observed) and Ultra-Rapid (predicted) products may be used. Moreover, the EVA technique may also use the undifferenced ionosphere-free carrier phase combination (LC), overcoming baseline limitations in cases where ionosphere gradients may be an issue and very low biases are required. During the development of this work, some problems were found in the velocity estimation process of the Kennedy method. The sources of the problems were identified, and an improved version of the Kennedy method was used for this research work. An experiment was performed using a light aircraft flying over the Pyrenees, showing that both EVA and the improved Kennedy methods are able to cope with the dynamics of mountainous flight. A RTK-derived solution was also generated, and when comparing the three methods to a known zero-velocity reference the results yielded similar performance. The EVA and the improved-Kennedy methods outperformed the RTK solutions, and the EVA method provided the best results in this experiment. Finally, both the improved version of the Kennedy method and the EVA method were applied to a network in equatorial South America with baselines of more than 1,770 km, and during local noon. Under this tough scenario, the EVA method showed a clear advantage for all components of velocity and acceleration, yielding better and more robust results.     

The ionosphere: effects,GPS modeling and the benefits for space geodetic techniques

The main goal of this paper is to provide a summary of our current knowledge of the ionosphere as it relates to space geodetic techniques, especially the most informative technology, global navigation satellite systems (GNSS), specifically the fully deployed and operational global positioning system (GPS). As such, the main relevant modeling points are discussed, and the corresponding results of ionospheric monitoring are related, which were mostly computed using GPS data and based on the direct experience of the authors. We address various phenomena such as horizontal and vertical ionospheric morphology in quiet conditions, traveling ionospheric disturbances, solar flares, ionospheric storms and scintillation. Finally, we also tackle the question of how improved knowledge of ionospheric conditions, especially in terms of an accurate understanding of the distribution of free electrons, can improve space geodetic techniques at different levels, such as higher-order ionospheric effects, precise GNSS navigation, single-antenna GNSS orientation and real-time GNSS meteorology.     

Evaluation of heavy metals and arsenic speciation discharged by the industrial activity on the Tinto-Odiel estuary, SW Spain

This study reports the annual amount of heavy metals discharged by industrial activity into the estuary of the Ría of Huelva (SW Spain). The findings showed that the discharged metals found in highest amounts were Fe (11 t y⁻¹), Zn (3.4 t y⁻¹) and Mo (0.88 t y⁻¹). There were other metals with high pollutant charge, such as Ti (232 kg y⁻¹), As (228 kg y⁻¹), Ni (195 kg y⁻¹), Pb (100 kg y⁻¹), Cr (39 kg y⁻¹) and Cd (33 kg y⁻¹). These results were compared with pollutants transported via the Tinto and Odiel rivers from abandoned mining activities in the Iberian Pyrite Belt (IPB), and it was deduced that the amounts spilled exclusively by industries were less than 1% in relation to the total discharge. Hence, the treatment of residues from the IPB should be the priority goal to improve water quality in the estuary.     

Ecological quality assessment of small estuaries from the Portuguese coast based on fish assemblages indices

The importance of establishing the ecological quality of estuarine systems has been widely acknowledged and led to the development of several fish community-based multimetric indices. Nevertheless, a question rose about the accuracy of these tools when natural disturbance is acting upon the organization of the systems’ communities. Four multimetric indices were used to examine their ability to differentiate the ecological status of five small estuarine systems (southern Portugal), and also to test if they reflected the level of anthropogenic pressures. Fish assemblages from Mira, Odeceixe and Aljezur (in the Southwest coast), Gilão and Bensafrim (in the South coast) estuaries were sampled seasonally for one year, and anthropogenic sources of pressure were identified and quantified. We found that although the applied indices provided information on ecological condition differentiation among systems, they are unable to explain different classes of ecological status in systems with equivalent pressure levels.     

Estuarine ecological risk based on hepatic histopathological indices from laboratory and in situ tested fish

Juvenile Senegalese soles were exposed through 28-day laboratory and field (in situ) bioassays to sediments from three sites of the Sado estuary (W Portugal): a reference and two contaminated by metallic and organic contaminants. Fish were surveyed for ten hepatic histopathological alterations divided by four distinct reaction patterns and integrated through the estimation of individual histopathological condition indices. Fish exposed to contaminated sediments sustained more damage, with especial respect to regressive changes like necrosis. However, differences were observed between laboratory- and field-exposed animals, with the latest, for instance, exhibiting more pronounced fatty degeneration and hepatocellular eosinophilic alteration. Also, some lesions in fish exposed to the reference sediment indicate that in both assays unaccounted variables produced experimental background noise, such as hyaline degeneration in laboratory-exposed fish. Still, the field assays yielded results that were found to better reflect the overall levels of contaminants and physico-chemical characteristics of the tested sediments.     

Paleosecular variation and absolute geomagnetic paleointensity records retrieved from the Early Cretaceous Posadas Formation (Misiones,Argentina)

The Early Cretaceous may be considered a key period for understanding the evolution of the Earth’s magnetic field. Some still unsolved problems are related to the mode of paleosecular variation (PSV) of the Earth’s magnetic field before and during the Cretaceous Normal Superchron. We report here a detailed rock-magnetic, paleomagnetic and paleointensity investigation from 28 lava flows (331 standard paleomagnetic cores) collected in the Argentinean part of the Parana Flood Basalts (Formation Posadas) in order to contribute to the study of PSV during the early Cretaceous and to obtain precise Cretaceous paleomagnetic pole positions for stable South America. The average paleofield direction is precisely determined from 26 sites, which show small within-site dispersion and high directional stability. Five sites show evidences for the self-reversal of thermoremanent magnetization. 23 sites yielded normal polarity magnetization and only 3 are reversely magnetized. Moving windows averages were used to analyze the sequential variation of virtual geomagnetic pole’s (VGP) axial positions. Interestingly, the axial average VGP path traces an almost complete cycle around the geographical pole and passes near the location of all previously published Paraná Magmatic Province poles. Both paleomagnetic poles and average VGP paths are significantly different from the pole position suggested by fixed hotspot reconstructions, which may be due to true polar wander or the hotspot motion itself. Only 15 samples from 5 individual basaltic lava flows, yielded acceptable paleointensity estimates. The site mean paleointensities range from 25.2 ± 2.2 to 44.0 ± 2.2 μT. The virtual dipole moments (VDMs) range from 4.8 to 9.9 × 10²² Am². This correspond to a mean value of 7.7 ± 2.1 × 10²² Am² which is 96% of the present day geomagnetic field strength. These intensities agree with the relatively high values already reported for Early Cretaceous, which are consistent with some inferences from computer simulations previously published.     

Evaluating restoration of man‐made slopes: a threshold approach balancing vegetation and rill erosion

The management of reclaimed slopes derived from industrial and civil activities (e.g. surface mining and road construction) requires the development of practical stability analysis approaches that integrate the processes and mechanisms that rule the dynamics of these ubiquitous emerging ecosystems. This work describes a new modelling approach focused on stability analysis of water‐limited reclaimed slopes, where interactive relationships between rill erosion and vegetation regulate ecosystem stability. Our framework reproduces two main groups of possible trends along the temporal evolution of reclaimed slopes: successful trends, characterized by widespread vegetation development and the effective control of rill erosion processes; and gullying trends, characterized by the progressive loss of vegetation and a sharp logistic increase in erosion rates. Furthermore, this analytical approach allows the determination of threshold values for the state variables (i.e. vegetation cover and rill erosion) that drive the system's stability, facilitating the identification of critical situations that require specific human intervention (e.g. revegetation or, in very problematic cases, revegetation combined with rill network destruction) to ensure the long‐term sustainability of the restored ecosystem. The application of our threshold analysis framework in Mediterranean‐dry reclaimed slopes derived from surface coal mining (the Teruel coalfield in central‐eastern Spain) showed a good field‐based performance. Therefore, we believe that this model is a valuable contribution for the management of water‐limited reclaimed systems, including those associated with rill erosion, as it provides a tool for the evaluation of restoration success and can play an important role in decision‐making during ecosystem restoration in severely disturbed landscapes. Copyright © 2011 John Wiley & Sons, Ltd.     

Geology,mineral chemistry and tourmaline B isotopes of the Córrego Bom Sucesso area,southern Serra do Espinhaço,Minas Gerais,Brazil: Implications for Au–Pd–Pt exploration in quartzitic terrain

The Palaeo-Mesoproterozoic metasiliciclastic rocks of the southern Serra do Espinhaço, Minas Gerais, Brazil, are host to historically important alluvial deposits of diamonds and gold. Detrital gold grains often comprise Au–Pd–Pt intermetallic compounds, with low Ag contents, which contain inclusions of tourmaline and titaniferous hematite (up to ~ 6 wt.% TiO₂). The latter minerals connect the alluvial mineralisation to the rutile–hematite–quartz veins and tourmalinisation observed in the quartzitic country rocks of the alluvial gravel. The quartzite (Sopa-Brumadinho Formation of lacustrine to fan-deltaic origin) is affected by pervasive B metasomatism with F-bearing tourmaline replacing the recrystallised quartz fabric. The tourmaline belongs to the alkali group, with Mg/(Mg + Fe) and X/(X + Na) ratios in the ranges from 0.5 to 0.7 and 0.18 to 0.29, respectively, where X represents vacancies in the X site. Boron-isotopic values of tourmaline vary from ~ 1 to − 10.4‰ δ¹¹B. The B-isotope range, in conjunction with the Na–Mg-rich tourmaline composition, and the widespread occurrence of tourmalinite in the Sopa-Brumadinho Formation suggest a derivation from non-marine evaporitic brines. Brines are capable of transporting otherwise immobile Ti and explain, under oxidising conditions, the fractionation of Ag from Pd to precipitate palladiferous gold with extremely high Pd/Ag ratios. Zirconium-in-rutile and Ti-in-quartz temperatures for a variety of hematite-rich veins suggest episodic vein emplacement over a temperature range from around 500 °C to ~ 350 °C. Cross-cutting relationships and episodic vein emplacement indicate a late-Brasiliano age.