Tungsten in ordinary chondrites

In ordinary chondrites tungsten displays both lithophile and siderophile characteristics. Its concentration in the metal phase is positively correlated with petrologic type, and with the distribution coefficientK_D =W in metal/W in silicates plus troilite. The oxidation-reduction reactions involved are temperature-dependent and the recrystallization temperature recorded on the basis of the partition of W between coexisting metal and silicate plus troilite fractions are950° ± 100°C for equilibrated chondrites (types 5 and 6), and800° ± 50°C for type 4, while Shaw (L7) records the highest recrystallization temperature (>1200°C).The different metallic content of the three groups of ordinary chondrites has been attributed to a metal-silicate fractionation process. Such a process appears to have fractionated W and Ir, but not W and Fe as these elements were partly oxidized when the fractionation process took place.     

Siderophile element fractionation in enstatite chondrites

The concentration of 10 to 15 siderophile elements was determined in the magnetic and non-magnetic portions of Abee (E4) and Hvittis (E6). The results indicate that, with the exception of Cu, W and Fe, all elements are strongly concentrated in the metal phase. Unlike ordinary chondrites, the metal phase of Abee and Hvittis consists exclusively of kamacite, which is very homogeneous and shows no systematic variation in composition with grain size.Differences in siderophile element content between Abee and Hvittis can be accounted for exclusively by differences in metal content and composition. These differences reflect different degrees of refractory siderophile loss, metal-silicate fractionation and loss of moderately volatile elements. The Ir/Ni ratio is 25% lower in Abee than in Hvittis, indicating that more Ir (Os, Pt, etc.) was lost from Abee during the refractory element fractionation. Abee and the other E4–5 members have also lost no metal and are not depleted in moderately volatile elements. In Abee the non-refractory elements Fe to Ge are present in CI ratios, and this meteorite has also Ir/Re ratios ?CI.These differences, which are recorded in the composition of the metal phase, make a straightforward genetic relationship between the two enstatite chondrite groups difficult to accept. In particular, the different Ir/Ni ratios, which were established very early in the chemical history of these chondrites, at the time of the refractory element fractionation, force us to conclude that E4–5 and E6 chondrites evolved from two different reservoirs, and that exchange of material among them never occurred. However, members of both groups have similar cosmic ray exposure ages suggesting derivation from the same parent body, which poses some interesting problems.     

Potential effects of global climatic change on the phenology and yield of maize in venezuela

Simulated impacts of global and regional climate change, induced by an enhanced greenhouse effect and by Amazonian deforestation, on the phenology and yield of two grain corn cultivars in Venezuela (CENIAP PB-8 and OBREGON) are reported. Three sites were selected:Turén, Barinas andYaritagua, representing two important agricultural regions in the country. The CERES-Maize model, a mechanistic process-based model, in theDecision Support System for Agrotechnology Transfer (DSSAT) was used for the crop simulations. These simulations assume non-limiting nutrients, no pest damage and no damage from excess water; therefore, the results indicate only the difference between baseline and perturbed climatic conditions, when other conditions remain the same. Four greenhouse-induced global climate change scenarios, covering different sensitivity levels, and one deforestation-induced regional climate change scenario were used. The greenhouse scenarios assume increased air temperature, increased rainfall and decreased incoming solar radiation, as derived from atmospheric GCMs for doubled CO₂ conditions. The deforestation scenarios assume increased air temperature, increased incoming solar radiation and decreased rainfall, as predicted by coupled atmosphere-biosphere models for extensive deforestation of a portion of the Amazon basin. Two baseline climate years for each site were selected, one year with average precipitation and another with lower than average rainfall. Scenarios associated with the greenhouse effect cause a decrease in yield of both cultivars at all three sites, while the deforestation scenarios produce small changes. Sensitivity tests revealed the reasons for these responses. Increasing temperatures, especially daily maximum temperatures, reduce yield by reducing the duration of the phenological phases of both cultivars, as expected from CERES-Maize. The reduction of the duration of the kernel filling phase has the largest effect on yield. Increases of precipitation associated with greenhouse warming have no effects on yield, because these sites already have adequate precipitation; however, the crop model used here does not simulate potential negative effects of excess water, which could have important consequences in terms of soil erosion and nutrient leaching. Increases in solar radiation increased yields, according to the non-saturating light response of the photosynthesis rate of a C₄ plant like corn, compensating for reduced yields from increased temperatures in deforestation scenarios. In the greenhouse scenarios, reduced insolation (due to increased cloud cover) and increased temperatures combine to reduce yields; a combination of temperature increase with a reduction in solar radiation produces fewer and lighter kernels.A report of thePAN-EARTH Project, Venezuela Case Study.     

Datos petrológicos sobre las erupciones basálticas del Bajo Ebro (España)

Bulletin of Volcanology -     

Vanishing Island States and sovereignty

Sea level rise could bring about an event that has not previously been seen in modern history, that of the physical disappearance of some low-lying Island States. The objective of this paper is to examine what are the likely scenarios for some of these islands in the course of the next century, and analyse for each scenario if these Island States could continue to claim an Exclusive Economic Zone or not. Also, it will analyse the possibility that Island States could continue having some sort of status analogous to statehood even if it was to lose all territory. Finally, the idea of a “government-in-exile” will be discussed, where the State could retain its identity waiting for a future re-emergence of the island.     

Analysis of groundwater mining in two carbonate aquifers in Sierra de Estepa (SE Spain) based on hydrodynamic and hydrochemical data

The carbonate aquifers of Lora and Mingo form part of the hydrogeological unit of Sierra de Estepa (SE Spain). By means of time series analysis and a 1D numerical groundwater model, groundwater exploitation was quantified and the mean annual recharge in both systems was estimated (2001–2004). During this period, the Lora and Mingo aquifers received an average groundwater recharge of 0.29 × 10⁶ m³/year and 0.14 × 10⁶ m³/year, respectively, whereas an average of 0.34 × 10⁶ m³/year and 0.21 × 10⁶ m³/year, respectively, was extracted. These conditions led to a conspicuous lowering of the water table in both systems. In addition, the analysis of the evolution of the main hydrogeochemical parameters of the groundwater showed that the increased pumping rates produced an increase in total dissolved solids, and chloride and sodium ions in both aquifers. In the case of the Lora aquifer, the only ion that presented decreased levels was nitrate. The results show that groundwater pumping in both aquifers should not exceed the mean annual recharge of 0.29 × 10⁶ m³/year and 0.14 × 10⁶ m³/year in the Lora and Mingo aquifers, respectively. Nevertheless, it would be advisable to reduce pumping rates to below these values in order to restore piezometric levels and improve groundwater quality for different uses in the future.     

Hurricane flood risk assessment for the Yucatan and Campeche State coastal area

Natural Hazards - In this study, the first ever Sea, Lake, Overland Surges from Hurricanes (SLOSH) grid was built for the Yucatan Peninsula. The SLOSH model was used to simulate storm surges in the...