The Herschel PACS photometer calibration

We present a flux calibration scheme for the PACS chopped point-source photometry observing mode based on the photometry of five stellar standard sources. This mode was used for science observations only early in the mission. Later, it was only used for pointing and flux calibration measurements. Its calibration turns this type of observation into fully validated data products in the Herschel Science Archive. Systematic differences in calibration with regard to the principal photometer observation mode, the scan map, are derived and amount to 5 ? 6 %. An empirical method to calibrate out an apparent response drift during the first 300 Operational Days is presented. The relative photometric calibration accuracy (repeatability) is as good as 1 % in the blue and green band and up to 5 % in the red band. Like for the scan map mode, inconsistencies among the stellar calibration models become visible and amount to 2 % for the five standard stars used. The absolute calibration accuracy is therefore mainly limited by the model uncertainty, which is 5 % for all three bands.     

Spatial and temporal distribution of landlocked Galaxias maculatus and Galaxias platei (Pisces: Galaxiidae) in a lake in the South American Andes

Galaxiids are present in many of the Andean lakes in southern South America. We studied landlocked Galaxias maculatus (Jenyns) and Galaxias platei Steindachner populations in a deep oligotrophic lake (Lake Gutiérrez, Patagonia, Argentina). Their temporal and spatial distribution, intralacustrine movements (horizontal and vertical), and spawning periods were analysed using several sampling techniques (ichthyoplankton net, seine net, gill net, and baited benthic taps). We identified the early life stages of both species based on their morphology and otolith shape. The free embryos of both species migrate to the limnetic zone, where they coexist as larvae, facing the same food availability and probably the same predation risk. Each species then moves on to its own juvenile and adult habitat: the littoral and benthic zone for G. maculatus and only the deeper benthic zone for G. platei. Their adult habitats and part of their spawning periods partly overlap.     

Long-term resilience, bush encroachment patterns and local knowledge in a Northeast African savanna

Bush encroachment is a significant phenomenon in savanna environments as it affects wildlife and local livelihoods by preventing new pasture generation. In this article we present a 2000-year record of vegetation change in the Dara range of the Mago National Park, southwestern Ethiopia, an area inhabited by Mursi agro-pastoralists. We use an interdisciplinary approach to understand whether bush encroachment in this area is a recent event or a transitional state of the savanna and describe the local understanding of encroachment as a species-specific process. The vegetation record was obtained from a fossil hyrax midden, a type of sediment already used in Southern Africa but never before in East Africa. Six encroaching phases, led by Capparaceae and Grewia, were found over the last two millennia. The system proved to be resilient, with alternating open and encroached phases, and showed a non-linear response to environmental change, thereby fitting the control theory hypothesis for hysteresis loops. Determining the thresholds conditioning the system's resilience could help to improve savanna management for both local people and National Park authorities.     

On the initial cluster mass distribution inferred from synthesis models

In this contribution we examine the problem of inferring ages and initial cluster masses from synthesis models at the limit of low-mass clusters (M≤ a few ×10⁴ M_⊙). We show that it is not possible to apply directly synthesis models using standard methods to such clusters, since the basic hypothesis implicit in the models (a fixed proportionality between the number of stars in different evolutionary phases) is not fulfilled due to an insufficient number of stars for a reliable sampling of the stellar initial mass function. The consequence of this incomplete sampling is a non-Gaussian distribution of the mass–luminosity relation for clusters that share the same evolutionary conditions (age, metallicity and stellar initial mass distribution function). We review some tests, that can be performed before the start of the analysis, to estimate if the observed cluster can be analyzed with synthesis models following traditional procedures (like χ ² minimization) or if it is necessary make use of synthesis models in a probabilistic framework. Finally, we show the implications of these results for estimating the low-mass tail in the initial cluster mass distribution function.     

Origin and history of chondrite regolith,fragmental and impact-melt breccias from Spain

Abstract— Six ordinary chondrite breccias from the Museo Nacional de Ciencias Naturales, Madrid (Spain), are described and classified as follows: the solar gas-rich regolith breccia Oviedo (H5); the pre-metamorphic fragmental breccias Cabezo de Mayo (type 6, L-LL), and Sevilla (LL4); the fragmental breccias Cañellas (H4) and Gerona (H5); and the impact melt breccia, Madrid (L6). We confirm that chondrites with typical light-dark structures and petrographic properties typical of regolith breccias may (Oviedo) or may not (Cañellas) be solar gas-rich. Cabezo de Mayo and Sevilla show convincing evidence that they were assembled prior to peak metamorphism and were equilibrated during subsequent reheating. These meteorites contain small melt rock clasts that were incorporated into the host chondrite while still molten and/or plastic and cooled rapidly and, yet, are totally equilibrated with their hosts. Compositions of olivine and low-Ca pyroxene in host chondrite and breccia clasts in Cabezo de Mayo are transitional between groups L and LL. It is suggested, based on mineralogic and oxygen isotopic compositions of host and clasts, that the rock formed on the L parent body by mixing, prior to peak metamorphism. This was followed by partial equilibration of two different materials: the indigenous L chondrite host and exotic LL melt rock clasts.     

High-pressure,low-temperature metamorphism in Alpujarride Units of southeastern Betics (Spain)Métamorphisme de haute pression et basse température dans les unités Alpujarrides du Sud-Est de la cordillère Bétique (Espagne)

We present the first occurrences of high-pressure, low-temperature ferro-magnesiocarpholite-bearing mineral assemblages associated to quartz segregations in the Alpujarride units of southeastern Betics (Sierra de Almagro, Sierra de los Pinos and Sierra Cabrera). Thermobarometric results show that the carpholite-bearing rocks underwent the same P–T conditions in the three outcrops, i.e. 8–10 kbar, 350–400 °C. Metamorphic and structural data allow us to conclude that these rocks belong to the same Alpujarride unit. In the Sierra de Almagro, tectonic units with carpholite-bearing rocks overlie low-pressure, low-temperature Alpujarride units, then forming a stack with an inverted tectono-metamorphic sequence, as observed in the central and western part of the Alpujarride complex. The preservation of carpholite-bearing assemblages in these rocks implies that no significant temperature increase occurred during the exhumation history. To cite this article: G. Booth-Rea et al., C. R. Geoscience 334 (2002) 857–865.     

Chemical characteristics of groundwater around two massive sulphide deposits in an area of previous mining contamination, Iberian Pyrite Belt, Spain

A detailed chemical study of groundwater was carried out to elucidate the processes controlling the oxidation and dissolution of sulphide minerals at two massive sulphide deposits in the Iberian Pyrite Belt (IPB), i.e. the mined La Zarza deposit and the unmined Masa Valverde deposit. It was found that major-element compositions varied according to the hydrological regime, La Zarza being in a relatively high area with groundwater recharge (and disturbance due to the human factor) and Masa Valverde being in a relatively low area with groundwater discharge. The variations mainly concern pH, Eh, SO₄ and Na concentrations. Metal concentrations were determined (a) by ICP-MS after filtration, and (b) in some cases by voltammetric measurement of Cu, Pb, Zn, Cd and Mn using the Voltammetric In situ Profiling (VIP) System, which allows detection of only the mobile fractions of trace elements (i.e., free metal ions and small labile complexes a few nanometers in size). If one compares the results obtained by each of the two methods, it would appear that the groundwater shows significant enhancement of metal solubility through complexing with organic matter and/or adsorption onto colloids and/or small particles. In areas of sulphide oxidation, however, this solubility enhancement decreases according to Cu>Zn>Cd>Pb. Under very low redox conditions, the attained metal concentrations can be several orders of magnitude (up to 10⁸–10⁹ for Cu and 10²–10³ for Pb) larger than those expected from equilibrium with respect to sulphide minerals as calculated with the EQ3NR geochemical code; Zn concentrations, however, are close to equilibrium with respect to sphalerite. The implication of these results is discussed with respect both to mineral exploration and to environmental issues.     

The effect of ionic interaction on the rates of oxidation in natural waters

The effect of ionic interactions on the kinetics of disproportionation of HO₂, and the oxidation of Fe(II) and Cu(I) has been examined. The interactions of O₂ with Mg²⁺ and Ca²⁺ ions in seawater increases the lifetime by 3–5 times compared to water. The effect of OH⁻ on the oxidation of Fe(II) in water and seawater shows a second degree dependence from 5 to 45°C. The effect of salinity on the oxidation of Fe(II) was found to be independent of temperature, while the effect of temperature was found to be independent of salinity. The energy of activation for the overall rate constant was found to be 7 ± 0.5 kcal mol⁻¹.The effect of pH, temperature, salinity and ionic composition on the oxidation of Cu(I) has also been examined. In NaCl solutions from 0.5 to 6 M, the log k for the oxidation was a linear function of pH (6–8) with a slope of 0.2 ± 0.05. The reaction was strongly dependent on the Cl⁻ concentration with variation of from 0.3 to 340 min from 0.5 to 6 M Cl⁻. The rates of oxidation of Cu⁺ and CuCl⁰ responsible for these effects are dependent upon ionic strength. The energy of activation for the reaction was 8.5–9.9 kcal mol⁻¹ from 0.5 to 6 M. Studies of the oxidation in various NaX salts (X = I⁻, Br⁻ and Cl⁻) give rates in the order Cl⁻ > Br⁻ > I⁻ as expected, due to complex formation of Cu⁺ with X⁻.