Nitrogen microanalysis of glass inclusions in chondritic olivines by nuclear reaction

Measured were the abundance and distribution of nitrogen in glasses of glass inclusions in olivines of CV3, CO3, CR, C4, CH3, and LL chondritic meteorites by means of the ¹⁴N(d, p)¹⁵N nuclear reaction. Similar to what was observed with carbon, nitrogen is present in low concentrations (<20 ppm) in the structure of olivines but can by stored in variable amounts in glasses of glass inclusions. These primitive glasses, characterized by a Si-Al-Ca-rich composition, have highly variable nitrogen contents (30 to 1500 ppm) and highly inhomogeneous nitrogen distribution. Nitrogen contents are independent of the chemical composition of the glasses. The heterogeneous distribution is a common feature of all studied inclusions, as is evidenced by the variable contents of nitrogen in glass inclusions occurring in the same olivine grain. Nitrogen heterogeneity is suggestive of trapping of solid nitrogen carrier phases during formation of the constituents of chondrules. However, part of the originally trapped nitrogen appears to have been lost, possibly, by ulterior oxidation and subsequent transformation into volatile species.     

The influence of sampling design on spatial data quality in a geographic citizen science project

Geographic citizen science has much potential to assist in wildlife research and conservation, but the quality of observation data is a key concern. We examined the effects of sampling design on the quality of spatial data collected for a koala citizen science project in Australia. Data were collected from three samples—volunteers (n = 454), an Internet panel (n = 103), and landowners (n = 35)—to assess spatial data quality, a dimension of citizen science projects rarely considered. The locational accuracy of koala observations among the samples was similar when benchmarked against authoritative data (i.e., an expert‐derived koala distribution model), but there were differences in the quantity of data generated. Fewer koala location data were generated per participant by the Internet panel sample than the volunteer or landowner samples. Spatial preferences for land uses affecting koala conservation were also mapped, with landowners more likely to map locations for residential and tourism development and volunteers less likely. These spatial preferences have the potential to influence the social acceptability of future koala conservation proposals. With careful sampling design, both citizen observations and land use preferences can be included within the same project to augment scientific assessments and identify conservation opportunities and constraints.     

The planet formation imager

The Planet Formation Imager (PFI, www.planetformationimager.org) is a next-generation infrared interferometer array with the primary goal of imaging the active phases of planet formation in nearby star forming regions. PFI will be sensitive to warm dust emission using mid-infrared capabilities made possible by precise fringe tracking in the near-infrared. An L/M band combiner will be especially sensitive to thermal emission from young exoplanets (and their disks) with a high spectral resolution mode to probe the kinematics of CO and H₂O gas. In this paper, we give an overview of the main science goals of PFI, define a baseline PFI architecture that can achieve those goals, point at remaining technical challenges, and suggest activities today that will help make the Planet Formation Imager facility a reality.     

The Horizontal Reactive Media Treatment Well (HRX Well®) for Passive In‐Situ Remediation

A new in‐situ remediation concept termed a Horizontal Reactive Media Treatment Well (HRX Well®) is presented that utilizes horizontal wells filled with reactive media to passively treat contaminated groundwater in‐situ. The approach involves the use of large‐diameter directionally drilled horizontal wells filled with granular reactive media generally installed parallel to the direction of groundwater flow. The design leverages natural “flow‐focusing” behavior induced by the high in‐well hydraulic conductivity of the reactive media relative to the aquifer hydraulic conductivity to passively capture and treat proportionally large volumes of groundwater within the well. Clean groundwater then exits the horizontal well along its downgradient sections. Many different types of solid granular reactive media are already available (e.g., zero valent iron, activated carbon, ion exchange resins, zeolite, apatite, chitin); therefore, this concept could be used to address a wide range of contaminants. Three‐dimensional flow and transport simulations were completed to assess the general hydraulic performance, capture zones, residence times, effects of aquifer heterogeneity, and treatment effectiveness of the concept. The results demonstrate that capture and treatment widths of up to tens of feet can be achieved for many aquifer settings, and that reductions in downgradient concentrations and contaminant mass flux are nearly immediate. For a representative example, the predicted treatment zone width for the HRX Well is approximately 27 to 44 feet, and contaminant concentrations immediately downgradient of the HRX Well decreased an order of magnitude within 10 days. A series of laboratory‐scale physical tests (i.e., tank tests) were completed that further demonstrate the concept and confirm model prediction performance. For example, the breakthrough time, peak concentration and total mass recovery of methylene blue (reactive tracer) was about 2, 35, and 20 times (respectively) less than chloride (conservative tracer) at the outlet of the tank‐scale HRX Well.     

Effectiveness of landscape‐based green infrastructure for stormwater management in suburban catchments

Land cover changes associated with urbanization have negative effects on downstream ecosystems. Contemporary urban development attempts to mitigate these effects by designing stormwater infrastructure to mimic predevelopment hydrology, but their performance is highly variable. This study used in situ monitoring of recently built neighbourhoods to evaluate the catchment‐scale effectiveness of landscape decentralized stormwater control measures (SCMs) in the form of street connected vegetated swales for reducing runoff volumes and flow rates relative to curb‐and‐gutter infrastructure. Effectiveness of the SCMs was quantified by monitoring runoff for 8 months at the outlets of 4 suburban catchments (0.76–5.25 ha) in Maryland, USA. Three “grey” catchments installed curb‐and‐gutter stormwater conveyances, whereas the fourth “green” catchment built parcel‐level vegetated swales. The catchment with decentralized SCMs reduced runoff, runoff ratio, and peak runoff compared with the grey infrastructure catchments. In addition, the green catchment delayed runoff, resulting in longer precipitation–runoff lag times. Runoff ratios across the monitoring period were 0.13 at the green catchment and 0.37, 0.35, and 0.18 at the 3 grey catchments. Runoff only commenced after 6 mm of precipitation at the decentralized SCM catchment, whereas runoff occurred even during the smallest events at the grey catchments. However, as precipitation magnitudes reached 20 mm, the green catchment runoff characteristics were similar to those at the grey catchments, which made up 37% of the total precipitation in only 10 of 72 events. Therefore, volume‐based reduction goals for stormwater using decentralized SCMs such as vegetated swales require additional redundant SCMs in a treatment train as source control and/or end‐of‐pipe detention to capture a larger fraction of runoff and more effectively mimic predevelopment hydrology for the relatively rare but larger precipitation events.     

Predominant period and equivalent viscous damping ratio identification for a full‐scale building shake table test

The predominant period and corresponding equivalent viscous damping ratio, also known in various loading codes as effective period and effective damping coefficient, are two important parameters employed in the seismic design of base‐isolated and conventional building structures. Accurate determination of these two parameters can reduce the uncertainty in the computation of lateral displacement demands and interstory drifts for a given seismic design spectrum. This paper estimates these two parameters from data sets recorded from a full‐scale five‐story reinforced concrete building subjected to seismic base excitations of various intensities in base‐isolated and fixed‐base configurations on the outdoor shake table at the University of California, San Diego. The scope of this paper includes all test motions in which the yielding of the reinforcement has not occurred and the response can still be considered ‘elastic’. The data sets are used with three system identification methods to determine the predominant period of response for each of the test configurations. One of the methods also determines the equivalent viscous damping ratio corresponding to the predominant period. It was found that the predominant period of the fixed‐base building lengthened from 0.52 to 1.30 s. This corresponded to a significant reduction in effective system stiffness to about 16% of the original stiffness. The paper then establishes a correlation between predominant period and peak ground velocity. Finally, the predominant periods and equivalent viscous damping ratios recommended by the ASCE 7‐10 loading standard are compared with those determined from the test building. Copyright © 2017 John Wiley & Sons, Ltd.     

Streamflow prediction under extreme data scarcity: a step toward hydrologic process understanding within severely data-limited regions

Streamflow prediction in ungauged basins is necessary to support water resources management decisions. Herein we refine and evaluate the Streamflow Prediction under Extreme Data-scarcity (SPED) model, a framework designed for streamflow prediction within regions of sparse hydrometeorological observation. With the SPED framework, inclusion of soft data directs optimization to balance runoff efficiency with the selection of hydrologically representative parameters. Here SPED is tested in catchments around the world, including four well-gauged catchments, by mimicking data-scarcity and comparing against data-intensive approaches. By differentiating equifinal models, SPED succeeds where traditional approaches are likely to fail: partially dissimilar reference/target catchments. For instance, in a pair of reference/target catchments with different base flow regimes, SPED outperforms a model calibrated only to maximize efficiency (NSE of 0.54 versus 0.08). SPED performs consistently (NSE range: 0.54–0.74) across the diverse climatological and physiographic settings tested and proves comparable to state-of-the-science methods that use robust data networks.     

pH variability off Goa (eastern Arabian Sea) and the response of sea urchin to ocean acidification scenarios

The increasing atmospheric CO₂ concentration in the last few decades has resulted in a decrease in oceanic pH. In this study, we assessed the natural variability of pH in coastal waters off Goa, eastern Arabian Sea. pH_T showed large variability (7.6–8.1) with low pH conditions during south-west monsoon (SWM), and the variability is found to be associated with upwelling rather than freshwater runoff. Considering that marine biota inhabiting dynamic coastal waters off Goa are exposed to such wide range of natural fluctuations of pH, an acidification experiment was carried out. We studied the impact of low pH on the local population of sea urchin Stomopneustes variolaris (Lamarck, 1816). Sea urchins were exposed for 210 days to three treatments of pH_T: 7.96, 7.76 and 7.46. Our results showed that S. variolaris at pH_T 7.96 and 7.76 were not affected, whereas the ones at pH_T 7.46 showed adverse effects after 120 days and 50% mortality by 210 days. However, even after exposure to low pH for 210 days, 50% organisms survived. Under low pH conditions (pH_T 7.46), the elemental composition of sea urchin spines exhibited deposition of excess Sr²⁺ as compared to Mg²⁺ ions. We conclude that although the sea urchins would be affected in future high CO₂ waters, at present they are not at risk even during the south-west monsoon when low pH waters reside on the shelf.     

Advancements in web‐mapping tools for land use and marine spatial planning

Land use and marine spatial planning processes are increasingly supported by systematic assessment techniques, particularly by multi‐criteria spatial analysis methods. This has been facilitated by the growing release and uptake of web‐mapping tools, which contribute to transparent, consistent, and informed planning processes and decisions. This article reviews the usability, functionality, and applicability of contemporary planning web‐mapping tools to identify the state‐of‐the‐art and future prospects. The review reveals that interfaces are increasingly available and intuitively applicable by non‐specialized users. Basic map navigation and data querying functionality is being expanded to incorporate advanced map‐making and online data geoprocessing capabilities that enable deriving new data and insights. However, the majority of published planning web tools are one‐off solutions, and a disconnect between research and practice is rendering many of these inaccessible or obsolete. Despite the significant progress made in advancing their provision in the last decade, there is a need for developing transferable interfaces that are maintained beyond project end dates, for them to effectively and consistently support planning processes.     

Classification comparisons between dual-pol, compact polarimetric and quad-pol SAR imagery

We present a study of the polarimetric information content of dual-pol imaging modes and dual-pol imaging extended by polarimetric scattering models. We compare Wishart classifications both among the partial polarimetric datasets and against the full quad-pol dataset. Our emphasis is the inter-comparisons between the classification results based on dual-pol modes, compact polarimetric modes and scattering model extensions of the compact polarimetric modes. We primarily consider novel dual-pol modes, e.g. transmitting a circular polarization and receiving horizontal and vertical polarizations, and the pseudo-quad-pol data derived from polarimetric scattering models based on dual-pol data. We show that the overall classification accuracy of the pseudo-quad-pol data is essential the same as the classification accuracy obtained directly employing the underlying dual-pol imagery.