Measuring and interpreting heat fluxes from shallow volcanic bodies using vertical temperature profiles: a preliminary test

 To test the potential of heat flux prospecting in active volcanic areas using shallow temperature data taken along vertical profiles, we carried out two thermal profile surveys, one not far from Yasur cone on Tanna Island, and another inside the caldera of Ambrym (New Hebrides arc, southwestern Pacific). The basic steady heat flux of internal volcanic origin was determined, taking into account both conductive and convective heat transfers. At both locations there exists, over small distances, significant differences in the heat flux. These differences correspond to shallow sources of heat. The use of a network of vertical profiles allowed: (a) heat flux mapping; (b) location of shallow volcanic heat sources; and (c) observation of the detailed structure of the heat release at quiescent but active volcanoes. Received: 18 July 1997 / Accepted: 13 May 1998     

Late Mesozoic compressional to extensional tectonics in the Yiwulüshan massif,NE China and their bearing on the Yinshan–Yanshan orogenic belt: Part II: Anisotropy of magnetic susceptibility and gravity modeling

Granitoids play an important role in deciphering both crustal growth and tectonic evolution of Earth. In the eastern end of the Yinshan–Yanshan belt of North China Craton, the Yiwulüshan massif is a typical region that presents the tectonic evolution features of this belt. Our field work on the host rocks has demonstrated two phases of opposite tectonics: compressional and extensional, however, the deformation is almost invisible in the intrusive rocks. To improve the understanding of the tectonic evolution of the Yiwulüshan massif and the Late Mesozoic tectonics of East Asia, a multidisciplinary study has been carried out. In this study, anisotropy of magnetic susceptibility (AMS) and gravity modeling have been applied on these Jurassic plutons (Lüshan, Jishilazi and Guanyindong), which intrude into the Yiwulüshan massif. According to laboratory measurements and microscopic observations on thin sections, the AMS of the Yiwulüshan massif is characterized by secondary fabrics, indicating that the intensive post solidus deformation has reset the (primary) magmatic magnetic fabrics. A relatively gentle NW dipping magnetic foliation has been identified with two distinct groups of magnetic lineations of N34°E and N335°E orientations, namely L_M1 and L_M2, relatively. Gravity modeling reveals a southward thinning of the massif with a possible feeding zone rooted in the northern part of the massif. Integrating all results from structural observation, geochronological investigation, AMS measurement and gravity modeling, two tectonic phases have been identified in the Yiwulüshan massif, posterior to the Jurassic (180–160 Ma) magmatism in the Yinshan–Yanshan area. The early one concerns a Late Jurassic–Early Cretaceous (~ 141 Ma) compressional event with a top-to-the-south to southwest sense of shear. The second one shows an Early Cretaceous (~ 126 Ma) NW–SE ductile extensional shearing. At that time, sedimentary basins widened and Jurassic plutons started to be deformed under post solidus conditions. In fact, the NW–SE trend of the maximum stretching direction is a general feature of East Asian continent during Late Mesozoic.     

Dynamical evolution of NEAs: Close encounters, secular perturbations and resonances

We discuss the main mechanisms affecting the dynamical evolution of Near-Earth Asteroids (NEAs) by analyzing the results of three numerical integrations over 1 Myr of the NEA (4179) Toutatis. In the first integration the only perturbing planet is the Earth. So the evolution is dominated by close encounters and looks like a random walk in semimajor axis and a correlated random walk in eccentricity, keeping almost constant the perihelion distance and the Tisserand invariant. In the second integration Jupiter and Saturn are present instead of the Earth, and the 3/1 (mean motion) and v ₆ (secular) resonances substantially change the eccentricity but not the semimajor axis. The third, most realistic, integration including all the three planets together shows a complex interplay of effects, with close encounters switching the orbit between different resonant states and no approximate conservation of the Tisserand invariant. This shows that simplified 3-body or 4-body models cannot be used to predict the typical evolution patterns and time scales of NEAs, and in particular that resonances provide some fast-track dynamical routes from low-eccentricity to very eccentric, planet-crossing orbits.On leave from the Department of Mathematics, University of Pisa, Via Buonarroti 2, 56127 Pisa, Italy, thanks to the G. Colombo fellowships of the European Space Agency.     

Development of a Darcy-Brinkman model to simulate water flow and tracer transport in a heterogeneous karstic aquifer (Val d’Orléans, France)

Darcy’s law is the equation of reference widely used to model aquifer flows. However, its use to model karstic aquifers functioning with large pores is problematic. The physics occurring within the karstic conduits requires the use of a more representative macroscopic equation. A hydrodynamic model is presented which is adapted to the karstic aquifer of the Val d’Orléans (France) using two flow equations: (1) Darcy’s law, used to describe water flow within the massive limestone, and (2) the Brinkman equation, used to model water flow within the conduits. The flow equations coupled with the transport equation allow the prediction of the karst transfer properties. The model was tested by using six dye tracer tests and compared to a model that uses Darcy’s law to describe the flow in karstic conduits. The simulations show that the conduit permeability ranges from 5?×?10^?6 to 5.5?×?10^?5?m² and the limestone permeability ranges from 8?×?10^?11 to 6?×?10^?10?m². The dispersivity coefficient ranges from 23 to 53 m in the conduits and from 1 to 5 m in the limestone. The results of the simulations carried out using Darcy’s law in the conduits show that the dispersion towards the fractures is underestimated.     

Polycyclic aromatic hydrocarbons (PAHs) in a large South American industrial coastal area (Santos Estuary, Southeastern Brazil): sources and depositional history

Located in southeastern Brazil, the Santos Estuary has the most important industrial and urban population area of South America. Since the 1950's, increased urbanization and industrialization near the estuary margins has caused the degradation of mangroves and has increased the discharge of sewage and industrial effluents. The main objectives of this work were to determine the concentrations and sources of polycyclic aromatic hydrocarbons (PAHs) in sediment cores in order to investigate the input of these substances in the last 50 years. The PAHs analyses indicated multiple sources of these compounds (oil and pyrolitic origin), basically anthropogenic contributions from biomass, coal and fossil fuels combustion. The distribution of PAHs in the cores was associated with the formation and development of Cubat?o industrial complex and the Santos harbour, waste disposal, world oil crisis and the pollution control program, which results in the decrease of organic pollutants input in this area.     

Petrological and experimental evidence for differentiation of water-rich magmas beneath St. Kitts,Lesser Antilles

St. Kitts lies in the northern Lesser Antilles, a subduction-related intraoceanic volcanic arc known for its magmatic diversity and unusually abundant cognate xenoliths. We combine the geochemistry of xenoliths, melt inclusions and lavas with high pressure–temperature experiments to explore magma differentiation processes beneath St. Kitts. Lavas range from basalt to rhyolite, with predominant andesites and basaltic andesites. Xenoliths, dominated by calcic plagioclase and amphibole, typically in reaction relationship with pyroxenes and olivine, can be divided into plutonic and cumulate varieties based on mineral textures and compositions. Cumulate varieties, formed primarily by the accumulation of liquidus phases, comprise ensembles that represent instantaneous solid compositions from one or more magma batches; plutonic varieties have mineralogy and textures consistent with protracted solidification of magmatic mush. Mineral chemistry in lavas and xenoliths is subtly different. For example, plagioclase with unusually high anorthite content (An_≤100) occurs in some plutonic xenoliths, whereas the most calcic plagioclase in cumulate xenoliths and lavas are An₉₇ and An₉₅, respectively. Fluid-saturated, equilibrium crystallisation experiments were performed on a St. Kitts basaltic andesite, with three different fluid compositions (XH₂O = 1.0, 0.66 and 0.33) at 2.4 kbar, 950–1025 °C, and fO₂ = NNO ? 0.6 to NNO + 1.2 log units. Experiments reproduce lava liquid lines of descent and many xenolith assemblages, but fail to match xenolith and lava phenocryst mineral compositions, notably the very An-rich plagioclase. The strong positive correlation between experimentally determined plagioclase-melt Kd_Ca–Na and dissolved H₂O in the melt, together with the occurrence of Al-rich mafic lavas, suggests that parental magmas were water-rich (> 9 wt% H₂O) basaltic andesites that crystallised over a wide pressure range (1.5–6 kbar). Comparison of experimental and natural (lava, xenolith) mafic mineral composition reveals that whereas olivine in lavas is predominantly primocrysts precipitated at low-pressure, pyroxenes and spinel are predominantly xenocrysts formed by disaggregation of plutonic mushes. Overall, St. Kitts xenoliths and lavas testify to mid-crustal differentiation of low-MgO basalt and basaltic andesite magmas within a trans-crustal, magmatic mush system. Lower crustal ultramafic cumulates that relate parental low-MgO basalts to primary, mantle -derived melts are absent on St. Kitts.     

The granite hosted gold deposit of Moulin de Chéni (Saint-Yrieix district,Massif Central,France): petrographic,structural, fluid inclusion and oxygen isotope constraints

The Moulin de Chéni orogenic gold deposit is the only granite-hosted deposit of the Saint-Yrieix district, French Massif Central. It occurs in 338±1.5 Ma-old peraluminous leucogranites and is characterized by intense microfracturing and bleaching of the granite in relation to pervasive sulfide crystallization. Formation of quartz veins and gold deposition occurred in two successive stages: an early mesozonal stage of quartz-sulfide (Fe-As-S) deposition, usually devoid of gold and a late epizonal stage of base metal and gold deposition. Both stages postdate peak metamorphism and granite intrusion. The genesis of the deposit is the result of four successive fluid events: (1) Percolation of aqueous-carbonic metamorphic fluids under an assumed lithostatic regime of 400–450 °C, at a maximum depth of 13 km; (2) Formation of the main quartz lodes with coeval K-alteration and introduction of As and S from aqueous-carbonic fluids percolating along regional faults. Arsenopyrite and pyrite deposition was linked to the alteration of Fe-silicates into K-feldspar and phengite at near-constant iron content in the bulk granite. Temperature was similar to that of the preceding stage, but pressure decreased to 100–50 MPa, suggesting rapid uplift of the basement up to 7.5 km depth; (3) The resulting extensional tectonic leads to the deposition of gold, boulangerite, galena and sphalerite in brecciated arsenopyrite and pyrite from aqueous fluids during a mixing process. Temperature and salinity decrease from 280 to 140 °C and 8.1 wt% eq. NaCl to 1.6 wt% eq. NaCl, respectively; (4) Sealing of the late fault system by barren comb quartz which precipitated from dilute meteoric aqueous fluids (1.6 wt% eq. NaCl to 0.9 wt% eq. NaCl) under hydrostatic conditions at 200–150 °C.Editorial handling: B. Lehmann     

Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.     

Spatial variability and non-linearity of strong ground motion near a fault

We present observations of ground accelerations recorded at a small array close to the fault during the Düzce earthquake and its early aftershocks. The records show the strong spatial variability of ground acceleration over distances of only a few hundred metres. During the main shock, the peak horizontal acceleration values ranged from 0.3 to about 1.0 g at stations distant of 1.5 km only. We attribute this spatial variability to a fault zone site effect as peak ground acceleration steadily increases as the distance to the fault trace decreases. The spectral ratio between the ground motion recorded near the fault and the one outside the fault zone shows a shift of the spectral peak to lower frequencies with increasing peak accelerations. Such an observation suggests a non-linear behaviour of the fault zone due to the strong ground shaking. As much as a 45 per cent reduction in the shear wave velocity is necessary for the observed shifts. The opening of pre-existing cracks throughout the fault zone is the proposed mechanism to account for the observed shear wave reductions. The observation that elastic fault zone properties are soon recovered following episodes of large strains shows that cracks and fissures close rapidly after the strong shaking is over.