Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.     

Geothermobarometry in albite-garnet orthogneisses: A case study from the Gran Paradiso nappe (Western Alps)

The aim of this paper is to estimate syntectonic P-T conditions within albite- and garnet-bearing orthogneisses. These rocks are generally characterized by the assemblage quartz + albite + biotite + phengite + CaFe-garnet + epidote + titanite. Garnet contains up to 55 mole per cent of grossular. K-feldspar is a relict magmatic phase.

P-T conditions are estimated using several independent methods. First, it is shown that exchange reactions based on the Fe---Mg partitioning between garnet and biotite or garnet and phengite cannot be used to estimate temperatures in these rocks, due to the high grossular content of garnet. Second, maximum and minimum pressures are constrained, respectively, by the occurrence of albite instead of jadeite + quartz and by the assemblage phengite + biotite + quartz. Third, phase equilibria in albite- and garnet-bearing metagranites are modelled in the system K₂O---CaO---FeO---Al₂O₃---SiO₂---H₂O. Equilibrium curves are calculated for the observed phase compositions. Uncertainties in P-T estimates mainly result from the choice of appropriate non-ideal solution models for the garnet.

An application is developed for granites from the Gran Paradiso nappe (Western Alps). These granites show an heterogeneous deformation of Alpine age expressed by mylonitic shear zones cutting across weakly deformed domains. Estimated P-T conditions for the synkinematic assemblages are 10–16 kbar at 550±50°C.     

Reducing global GHG emissions by replicating successful sector examples: the ‘good practice policies’ scenario

This article shows the potential impact on global GHG emissions in 2030, if all countries were to implement sectoral climate policies similar to successful examples already implemented elsewhere. This assessment was represented in the IMAGE and GLOBIOM/G4M models by replicating the impact of successful national policies at the sector level in all world regions. The first step was to select successful policies in nine policy areas. In the second step, the impact on the energy and land-use systems or GHG emissions was identified and translated into model parameters, assuming that it would be possible to translate the impacts of the policies to other countries. As a result, projected annual GHG emission levels would be about 50 GtCO₂e by 2030 (2% above 2010 levels), compared to the 60 GtCO₂e in the ‘current policies’ scenario. Most reductions are achieved in the electricity sector through expanding renewable energy, followed by the reduction of fluorinated gases, reducing venting and flaring in oil and gas production, and improving industry efficiency. Materializing the calculated mitigation potential might not be as straightforward given different country priorities, policy preferences and circumstances.

Key policy insights

• Considerable emissions reductions globally would be possible, if a selection of successful policies were replicated and implemented in all countries worldwide.

• This would significantly reduce, but not close, the emissions gap with a 2°C pathway.

• From the selection of successful policies evaluated in this study, those implemented in the sector ‘electricity supply’ have the highest impact on global emissions compared to the ‘current policies’ scenario.

• Replicating the impact of these policies worldwide could lead to emission and energy trends in the renewable electricity, passenger transport, industry (including fluorinated gases) and buildings sector, that are close to those in a 2°C scenario.

• Using successful policies and translating these to policy impact per sector is a more reality-based alternative to most mitigation pathways, which need to make theoretical assumptions on policy cost-effectiveness.

     

Climate benefits of changing diet

Climate change mitigation policies tend to focus on the energy sector, while the livestock sector receives surprisingly little attention, despite the fact that it accounts for 18% of the greenhouse gas emissions and for 80% of total anthropogenic land use. From a dietary perspective, new insights in the adverse health effects of beef and pork have lead to a revision of meat consumption recommendations. Here, we explored the potential impact of dietary changes on achieving ambitious climate stabilization levels. By using an integrated assessment model, we found a global food transition to less meat, or even a complete switch to plant-based protein food to have a dramatic effect on land use. Up to 2,700 Mha of pasture and 100 Mha of cropland could be abandoned, resulting in a large carbon uptake from regrowing vegetation. Additionally, methane and nitrous oxide emission would be reduced substantially. A global transition to a low meat-diet as recommended for health reasons would reduce the mitigation costs to achieve a 450 ppm CO₂-eq. stabilisation target by about 50% in 2050 compared to the reference case. Dietary changes could therefore not only create substantial benefits for human health and global land use, but can also play an important role in future climate change mitigation policies.     

The role of the land use, land use change and forestry sector in achieving Annex I reduction pledges

Annex I Parties may receive credits or debits from Land Use, Land Use Change and Forestry (LULUCF) activities, contributing to achieving individual emission reduction targets. In the Durban climate negotiations, Parties agreed new LULUCF accounting rules for the second commitment period of the Kyoto Protocol (CP2). By using these new rules, this paper presents key differences among Parties at the minimum (assuming no additional action) and potential (assuming additional actions) contribution of the forest-related LULUCF activities in achieving the pledges for 2020. Overall, the potential contribution of LULUCF is relatively modest (up to about 2 % of 1990 emissions) for the EU, the Annex I Parties likely joining the CP2, and for the Annex I Parties that joined the CP1 as a whole. However, for specific Parties, LULUCF can make a substantial contribution to achieving the pledges. For New Zealand, for instance, the potential contribution of future LULUCF credits may equal 33 % of its 1990 emission level. For Australia, the pledges are expressed relative to 2000 emission levels including LULUCF emissions. Given that LULUCF emissions have strongly declined between 1990 and 2000, and a further decline in foreseen by 2020 (based on Australia’s projections), the minimum contribution of LULUCF to meet the Australian pledges appears to be about 19 % and 7 % relative to its 1990 and 2000 emission level, respectively. A further 3 % potential contribution is estimated from additional actions.     

Regional GHG reduction targets based on effort sharing: a comparison of studies

Over 40 studies that analyse future GHG emissions allowances or reduction targets for different regions based on a wide range of effort-sharing approaches and long-term concentration stabilization levels are compared. This updates previous work undertaken for the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Regional reduction targets differ significantly for each effort-sharing approach. For example, in the Organisation for Economic Co-operation and Development (OECD) 1990 region, new proposals that emphasize the equity principles of responsibility, capability, and need, and those based on equal cumulative per capita emissions (carbon budgets), lead to relatively stringent emissions reduction targets. In order to reach a low concentration stabilization level of 450?ppm CO₂e, the allowances under all effort sharing approaches in OECD1990 for 2030 would be approximately half of the emissions of 2010 with a large range, roughly two-thirds in the Economies in Transition (EIT), roughly at the 2010 emissions level or slightly below in Asia, slightly above the 2010 level in the Middle East and Africa and well below the 2010 level in Latin America. For 2050, allowances in OECD1990 and EIT would be a fraction of today's emissions, approximately half of 2010 emission levels in Asia, and possibly less than half of the 2010 level in Latin America.

Policy relevance

The concept of equity and the stringency of future national GHG reduction targets are at the heart of the current debate on the new international climate change agreement to be adopted in 2015. Policy insights gained from an analysis of over 40 studies, which have quantitatively analysed the proposed GHG reduction targets, are presented. It is found that the outcome of effort-sharing approaches is often largely determined by the way the equity principle is implemented and that the distributional impacts of such approaches can be significantly different depending on the criteria used, the stabilization level and shape of the global emissions pathway. However, the current literature only covers a small proportion of the possible allocation approaches. There should thus be an in-depth modelling comparison to ensure consistency and comparability of results and inform decision making regarding the reduction of GHG emissions.     

Ice-Core Study of the Link between Sea-Salt Aerosol,Sea-Ice Cover and Climate in the Antarctic Peninsula Area

Three ice cores and a set of snow pit samples collected on James Ross Island, Antarctic Peninsula, in 1979, 1981 and 1991 have been analyzed for water stable isotope content D or ¹⁸O (isotopic temperature) and major chemical species. A reliable and detailed chronological scale has been established first for the upper 24.5 m of water equivalent (1990–1943) where various data sets can be compared, then extended down to 59.5 m of water equivalent (1847) with the aid of seasonal variations and the sulphate peak reflecting the 1883 Krakatoa volcanic eruption. At James Ross Island, sea-salt aerosol is generally produced by ice-free marine surfaces during the summer months, although some winter sea-salt events have been observed. For the upper part of the core (1990–1943), correlations (positive or negative) were calculated between isotopic temperature, chloride content (a sea-salt indicator), sea-ice extent, regional atmospheric temperature changes and atmospheric circulation. The D and chloride content correlation was then extended back to 1847, making it possible to estimate decadal sea-ice cover fluctuations over the study period. Our findings suggest that ice-core records from James Ross Island reflect the recent warming and sea-ice decrease trends observed in the Antarctic Peninsula area from the mid-1940s.     

Investigating the Halogen Chemistry From High-Latitude Nighttime Stratospheric Measurements of OClO and NO2

Two cases of simultaneous nighttime measurements of NO₂ and OClO in the winter polar stratosphere are analyzed in order to test our present knowledge of halogen chemistry in the presence of high amount of NO₂ at low temperature. Comparisons with Lagrangian model calculations using several hypotheses are performed. First simulations, using the admitted constant rates of chemical reaction, strongly underestimate the measured OClO while the NO₂ profiles are correctly reproduced. If uncertainties in actinic fluxes calculations are taken into account, simulation results do not show a significant reduction of the underestimation. A better agreement can be achieved if the formation of unstable isomers of ClONO₂ and of BrONO₂ occurs in the cold conditions of the polar stratosphere. An approximate value of the branching ratios of the channels leading to ClONO₂ and ClOONO, and to BrONO₂ and BrOONO, necessary to reproduce both OClO and NO₂ is given and discussed.     

Geochemistry of Pliocene/Pleistocene basalts along the Central Anatolian Fault Zone (CAFZ), Turkey

Abstract

Pliocene-Pleistocene volcanism accompanied strike-slip-related transtensional deformation along the K?z?l?rmak fault segment of the Central Anatolian fault zone (CAFZ) in the west of ?ark??la (Sivas-central Turkey). These volcanic rocks are represented by alkali olivine basalts. They can be divided into four different sub-groups on the basis of their Zr, Nb, TiO₂ contents. A primitive mantle-normalized incompatible trace element diagram for four subgroups shows close similarity to typical OIB pattern. Some of the incompatible trace element ratios (Ce/Y, Zr/Nb, La/Ba, La/Nb) are also akin to OIB values. Highly fractionated REE patterns (La/Yb_N=24.7–9.2) with no Eu anomaly are the main features of the alkali basalts and are comparable to alkaline volcanism in continental rift zones. On the basis of Al₂O₃/TiO₂, Nb/Y, Zr/Y Zr/Nb ratios, the geochemical differences among four sub-groups can be explained by variable degrees of partial melting of compositionally similar mantle source. Th/Nb, Th/Y, Nb/Y ratios and the primitive mantle-normalized trace element diagram suggests significant amount of crustal involvement for most of the alkali olivine basalts erupted along the CAFZ. Rupture of the continental lithosphere by strike-slip-related transtensional deformation might have caused decompressional partial melting of the asthenospheric mantle and generating alkali olivine basalts in this region. © 2001 Éditions scientifiques et médicales Elsevier SAS.     

Late Mesozoic compressional to extensional tectonics in the Yiwulüshan massif,NE China and their bearing on the Yinshan–Yanshan orogenic belt: Part II: Anisotropy of magnetic susceptibility and gravity modeling

Granitoids play an important role in deciphering both crustal growth and tectonic evolution of Earth. In the eastern end of the Yinshan–Yanshan belt of North China Craton, the Yiwulüshan massif is a typical region that presents the tectonic evolution features of this belt. Our field work on the host rocks has demonstrated two phases of opposite tectonics: compressional and extensional, however, the deformation is almost invisible in the intrusive rocks. To improve the understanding of the tectonic evolution of the Yiwulüshan massif and the Late Mesozoic tectonics of East Asia, a multidisciplinary study has been carried out. In this study, anisotropy of magnetic susceptibility (AMS) and gravity modeling have been applied on these Jurassic plutons (Lüshan, Jishilazi and Guanyindong), which intrude into the Yiwulüshan massif. According to laboratory measurements and microscopic observations on thin sections, the AMS of the Yiwulüshan massif is characterized by secondary fabrics, indicating that the intensive post solidus deformation has reset the (primary) magmatic magnetic fabrics. A relatively gentle NW dipping magnetic foliation has been identified with two distinct groups of magnetic lineations of N34°E and N335°E orientations, namely L_M1 and L_M2, relatively. Gravity modeling reveals a southward thinning of the massif with a possible feeding zone rooted in the northern part of the massif. Integrating all results from structural observation, geochronological investigation, AMS measurement and gravity modeling, two tectonic phases have been identified in the Yiwulüshan massif, posterior to the Jurassic (180–160 Ma) magmatism in the Yinshan–Yanshan area. The early one concerns a Late Jurassic–Early Cretaceous (~ 141 Ma) compressional event with a top-to-the-south to southwest sense of shear. The second one shows an Early Cretaceous (~ 126 Ma) NW–SE ductile extensional shearing. At that time, sedimentary basins widened and Jurassic plutons started to be deformed under post solidus conditions. In fact, the NW–SE trend of the maximum stretching direction is a general feature of East Asian continent during Late Mesozoic.