Acid leaching of ash and coal: Time dependence and trace element occurrences

The leaching of coal and coal/asphaltite/wood-ashes in sulfuric acid (pH 1.0, 25 °C, S/L, 1:10) was studied as a function of time; acid consumption and extracted metal concentrations are presented. Whole coals consumed acid rapidly during the first few minutes, followed by slow acid consumption. Wood-, lignite-, and asphaltite-ashes consumed acid in two stages, the rapid phase extending < 30 min and the slow phase extended up to 10 days. The rapid phase was dominated by the dissolution of Ca, K and Mg ions for wood-ash, by Ca, Al and Mg ions for lignite-ash and Ca and Mg ions for asphaltite-ash. The sulfur concentration in solution and the concentrations of Ca, Fe, K, Mg, Na, P, Al and Mn in the aqueous phase verified the neutralizing capacity of the untreated ashes as well as the formation of insoluble sulfates in the residues. The slow phase kinetics differed for different fuels and exhibited leaching of several abundant elements—Fe, Al, K, Na and Mn. Trace elements (Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Th, U, V, Zn) sometimes required up to 32 h for maximal extraction from ashes. Suggestions are presented regarding the chemical nature of trace elements in the untreated coals and ashes and suitable residence times for economical industrial processes. We think it possible to combine bacteriological oxidation of sulfidic concentrates of acid leaching from ash of various qualities or even whole coals.     

A non-main-sequence secondary in SY Cancri

Simultaneous spectroscopic and photometric observations of the Z Cam type dwarf nova SY Cancri were used to obtain absolute flux calibrations. A comparison of the photometric calibration with a wide-slit spectrophotometric calibration showed that either method is equally satisfactory. A radial velocity study of the secondary star, made using the far-red Na  i doublet, yielded a semi-amplitude of   K ₂= 127 ± 23 km s⁻¹  . Taking the published value of  86 ± 9 km s⁻¹  for K ₁ gives a mass ratio of   q = M ₂/ M ₁= 0.68 ± 0.14  ; this is very different from the value of  1.13 ± 0.35  quoted in the literature. Using the new lower mass ratio, and constraining the mass of the white dwarf to be within reasonable limits, then leads to a mass for the secondary star that is substantially less than would be expected for its orbital period if it satisfied a main-sequence mass–radius relationship. We find a spectral type of M0 that is consistent with that expected for a main-sequence star of the low mass we have found. However, in order to fill its Roche lobe, the secondary must be significantly larger than a main-sequence star of that mass and spectral type. The secondary is definitely not a normal main-sequence star.     

Effects of peat on the shapes of alluvial channels: examples from the Cumberland Marshes, Saskatchewan, Canada

An avulsion of the lower Saskatchewan River in the 1870s inundated a large segment of peat-covered floodplain that subsequently has become aggraded with a broad (500 km²) belt of alluvium deposited by the redirected flow. Routing of water and sediment discharge through the avulsion-affected area has been accomplished mainly by networks of sandy bedded anastomosed channels that have formed, evolved, and abandoned as the alluvial belt prograded down the floodplain slope. These processes continue today, though at a much-reduced rate. New channels, formed by crevassing and basinward extension of distributaries, are initially small and shallow, with bottom elevations situated within the avulsive alluvium but above the pre-avulsion peat (floodplain) surface. Subsequent enlargement and downcutting of many of these channels eventually uncovers the underlying peat layer whose resistance to erosion exerts significant influence on cross-sectional shape and further channel development. Peat-floored channels tend to have rectangular cross-sections, high ratios of average to maximum depth (D/D_max), and a large range of width-to-depth ratios. If the channel continues to enlarge, the peat layer eventually becomes breached, commonly leading to temporarily irregular cross-sections caused by localized scouring at the breach sites. Eventually, the peat layer is completely eroded from the channel floor by undercutting and slumping, after which channel shape becomes governed mainly by other perimeter characteristics. Channels unaffected by peat, either before the peat layer is encountered during early channel development or after it is entirely removed, tend to have low width/depth ratios and a large range of D/D_max values.     

Cross-Calibration and Long-Term Monitoring of the Microwave Radiometers of ERS, TOPEX, GFO, Jason, and Envisat

The radiometers on board the satellites ERS-1, TOPEX/Poseidon, ERS-2, GFO, Jason-1, and Envisat measure brightness temperatures at two or three different frequencies to determine the total columnal water vapor content and wet tropospheric path delay, a major correction to the altimeter range measurements. In order to asses the long-term stability of the path delay, the radiometers are calibrated against vicarious cold and hot references, against each other, and against several atmospheric models. Four of these radiometers exhibit significant drifts in at least one of the channels, resulting in yet unmodeled errors in path delay of up to 1 mm/year, thus limiting the accuracy at which global sea level rise can be inferred from the altimeter range measurements.     

Revolution or evolution? New Zealand agriculture since 1984

Agriculture was the primary target of moves to deregulate the New Zealand economy in 1984. Within twelve-months all production subsidies had been removed, including those for fertiliser and other inputs, as well as funding for drought relief, floods and other natural weather disasters. Whereas at the start of 1984, subsidies were estimated to represent as much as 33% of farm income, by 2003 this had fallen to less than 2% with most of this spent on agricultural research. The anticipated shift of thousands of people off the land did not appear to occur, and by conventional measures at least New Zealand agriculture in 2003 is a major success story. At the core of the changes imposed on agriculture was a commitment to remove all state or government distortions from the system and to fully expose the agricultural sector to market forces. This included wide-ranging and fundamental changes in the broad institutional context within which agriculture must operate. All this was achieved at great social cost and with a significant impact on the environment. In many respects New Zealand agriculture is now very different from that in 1984. Some sectors, such as dairying, have grown and become increasingly industrialised. On the other hand, sheep farming, particularly for wool has struggled to maintain its market share, while other enterprises have emerged as significant sources of income, including horticulture, viticulture and fruit. It is argued here that the trends evident in New Zealand agriculture since 1984 pre-existed the reform period and that the apparent success of the reforms evident at a national scale have not addressed or removed the fundamental problems which face New Zealand agriculture, just as they do modern agricultural systems elsewhere. This revised version was published online in July 2006 with corrections to the Cover Date.     

Generation of correlated properties in heterogeneous porous media

The spatial distribution of rock properties in porous media, such as permeability and porosity, often is strongly variable. Therefore, these properties usefully may be considered as a random field. However, this variability is correlated frequently on length scales comparable to geological lengths (for example, scales of sand bodies or facies). To solve various engineering problems (for example, in the oil recovery process) numerical models of a porous medium often are used. A need exists then to understand correlated random fields and to generate them over discretized numerical grids. The paper describes the general mathematical methods required to do this, with one particular method (the nearest neighbor model) described in detail. How parameters of the mathematical model may be related to rock property statistics for the nearest neighbor model is shown. The method is described in detail in one, two, and three dimensions. Examples are given of how model parameters may be determined from real data.     

Development of unusual rock weathering features in the Cordillera Blanca,Peru

Mylonite textures in granodiorite boulders are responsible for higher rates of surface denudation of host rocks and the progressive development of unusual rock weathering features, termed weathering posts. These textures are characterized by smaller grain sizes, higher biotite content, and a higher biotite axial ratio in host rocks relative to weathering posts. Elemental concentrations do not show a significant difference between weathering posts and the host rocks in which they are found, and this reflects the absence of a weathering residue on the rock surfaces. Chemical weathering loosens the bonds between mineral grains through the expansion of biotite, and the loosened grains fall off or are blown off the boulder surface and continue their chemical alteration in the surrounding soil. The height of weathering posts on late Quaternary moraines increases at a linear rate of ~ 1.45 ± 0.45 cm (1000 yr)^? 1 until post heights reach the diameter of host rocks. Such a rate of boulder denudation, if unrecognized, would generate significant errors (> 20%) in cosmogenic exposure ages for Pleistocene moraines. Given the paucity of boulders with diameters that significantly exceed 1.5 m, the maximum age of utility of weathering posts as a numeric age indicator is ~ 100 ka.