Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.     

Evolutionary Processes in Low-Mass Binary Systems

We consider the evolution of certain low-mass binaries, incorporating models of (a) internal evolution, (b) tidal friction, (c) dynamo activity driven by an elementary α,Ω dynamo, (d) stellar wind driven by the activity, and (e) magnetic braking as a consequence of wind and poloidal dynamo-generated magnetic field. In some circumstances the stellar wind is found to remove mass on a nuclear timescale, as is necessary to explain some observed systems. We can hope that various uncertainties in the model may be clarified by a careful comparison of the models with such observed quantities as rotation periods. These are modified by processes (a), (b) and (e). Assuming that stellar evolution is slow, rotation rate should in some circumstances represent a balance between magnetic braking trying to slow the star down and tidal friction trying to spin it up. Preliminary attempts are promising, but indicate that some fine tuning is necessary. When there is a third body present, in an orbit which is inclined but not necessarily of short period, the eccentricity of a close binary can be strongly modified by ‘Kozai cycles’. We show that this may complicate attempts to account for spin rates of stars in close binaries.     

2060 Chiron back to a minimum of brightness

The results of photometric observations of comet/asteroid 2060 Chiron at the Observatório do Pico dos Dias (Brazil-OPD) and the Observatoire de Haute-Provence (France-OHP) during 1994 and 1995 are presented. The analysis of the data shows a decrease of 2060 Chiron brightness from its peak values of 1988–1991. The absolute magnitude, H_v, varies from a maximum of 6.6 in February 1994 up to a minimum of 6.8 in June 1995. Therefore 2060 Chiron is back to a minimum of activity close to that of 1983–1985. The slope parameter G is found to be G = 0.71 ± 0.15. It is suggested that the H-G magnitude system, generally adopted to present 2060 Chiron brightness, is not the most appropriate due to the cometary activity of this object.     

Mass loss from Wolf-Rayet stars

The observed times of minimum light derived from the photometry of the Wolf-Rayet eclipsing binary stars CQ Cep and V444 Cyg are used to estimate the mass-loss rate of the Wolf-Rayet components in several modes of mass-loss and mass-exchange.     

measurement of noise power spectrum in photon counting PMT's and the effect of the observed (1/f) noise on astronomical photometry

In astronomical photometry, the sensitivity of observations is limited by the dark counts of the photomultiplier tube. In the present work, the effect of dark count noise in photon counting systems is investigated by theory and experimental measurements. Dark counts are considered to be originating from two sources, namely: dc fluctuations and random pulses.Experimental measurements were carried out to determine noise effects in different operating regions of noise dominance. The results provide strong evidence that: in normal operating mode, where the effect of random pulses is dominant, dark counts do not follow Poisson statistics. The observed noise shows strong (1/f) power spectrum, where the observed noise power is found to increase with time of observation.The results are important in photon counting systems operating under dark count limited mode. The conclusions drawn can be useful in obtaining more accurate error estimates and in assessing astronomical photometric observations and data reduction techniques.     

PREDICTING MARTIAN AND VENUSIAN METEOR SHOWER ACTIVITY

Based on the number of planet-approaching cometary orbits at Mars and Venus relative to the Earth, there should be ample opportunities for observing meteor activity at those two planets. The ratio of planet-approaching Jupiter family comets (JFCs) at Mars, Earth, and Venus is 4:2:1 indicating that JFC-related outbursts would be more frequent at Mars than the Earth. The relative numbers of planet-approaching Halley-type comets (HTCs) implies that the respective levels of annual meteor activity at those three planets are similar. We identify several instances where near-comet outbursts (Jenniskens, P.: 1995, Astron. Astrophys. 295, 206–235) may occur. A possible double outburst of this type at Venus related to 45P/Honda-Mrkos-Padjusakova may be observable by the ESA Venus Express spacecraft in the summer of 2006. Similarly, the Japanese Planet-C Venus orbiter may observe an outburst related to 27P/Crommelin’s perihelion passage in July 2011. Several additional opportunities exist to observe such outbursts at Mars from 2019 to 2026 associated with comets 38P/Stephan-Oterma, 13P/Olbers and 114P/Wiseman-Skiff.     

A measurement of the 362 GHz absorption line of Mars atmospheric H2O2

The 362.156 GHz absorption spectrum of H₂O₂ in the Mars atmosphere was observed on September 4 of 2003, employing the James Clerk Maxwell Telescope (JCMT) sub-millimeter facility on Mauna Kea, Hawaii. Radiative transfer analysis of this line absorption yields an average volume mixing ratio of 18±0.4 ppbv within the lower (0-30 km) Mars atmosphere, in general accordance with standard photochemical models (e.g., Nair et al., 1994, Icarus 111, 124-150). Our derived H₂O₂ abundance is roughly three times greater than the upper limit retrieved by Encrenaz et al. (2002, Astron. Astrophys. 396, 1037-1044) from infrared spectroscopy, although part of this discrepancy may result from the different solar longitudes (L_s) of observation. Aphelion-to-perihelion thermal forcing of the global Mars hygropause generates substantial (>200%) increases in HO_x abundances above ∼10 km altitudes between the L_s=112° period of the Encrenaz et al. upper limit measurement and the current L_s=250° period of detection (Clancy and Nair, 1996, J. Geophys. Res. 101, 12785-12590). The observed H₂O₂ line absorption weakens arguments for non-standard homogeneous (Encrenaz et al., 2002, Astron. Astrophys. 396, 1037-1044) or heterogeneous (Krasnopolsky, 2003a, J. Geophys. Res. 108; 2003b, Icarus 165, 315-325) chemistry, which have been advocated partly on the basis of infrared (8 μm) non-detections for Mars H₂O₂. Observation of Mars H₂O₂ also represents the first measurement of a key catalytic specie in a planetary atmosphere other than our own.