Sample treatment with focused ultrasound and bath sonication as a powerful tool for the evaluation of cadmium pollution in estuarine waters

A new sample treatment was developed for the determination of dissolved cadmium in Tagus estuarine waters, based on focused ultrasound in conjunction with small volumes in the extraction steps for Cd pre-concentration. Cadmium was first pre-concentrated using a classical approach (APDC as the complexing agent and MIBK as the organic phase) and then back-extracted into HNO₃ with the aid of focused ultrasound, which reduced the acid concentration by more than one order of magnitude (from 4 to 0.1 mol L^− 3). This sample treatment was accomplished in less than 5 min, using low sample volume (20 mL), and low-volume, low-concentration reagents. The pre-concentration factor used in this work was 25, but different sample/organic volume ratios may be used in order to increase that value. The limit of detection and the limit of quantification in Tagus water samples were 0.03 nmol L^− 1 and 0.1 nmol L^− 3, respectively. Recoveries from spiked Tagus water were higher than 90%. The procedure was validated using the reference estuarine water NRC-SLEW-3. In the solubilization of Cd particulate, bath ultrasonication was used in conjunction with HNO₃ + HCl, followed by H₂O₂, which took about 2 instead of the usual 12 h (cooling included) when high-pressure microwave digestion is used.     

Suspended sediment concentration in a buoyant plume: Fraser River,Canada

A study of suspended sediment concentration in the buoyant plume of the Fraser River, Canada, showed that unstratified flow conditions at the river mouth caused resuspension of sandy bed material and high concentrations of coarse sediment. When flow at the mouth was stratified, sediment was fine-grained and concentrations were low. Application of a multivariate model revealed that suspended sediment concentration along the plume axis was controlled primarily by distance seaward of the river mouth, secondly by tidal height, and least by sediment concentration in the river.     

A technique for conducting seismic refraction experiments on the ocean bed using bottom shots

A technique has been devised for firing arrays of bottom shots on the ocean bed in depths upto 4000 m or more. Ten kilogram explosive charges are dropped from the surface while the shooting ship is navigated acoustically. They are detonated at preset times by an electronic timer which initiates an electrical detonator, detonating cord and cast PETN/TNT explosive. Ranges to ocean bottom seismographs, and the shot instants, can be calculated from the arrival-time differences of the direct and surface-reflected water waves. The accuracy, which is dependent on water-depth and range, was better than 22 m in range and 14 msec in shot instant for our experiments.     

Wave group statistics from numerical simulations of a random sea

Two commonly used methods of simulating random time series, given a target power spectrum, are discussed. Wave group statistics, such as the mean length of runs of high waves, produced by the different simulation schemes are compared. The target spectra used are obtained from ocean measurements, and cover a wide range of ocean conditions. For a sufficiently large number of spectral components, no significant differences are found in the wave group statistics produced by the two simulation techniques.     

Prediction of wave height based on half-cycle excursion analysis

This paper presents a method to evaluate statistical properties of half-cycle excursions including extreme values. The probability density function for half-cycle excursions for an arbitrarily given wave spectrum is developed based on the Gaussian assumption. The results of numerical computations carried out using wave data obtained during hurricane Camille show that the half-cycle probability density function agrees well with the histogram constructed from the data. The extreme wave height for design consideration computed with risk parameter 0.01 is approximately 20% greater than the observed extreme height.     

A nomogram method for predicting the movement of oil slicks

In order to obtain quick initial guidance on a first estimation of motion of the spilled oil, a simple manual procedure incorporating advection and spreading processes has been devised. This procedure involves the utilization of a nomogram based on simplified equations. Spill displacements throughout a given forecast period can be easily read from the nomogram. The technique is demonstrated with a real spill case.     

A new concept of a hull form to improve wave response characteristics for marine construction barges

The object of the new hull form is to provide a single hull which possesses long natural periods of roll and heave and has substantially reduced motion response amplitudes in very high sea states. Model tests and preliminary estimates indicated that the new hull form can be designed for roll and heave motions nearly equivalent to those of much larger semisubmersible units.All existing conventional marine construction barges have rectangular cross section hull. The new hull form consists of a system of upper side tanks and lower side tanks added onto a rectangular cross section hull. The upper tanks and lower tanks form longitudinal troughs on the port and starboard sides. Structural grillage of any open type is to connect the upper and lower tanks at the side of the vessel. Figure 1 indicates a profile and a typical transverse section of the new hull form. The new hull comprises the concept of reduced water plane area which is turn results in low transverse metacentric height and low tons per in. immersion. The novel features of combining low GM_T and low TPI with extremely heavy damping and added mass of the entrained water characteristics result in very long natural periods of roll and heave and considerably small rolling and heaving amplitudes in high sea states. The open side shell plating on the side of the vessel functions to dissipate wave energy at the side of the vessel which would have otherwise been transmitted to the vessel and caused the vessel to respond. This paper presents the conceptual foundation and outline of the new hull form. Model test results are presented and implemented. Also presented is the design philosophy.