Fluxes of organic carbon in Manukau Harbour, New Zealand

We collated information on the sources and sinks of organic carbon in Manukau Harbour, a shallow temperate estuary. Two contrasting inner harbor regions were considered; the northern region, which is urbanized and receives a major load of sewage wastewater, and the southern region, where allochthonous inputs are dominated by the runoff from small rural streams. Although high levels of dissolved nitrogen in the wastewater supported phytoplankton blooms in the northern region, total primary production there was similar to that in the southern region (ca. 300 g C m^?2yr^?1). By contrast, high concentrations of organic carbon in the wastewater resulted in an additional input to the northern region of 120 g C m^?2 yr^?1. Loads from runoff and streams to both regions were low. At 350 g C m^?2 yr^?1, total respiration in the northern region exceeded total production, so the region was slightly heterotrophic. Respiration was lower in the southern region (270 g C m^?2 yr^?1), which was net autotrophic. Some carbon was exported from each region to the outer harbour (50–80 g C m^?2 yr^?1). Dissolved oxygen levels in the northern region were somewhat depleted at times; and the high numbers of microzooplankton indicated consumption was enhanced there. Apart from a relatively small area of organic enrichment close to the wastewater discharge, benthic consumers in the harbor appeared to be limited by physical disturbance (by wind-waves) rather than by food availability. Improved wastewater treatment is expected to substantially reduce the allochthonous input to the northern region, with the total input of carbon in the future being only slightly higher than that to the southern region.     

The complex one-sided integrals of Cauchy and Hadamard and application to boundary element method

The definitions of complex integrals of Cauchy and Hadamard with the singular point coinciding with the end point of the integration curve are proposed. It is shown that the new integrals satisfy most of the properties of the regular ones, including the change of variables. It is also shown that the Cauchy principal value (CPV) and Hadamard finite-part (HFP) integrals can be considered as a sum of the new type integrals. The application to numerical solution by the boundary element method (BEM) and the complex hypersingular integral equation (CHSIE) for the multiregions of interacting elastic bodies and bodies with cracks and holes is discussed. The different ways to place the collocation points are considered. The numerical results for the problems of circular hole and circular elastic inclusion in infinite plate indicated that the appropriate choice of the approximating functions leads to a high accuracy of the calculation. Applications of the new technique to geomechanics problems are discussed. © 1998 John Wiley & Sons, Ltd.     

A macroscopic damage‐plastic constitutive law for modeling quasi‐brittle fracture and ductile behavior of concrete

A new phenomenological macroscopic constitutive model for the numerical simulation of quasi‐brittle fracture and ductile concrete behavior, under general triaxial stress conditions, is presented. The model is particularly addressed to simulate a wide range of confinement stress states, as also, to capture the strong influence of the mean stress value in the concrete failure mechanisms. The model is based on a two‐surface damage‐plastic formulation. The mechanical behavior in different domains of the stress space is separately described by means of a quasi‐brittle or ductile material response:

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Artificial neural networks and nonlinear regression techniques to assess the influence of slake durability cycles on the prediction of uniaxial compressive strength and modulus of elasticity for carbonate rocks

Understanding rock material characterizations and solving relevant problems are quite difficult tasks because of their complex behavior, which sometimes cannot be identified without intelligent, numerical, and analytical approaches. Because of that, some prediction techniques, like artificial neural networks (ANN) and nonlinear regression techniques, can be utilized to solve those problems. The purpose of this study is to examine the effects of the cycling integer of slake durability index test on intact rock behavior and estimate some rock properties, such as uniaxial compressive strength (UCS) and modulus of elasticity (E) from known rock index parameters using ANN and various regression techniques. Further, new performance index (PI) and degree of consistency (Cd) are introduced to examine the accuracy of generated models. For these purposes, intact rock dataset is established by performing rock tests including uniaxial compressive strength, modulus of elasticity, Schmidt hammer, effective porosity, dry unit weight, p‐wave velocity, and slake durability index tests on selected carbonate rocks. Afterward, the models are developed using ANN and nonlinear regression techniques. The concluding remark given is that four‐cycle slake durability index (I_d4) provides more accurate results to evaluate material characterization of carbonate rocks, and it is one of the reliable input variables to estimate UCS and E of carbonate rocks; introduced performance indices, both PI and Cd, may be accepted as good indicators to assess the accuracy of the complex models, and further, the ANN models have more prediction capability than the regression techniques to estimate relevant rock properties. Copyright © 2011 John Wiley & Sons, Ltd.     

Age of the Ust’-Gilyui sequence in the Stanovoi Complex of the Selenga-Stanovoi Superterrain, Central Asian fold belt

According to the results of U-Pb geochronological investigations, the age of the amphibolite protoliths (metabasalts) in the Ust??-Gilyui sequence within the Stanovoi Complex of the Amazar-Gilyui structural and formational zone in the Selenga-Stanovoi Superterrain of the Central Asian fold belt can be estimated at 193 ± 1 Ma. The Nd model age of the Ust??-Gilyui metasedimentary rocks is in the interval of t _Nd(DM) = 1.1?C3.1 Ga. This information along with the previously obtained geochronological data are indicative of the fact that the Ust??-Gilyui sequence consists of metasedimentary and metavolcanic rocks of various ages: (1) volcanic rocks with the age of 193 ± 1 Ma; (2) metasedimentary and metavolcanic rocks broken through by the Paleozoic granitoids dated to 370 Ma and characterized by minimum estimations of t _Nd(DM) = 1.1 Ga, i.e., rocks with an age of 1.1?C0.4 Ga. In addition, it is quite possible that this sequence also includes more ancient rocks. The SSS Amazar-Gilyui structural and formational zone is likely to be a tectonic mélange composed of the metasedimentary and metavolcanic rocks of the Mesozoic and, probably, Paleozoic and Early Precambrian ages. The studied zone was formed in the Mesozoic, most likely, in the course of the collision processes initiated by the closing up of the Mongol-Okhotsk Ocean.     

Magnetic-field variations and solar flare activity

Solar filtergrams obtained at the Crimean Astrophysical Observatory at the center and wings of the H?? line are used to study variations in filaments, in particular, in arch filament systems (AFSs). These are considered as an indicator of emerging new magnetic flux, providing information about the spatial locations of magnetic-field elements. Magnetic-field maps for the active region NOAA 10030 are analyzed as an example. A method developed earlier for detecting elements of emerging flux using SOHO/MDI magnetograms indicates a close link between the increase in flare activity in theNOAA 10030 group during July 14?C18, 2002 and variations in the topological disconnectedness of the magnetograms. Moreover, variations in the flare activity one day before a flare event are correlated with variations in the topological complexity of the field (the Euler characteristic) in regions with high field strengths (more than 700 G). Analysis of multi-wavelength polarization observations on the RATAN-600 radio telescope during July 13?C17, 2002 indicate dominance of the radio emission above the central spot associated with the increase in flare activity. In addition to the flare site near the large spot in the group, numerous weak flares developed along an extended local neutral line, far from the central line of the large-scale field. The statistical characteristics of the magnetic-field maps analyzed were determined, and show flare activity of both types, i.e., localized in spot penumbras and above the neutral line of the field.     

A study of the net flux of nitrates from estuaries of the eThekwini Municipality of Durban, KwaZulu-Natal, South Africa

Estuaries, the interface of interaction of fluvial discharge and marine action serve as temporary repositories of materials (solid and dissolved) before finally exporting them to sea. This interchange of material is dependant on a range of factors such as those due to tidal variation, fluvial flows and estuarine morphodynamics. The efficacy of transfer of materials to the marine environment is important for estuarine health particularly in estuaries located in highly developed areas such as the major coastal metropolitan areas of many countries. This study assesses this efficacy for three estuaries of the eThekwini Municipality (TM) of the city of Durban, South Africa which maintains an open mouth status, ensuring tidal exchange through the year. The net flux of nitrates was measured for these estuaries on a seasonal basis for both spring and neap tides. Results indicate that although there is a net export of nitrates to the nearshore, there were instances, particularly on the spring tide, when a net import of nitrates into the estuary occurred. Data analysis reveal summer and neap tide flux dominance for the Tongati and Mgeni estuaries whilst the Isipingo Estuary exhibited larger flux variance for spring tides and the spring season. The origin of the latter is likely derived from unusually high biotic decomposition at sea and/or the longshore transport of decomposing sewage outfall. This creates an added dimension for consideration in estuarine management plans. Taking all three estuaries studied into consideration, a net export of nitrates for all seasons for the TM was measured with a clear seasonal influence detected where high rainfall seasons led to greater export as a consequence of greater fluvial flows, erosion and leaching of agricultural lands and, longer ebb duration and flows.     

Risk of water pollution due to ash–sludge mixtures: column trials

The purpose of this work was to study the risks of water pollution due to the use of mixtures containing wood ash and sewage sludge. Mixtures including sludge and ash may be recycled as fertilizers, and they are economical as they do not integrate commercial limes, but Escherichia coli counts may keep significantly high in such mixtures, because their pH is not alkaline enough. In view of that, it seems interesting to study the E. coli survival in lixiviate from ash?Csludge mixtures including limes rather than from ash?Csludge mixtures alone. Two kinds of experiments were performed using laboratory column trials under saturated flow conditions. The first experiment investigated the chemical leaching behaviour of a mixture of 70% timber-industry wood ashes and 30% urban sewage sludge (% dry weight) at doses equivalent to 10 and 30?Mg/ha. The second experiment studied the survival of E. coli in lixiviates generated from 30?Mg/ha of a mixture consisting in 75% wood ash, 20% sewage sludge and 5% quicklime (% dry weight). In the first experiment, admixture of the ash and sludge achieved a stabilization of elements such as aluminium, iron, magnesium, nickle, carbon monoxide, cadmium, chromium and molybdenum that reduced their solubility compared with that in the ash or sludge alone. Significant solubilisation of heavy metals was not observed, with overall minor risk of chemical water pollution. In the second experiment, although including quicklime E. coli counts were still detected in the lixiviate, indicating risk of water contamination.