Antimony adsorption on kaolinite in the presence of competitive anions

Antimony (Sb) emissions to the environment are increasing, and there is a dearth of knowledge regarding Sb fate and behavior in natural systems. In natural systems, the presence of competitive anions may compete with Sb for adsorption sites on mineral surfaces, hence increasing its potential bioavailability. Accordingly, the adsorption of Sb(III) on kaolinite was investigated in the presence of competitive anions. Kinetic studies suggest that adsorption reaction of Sb(III) on kaolinite is rapid initially and becoming slow after 12 h both in binary Sb(III)–kaolinite system and in ternary Sb(III)-competitive anion–kaolinite system. The presence of PO₄ ^3? has a much stronger and more obvious promotive effect on the adsorption of Sb(III) on kaolinite compared with the other two anions. The adsorption data of Sb(III) on kaolinite in the absence and presence of competitive anions at three temperatures were successfully modeled using Langmuir (r ² > 0.95) and Freundlich (r ² > 0.95) isotherms. Accompanied the adsorption of Sb(III) on kaolinite, significant oxidation of Sb(III) to Sb(V) had occurred under the experimental conditions used in this study. The presence of kaolinite which has a larger specific surface area could increase the contact area between the adsorbed Sb(III) and oxygen in the bulk solution, which promoted the oxidation rate of Sb(III) to Sb(V).     

Hydrogeochemical balance of forest umbrisol profiles (‘Sierra de Gata’, central western Spain)

Three techniques for obtaining soil water solutions (gravitational and matrical waters extracted using both in situ tension lysimeters and in vitro pressure chambers) and their later chemical analysis were performed in order to know the evolution of the soil‐solution composition when water moves down through the soil, from the Ah soil horizon to the BwC‐ or C‐horizons of forest soils located in western Spain. Additionally, ion concentrations and water volumes of input waters to soil (canopy washout) and exported waters (drainage solutions from C‐horizons) were determined to establish the net balance of solutes in order to determine the rates of leaching or retention of ions. A generalized process of sorption or retention of most components (even Cl^?) was observed, from the soil surface to the C‐horizon, in both gravitational and matrical waters, with H₄SiO₄, Mn²⁺, Na⁺, and SO₄^2? being the net exported components from the soil through the groundwater. These results enhance the role of the recycling effect in these forest soils. The net percentages of elements retained in these forest soils, considering the inputs and the outputs balance, were 68% K⁺, 85% Ca²⁺, 58% Mg²⁺, 7% Al³⁺, 5% Fe³⁺, 34% Zn²⁺, 57% Cl^?, and 20% NO₃^?, and about 75% of dissolved organic carbon was mineralized. Copyright © 2007 John Wiley & Sons, Ltd.     

土坡稳定性的极限分析方法

本文应用塑性力学中的极限分析法原理，建立了滑动面为折线时的土坡稳定性极限分析公式。通过工程实例证明，该公式具有使用简便、可靠性强等优点。它对于评价斜坡的稳定性，合理地进行滑坡治理等，都具有实际意义。     

Potential changes in extremes and links with the Southern Annular Mode as simulated by a multi-model ensemble

We assess the likely changes in climate extremes under enhanced greenhouse gases over the southern extratropics, with emphasis in southern South America and sub-Antarctic seas, through the analysis of extreme indices measured from models participating in the IPCC 4th Assessment Report. We discuss how the anthropogenic climate change under A1B scenario influences both the patterns of mean change of extreme indices and the likelihood of occurrence of severe extreme indices. The likelihood of occurrence of a year with a large number of days with “warm” minimum temperatures is estimated to increase by a factor of 4 by the end of this century over most of the southern extratropics. By that time, the risk of “severe” precipitation intensity is projected to rise in most areas with the exception of the subtropical anticyclones, which experience particularly strong drying. Over the Southern Ocean this likelihood has increased to over 60%. Corresponding estimates of the changing likelihood for very long dry spells show a banded structure with positive ratios to the north of about 50° S and negative ratios in the sub Antarctic seas. In southern South America this risk about doubled between present and future climates. Then, we explore if the Southern Annular Mode influences the occurrence of severe extreme indices during the period 2070–2099. Its positive phase inhibits the extremely warm minimum temperatures in the Southern Ocean, with the exception of the eastern Bellingshausen Sea, and favors severe frost days to the north of the Ross Sea. Temperature indices show very little change induced by the SAM to the north of 50° S. Severe dry spells are inhibited during the positive phase along the sub Antarctic seas, while the mid-latitudes, including most of Patagonia, show the opposite behaviour. The Southern Ocean reveals a non-uniform distribution with both increases and decreases in the occurrence of heavier precipitation during positive SAM.     

萃取法制取磷酸二氢钾工艺研究

本文研究改进了萃取法制取磷酸二氢钾的工艺路线,确定了较适宜的工艺条件,萃取在常温下进行,一次反应得到磷酸二氢钾。产品纯度高,能耗低,有望成为大规模工业生产该产品最经济的路线之一。     

两种珍稀鱼类的形态学和生态学的补充研究

通过形态学比较研究和饲养生态学的观察,作者补充了细刺鱼牙齿结构特征和条石鲷的体色、鳍色的形态学特点,探讨了这两种鱼类的生态习性和１９９８ 年在青岛海域出现的原因。进行２～３ 个月的饲养实验后,得到细刺鱼月均增长量为１０．３％ ,条石鲷为１４．６％ 而明显高于同池饲养六线鱼的结果。鉴于两种鱼类彩色艳丽、游姿优美,具观赏价值,为此建议可将这两种鱼作为海水养殖或观赏鱼类的实验对象     

Ulvöspinel from xenoliths of contact-altered volcanic and volcanosedimentary rocks in nepheline syenites of the Khibiny and Lovozero plutons

Ulvöspinel is a typical accessory mineral of xenoliths of volcanic and volcanosedimentary rocks in alkaline syenites of the Khibiny and Lovozero plutons. Ulvöspinel forms homogeneous Cr- and V-rich grains in slightly altered olivine basalts, basaltic tuffs, and tuffites and is enriched in Mn and Si in the course of contact-metasomatic alteration of these rocks. The strongly reduced conditions of contact metamorphism controlled by ascending flows of hydrocarbon gases and hydrogen sulfide gave rise to the subsolidus decomposition of primary ulvöspinel and Ti-high magnetite with the formation of ilmenite lamellae and then, with decreasing redox potential, of the second-generation latticed ulvöspinel lamellae.     

Evidence for Century-Timescale Acceleration in Mean Sea Levels and for Recent Changes in Extreme Sea Levels

Two of the most important topics in Sea Level Science are addressed in this paper. One is concerned with the evidence for the apparent acceleration in the rate of global sea level change between the nineteenth and twentieth centuries and, thereby, with the question of whether the twentieth century sea level rise was a consequence of an accelerated climate change of anthropogenic origin. An acceleration is indeed observed in both tide gauge and saltmarsh data at different locations around the world, yielding quadratic coefficients ??c?? of order 0.005 mm/year², and with the most rapid changes of rate of sea level rise occurring around the end of the nineteenth century. The second topic refers to whether there is evidence that extreme sea levels have increased in recent decades at rates significantly different from those in mean levels. Recent results, which suggest that at most locations rates of change of extreme and mean sea levels are comparable, are presented. In addition, a short review is given of recent work on extreme sea levels by other authors. This body of work, which is focused primarily on Europe and the Mediterranean, also tends to support mean and extreme sea levels changing at similar rates at most locations.     

226Ra and 228Ra in the seawater of the western Yellow Sea

1Introduction Therearefourradiumisotopesinnature,ofwhich224Ra,226Raand228Rahavebeenwidelyinvestigated inmarineresearch,butthespecificactivityof223Rais toolowtobemeasured,therefore,itsapplicationsarelimited(Moore,1969;Broeckeretal.,1976;KuandLin,1976;Nozak…