Crystal field stabilization energies of almandine-pyrope and almandine-spessartine garnets determined by FTIR near infrared measurements

The band positions of three partially overlapping Fe²⁺ spin-allowed transitions located between 4000 and 9000 cm^–1 in almandine-pyrope and almandinespessartine garnets solid solutions were measured using near-infrared (NIR) spectroscopy. The crystal field stabilization energies (CFSE) along both binaries were calculated assuming a splitting of 1100 cm^–1 for the lower orbitals. The CFSE show a slight increase along the almandine-spessartine binary from 3730 to 3810 cm^–1 and a larger increase from 3730 to 3970 cm^–1 for the almandine-pyrope binary. Dodecahedral Fe²⁺-site distortion increases with an increase in spessartine component and decreases with increasing pyrope component, in agreement with average dodecahedral site distortions determined from diffraction experiments. The excess CFSE's along both joins are negative. For the almandinespessartine binary they are small, but are about 3.5 times larger in magnitude along the join almandine-pyrope, where an interaction parameter of W= -2.9 KJ/mole has been derived from a symmetric mixing model. The excess CFSE are relatively small compared to the magnitudes of the excess enthalpies of mixing that have been assigned to garnet solid solutions. Moreover, they give no indication which could support the positive and asymmetric excess enthalpies of mixing that have been proposed for almandine-pyrope solid solutions.     

The frequency of wide binaries among the southern barium stars

Summary All of the barium and marginal barium stars in the 1972 MacConnell, Frey, and Upgren (1972: MFU) list of such objects which are located south of the celestial equator were examined for visual duplicity. Over 200 objects were observed, and a total of six possible candidates for wide pair visual binaries were found. Of these, four are most likely optical in nature. These data suggest that the incidence of wide binaries among barium stars is of the order of 1%.     

Electromagnetic studies in the central Arctic water basin

The results of the electromagnetic studies, obtained on the North Pole drifting stations, are reviewed. These results are still of current interest. The aspects of similar future works are discussed.     

Surface water quality evaluation in Odukpani, Calabar Flank, south-eastern Nigeria

 The present article is the second in a series of baseline water quality evaluation studies in parts of south-eastern Nigeria. Study results indicate that the water samples from the study are generally acidic, soft and fresh in addition to low sodium and salinity hazard. Regression equations indicate a good positive correlation between conductivity and Na, Ca, Mg and SO₄. Ca-SO₄ and Ca-Cl constitute the major facies in the area. Generally the waters in the area are good for most domestic and agricultural purposes. Received: 14 April 1997 · Accepted: 3 February 1998     

Modeling the dynamics of a high specific energy plasma bulge in the upper atmosphere: 1. Physics of the processes and numerical simulation of the early stage of plasma bulge expansion and interaction with the ionosphere and geomagnetic field: A review

The physicomathematical features of the plasma explosion region dynamics at altitudes higher than 100 km at the early stage of its development, which culminates in the transfer of a considerable portion of the initial plasma energy into the environment, are discussed in the first part of the work. The radiation gas dynamic, inertial, and shock stages of the disturbed region development are calculated.     

Human-induced Changes in the Groundwater Chemical Composition within an Oil Field Area

The effect of highly saline oil-field water on soils and potable groundwater is considered. Three phases of the hydrochemical evolution of groundwater quality affected by transborder pollution and field development that has deteriorated potable groundwater in the two topmost aquifers are identified.     

RHESSI Microflares: II. Implications for Loop Structure and Evolution

We present simple analytic models which predict the peak X-ray emission measure and temperature attained in flares in which the chromospheric evaporation process takes place either in a single ‘monolithic’ loop or in a loop consisting of several filaments that are created successively as the energy release process proceeds in time. As possible mechanisms driving chromospheric evaporation we consider both classical heat conduction from the loop top and non-thermal electron beams. The model predictions are tested for a set of 18 well studied RHESSI microflares. The results suggest beam driven evaporation in filamented loops as being capable of accounting for the observed emission measures and temperatures though there are issues with the very high beam densities needed. On the other hand, estimates of the emission measures achieved by conductive evaporation which are derived by using the Rosner – Tucker – Vaiana (RTV) scaling law are much larger than the observed ones. Possible reasons for this discrepancy are discussed.