Thermal expansion and dehydroxylation of phengite micas

Phengite samples (2M ₁ and 3T politypes) and a synthetic end-member muscovite specimen were studied by in situ high-temperature synchrotron radiation X-ray diffraction. The measured volume thermal expansion of 2M ₁ phengite (<α _V> ≈ 36.6 × 10⁻⁶ K⁻¹) was systematically greater than <α _V> of the 3T polytype (≈33.3 × 10⁻⁶ K⁻¹). A positive linear correlation between the average thermal expansion on (001) plane and the mean tetrahedral rotation angle at ambient condition is proposed on the ground of new measurements and literature data. Dehydroxylation processes were observed in 2M ₁, starting at 1,000 K in 3T at 800 and 945 K in synthetic muscovite. Rietveld refinements allowed a determination of structural variations upon heating of phengite samples and their dehydroxylate phases. The phengite structure expands by regularizing the tetrahedral sheet and by reducing the bond length differences between the outer and inner coordination shell of the interlayer site. The dehydroxylate phase derived from 2M ₁ is characterized by fivefold polyhedra in the low temperature form as a consequence of two OH groups reacting to form H₂O + O (residual). The dehydroxylate exhibits an increase of the cation–cation distances along the M–Or–M bonds with respect to low-temperature phengite structures. For the 3T phase, we were unable to achieve completion of dehydroxylation. The refined structural model of the dehydroxylate phase shows two hydroxyl sites, but at a short distance from one another. This result suggests that the dehydroxylation reaction did not proceed to completion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Origin and evolution of a salty gypsum/anhydrite karst spring: the case of Poiano (Northern Apennines, Italy)

Poiano is the largest karst spring of the Emilia Romagna region (northern Italy). It drains an aquifer of unique properties composed of anhydrite with halite lenses at depth and gypsum at the surface (both with high NaCl content). Hydrogeological research has been undertaken using automatically recorded hourly data on temperature, electrical conductivity, and water level. Water feeding the Poiano spring is restricted within the gypsum/anhydrite outcrop between the Lucola, Sologno and Secchia rivers. Karstification in the Upper Secchia Valley only concerns the gypsum rocks mainly present along the border and in the shallower parts of the sulfate outcrop and does not appear to occur at depth. Data strongly support the hypothesis that the salt content in the spring water derives from active halokinetic movements. For the first time, the fundamental hydrogeological importance of the anhydrite part inside the sulfate rocks is demonstrated. If gypsum prevails over anhydrite the karst drainage network can extend deep into the rocks following a network of fractures and fissures. Instead, if in the deep parts of the aquifer anhydrite prevails over gypsum, the karst evolution cannot take place at depth and the structure of the underground drainage paths only follows near-surface paths in gypsum.     

Out‐of‐plane seismic behaviour of rocking masonry walls

The evaluation of the out‐of‐plane behaviour of unreinforced walls is one of the most debated topics in the seismic assessment of existing masonry buildings. The discontinuous nature of masonry and its interaction with the remainder of the building make the dynamic modelling of out‐of‐plane response troublesome. In this paper, the results of a shaking table laboratory campaign on a tuff masonry, natural scale, U‐shaped assemblage (façade adjacent to transverse walls) are presented. The tests, excited by scaled natural accelerograms, replicate the behaviour of external walls in existing masonry buildings, from the beginning of rocking motion to overturning. Two approaches have been developed for modelling the out‐of‐plane seismic behaviour: the discrete element method and an SDOF analytic model. Both approaches are shown to be capable of reproducing the experimental behaviour in terms of maximum rotation and time history dynamic response. Finally, test results and numerical time history simulations have been compared with the Italian seismic code assessment procedures. Copyright © 2011 John Wiley & Sons, Ltd.     

Modelling of fractured carbonate reservoirs: outline of a novel technique via a case study from the Molasse Basin, southern Bavaria, Germany

Fluid flow in low-permeable carbonate rocks depends on the density of fractures, their interconnectivity and on the formation of fault damage zones. The present-day stress field influences the aperture hence the transmissivity of fractures whereas paleostress fields are responsible for the formation of faults and fractures. In low-permeable reservoir rocks, fault zones belong to the major targets. Before drilling, an estimate for reservoir productivity of wells drilled into the damage zone of faults is therefore required. Due to limitations in available data, a characterization of such reservoirs usually relies on the use of numerical techniques. The requirements of these mathematical models encompass a full integration of the actual fault geometry, comprising the dimension of the fault damage zone and of the fault core, and the individual population with properties of fault zones in the hanging and foot wall and the host rock. The paper presents both the technical approach to develop such a model and the property definition of heterogeneous fault zones and host rock with respect to the current stress field. The case study describes a deep geothermal reservoir in the western central Molasse Basin in southern Bavaria, Germany. Results from numerical simulations indicate that the well productivity can be enhanced along compressional fault zones if the interconnectivity of fractures is lateral caused by crossing synthetic and antithetic fractures. The model allows a deeper understanding of production tests and reservoir properties of faulted rocks.     

A Study of the Solar-Like Properties of β Hydri

We investigate properties of the internal structure of HR2021, better known as Hydri, a G2 IV subgiant with mass close to solar and for which observations by Bedding et al. (2001) have shown the presence of solar-like oscillations.We have computed models of Hydri,based on updated global parameters,and compared the computed frequencies for the models with the observed oscillation spectrum.     

Reliability of water content estimation by profile probe and its effect on slope stability

Shallow landslide failures are distributed worldwide and cause economic losses and fatalities. A proper evaluation of the possible occurrence of shallow landslides requires reliable characterization of water content. Volumetric water content (θ) is commonly estimated using dielectric sensors, which use manufacturers’ calibration curves developed for specific soil types. In this study, we present the experimental results achieved during a laboratory calibration of a capacitance probe (PR2/6 probe), tested on two sandy soils widely outcropping in Central Italy. The proposed equations demonstrate a more reliable estimation of θ with respect to the generalized soil equation provided by the manufacturer, which overestimates θ by up to 10 percentage points. Such overestimation could affect the evaluation of suction stress in partially saturated shallow soils affecting the slope stability analysis. Although the use of θ from correct calibration equations provides less precautionary factor of safety values, a reliable evaluation of the soil moisture condition is fundamental when mapping and predicting the spatial and temporal occurrence of shallow landslides. The use of the PR2/6 probe with the appropriate soil calibration equations in early warning monitoring systems will provide a more reliable forecast, minimizing the number of false alarms.     

Ground‐based InSAR reveals conduit pressurization pulses at Stromboli volcano

At Stromboli volcano (Southern Italy), only few minor precursors (gas output) have been identified for ‘major’ Strombolian explosions. We use ground‐based interferometric synthetic aperture radar (GBInSAR) technology to monitor the displacement rate of the summit area of Stromboli. We analysed the 2009–2011 period. The analysis of the displacement rate has been performed by dividing the summit zone monitored by the GBInSAR into three regions, corresponding to the edge of the crater area (1 and 2), and to the slope of the NE crater (3). Pulses of rapid expansion of sector 3, of variable duration and amplitude, appear in coincidence with periods of intense activity that include lava flows and major explosions. We associate this expansion with the pressurization of the magma column that is recharged by deep‐derived gas, promoting the onset of ‘major explosion‐dominated’ activity.     

Connectivity and single/dual domain transport models: tests on a point-bar/channel aquifer analogue

In porous aquifers, groundwater flow and solute transport strongly depend on the sedimentary facies distribution at fine scale, which determines the heterogeneity of the conductivity field; in particular, connected permeable sediments could form preferential flow paths. Therefore, properly defined statistics, e.g. total and intrinsic facies connectivity, should be correlated with transport features. In order to improve the assessment of the relevance of this relationship, some tests are conducted on two ensembles of equiprobable realizations, obtained with two different geostatistical simulation methods—sequential indicator simulation and multiple point simulation (MPS)—from the same dataset, which refers to an aquifer analogue of sediments deposited in a fluvial point-bar/channel association. The ensembles show different features; simulations with MPS are more structured and characterised by preferential flow paths. This is confirmed by the analysis of transport connectivities and by the interpretation of data from numerical experiments of conservative solute transport with single and dual domain models. The use of two ensembles permits (1) previous results obtained for single realizations to be consolidated on a more firm statistical basis and (2) the application of principal component analysis to assess which quantities are statistically the most relevant for the relationship between connectivity indicators and flow and transport properties.     

High Resolution DEM Generation in High‐Alpine Terrain Using Airborne Remote Sensing Techniques

Up‐to‐date and accurate digital elevation models (DEMs) are essential for many applications such as numerical modeling of mass movements or mapping of terrain changes. Today the Federal Department of Topography, swisstopo, provides Digital Terrain Models (DTMs) and Digital Surface Models (DSMs) derived from airborne LiDAR data with a high spatial resolution of 2 m covering the entire area of Switzerland below an elevation of 2000 m a.s.l.. However, above an elevation of 2000 m a.s.l., which is typical for high‐alpine terrain, the best product available is the a DTM with a spatial resolution of 25 m. This spatial resolution is insufficient for many applications in complex terrain. In this study, we investigate the quality of DSMs derived from opto‐electronic scanner data (ADS80; acquired in autumn 2010) using photogrammetric image correlation techniques based on the multispectral nadir and backward looking sensor data. As reference, we take a high precision airborne LiDAR data set with a spatial resolution of ca. 0.5 m, acquired in late summer 2010, covering the Grabengufer/Dorfbach catchment near Randa, VS. We find the deviations between the two datasets are surprisingly low. In terrain with inclination angles of less than 30° the RMSE is below 0.5 m. In extremely steep terrain of more than 50° the RMSE goes up to 2 m and outliers increase significantly. We also find dependencies of the deviations on illumination conditions and ground cover classes. Finally we discuss advantages and disadvantages of the different data acquisition methods.