Quantum-mechanical calculation of the vibrational spectrum of beryl (Al4Be6Si12O36) at the Γ point

A quantum-mechanical calculation of the zone-centre phonon spectrum of beryl has been performed, by using an hybrid HF/DFT Hamiltonian (B3LYP). An excellent agreement with the experiment has been obtained, being the difference between the calculated and the experimental vibrational frequencies (Raman, IR-TO and IR-LO) less than 5 cm^?1 on average. In the few cases where a relatively large disagreement between calculated and experimental data is observed, an explanation can be found which attributes the reason of the discrepancies to the experimental data rather than to the calculated ones. The calculation (i) allows the identification, in the experimental spectra, of the peaks corresponding to fundamental modes, overtones, combination bands and leakage; (ii) solves problems of band assignements due to the presence of LO–TO splitting in the IR spectra; (iii) provides the frequencies of silent modes; (iv) permits a full analysis of the atomic motion corresponding to each normal mode.     

Deriving vulnerability curves using Italian earthquake damage data

The concerted effort to collect earthquake damage data in Italy over the past 30 years has led to the development of an extensive database from which vulnerability predictions for the Italian building stock can be derived. A methodology to derive empirical vulnerability curves with the aforementioned data is presented herein and the resulting curves have been directly compared with mechanics-based vulnerability curves. However, it has been found that a valid comparison between the empirical and analytical vulnerability curves is not possible mainly due to a number of shortcomings in the database of surveyed buildings. A detailed discussion of the difficulties in deriving vulnerability curves from the current observed damage database is thus also presented.     

Lateral force distributions for the linear static analysis of base-isolated buildings

This paper presents a new approach for the evaluation of accurate lateral force distributions for the Linear Static Analysis (LSA) of Base Isolated (BI-) buildings. In essence, the proposed lateral force distributions depend on a factor measuring the degree of non- linearity of the Isolation System (IS) and on the ratio between the effective period of the BI-structure (T_is) and the fundamental period of the Fixed Based (FB-) structure (T_fb). The proposed approach is fully compatible with the Direct Displacement-Based Design (DDBD) method, recently developed by Priestley and co-workers. The proposed lateral force distributions have been derived from the results of a large number of Nonlinear Time-History Analyses (NTHA), carried out on six numerical models of multi-storey buildings, differing in storey number (3, 5 and 8, respectively) and fundamental period of vibration (from 0.25 to 0.8 s) in the fixed-base configuration. A great variety of Isolation Systems (ISs), characterised by either Elasto-Plastic with Hardening (EPH) or Flag-Shaped (FS) force-displacement behaviour, have been considered in the NTHA. The numerical parameters of the IS models have been varied in such a way as to reproduce the actual mechanical behaviour of the main currently used ISs, including: (i) Lead Rubber Bearings (LRB), (ii) High-Damping Rubber Bearings (HDRB), (iii) Friction Pendulum Bearings (FPB), (iv) combinations of flat Sliding Bearings (SB) and Low-Damping Rubber Bearings (LDRB) and (v) Combinations of flat SB and re-centring devices based on Shape Memory Alloys (SMA). Comparisons between the storey shear forces derived with the proposed method and those obtained from NTHA clearly show the great improvements in the accuracy of LSA predictions, when using the proposed lateral force distributions.     

Enhancing imaging of the Sub-Andean Foothills geology using magnetotellurics: A case history of a 3D survey in southern Bolivia

A magnetotelluric acquisition and modelling campaign, comprising 400 full tensor soundings, was carried out in the Sub-Andean Foothills in the area located south of Santa Cruz de la Sierra, Bolivia. The objective of the survey was to improve the imaging of the Paleozoic section and provide insight to the overall structure of the Devonian Silurian complex. The acquired data were inverted assuming both two-dimensional and three-dimensional dimensionality of the subsurface structure, adopting a multi-step iterative workflow, which began applying unconstrained inversion and introduced increasing constraints determined at each following step based on the interpretation of the latest inversion results. The geological interpretation of the final inversion results allowed to better image the expected complexity in the structures, particularly highlighting several different levels of detachment, mainly in the area of Kirusillas Formation. Furthermore, an oblique sense was identified of the main tendency of N-S deformation, related to a dextral transgressional movement that generates discrete dislocations, at a length scale of the order of a few kilometres.     

A multidisciplinary approach to reveal the Sicily Climate and Environment over the last 20 000 years

We present a thorough review of the knowledge on the climate and environment in Sicily over the last 20 000 years, taking into account results of several studies carried using terrestrial and marine records. We obtain a coherent framework of the most important changes succeeded in the island, even if some points need further investigation. All the reconstructions of surface temperatures of the seas and the air surrounding Sicily point out severe climatic conditions during the last glacial period. The steppe- and semisteppe-like vegetation pattern testifies, together with additional evidence from geochemical data of lacustrine evidence, markedly arid conditions. Fi-nally, significant episodes of sea level drop connected Sicily to the Italian Peninsula and favoured the dispersion of faunal elements from southern Italy. The transition between the last glacial and the Holocene was not characterized by a gradual warming but was punctuated by two abrupt suborbital climatic fluctuations: Bølling-Allerød (warm) and Younger Dryas (cold), as recognized in the sediments recovered close to the northern and southern coast of Sicily. A denser arboreal cover is possibly indicated by the occurrence of dormouse and Arvicola remains. Finally the sensitivity of Sicily to climate perturbations is demonstrated by the occurrence of repeated subtle climatic anomalies during the Holocene, including the Little Ice Age, also known from historical chronicles. Forests, woods and Mediterranean maquis developed in the early-middle Holocene. Thereafter was a general decline of arboreal vegetation, following a general aridification trend that seems to be a common feature in southern Europe and North Africa. Science Greek colonization (7^th century before Christ), the landscape was intensively modelled for agriculture and breeding, leading to a significant loss of vegetation cover.     

Conditional risk based on multivariate hazard scenarios

We present a novel methodology to compute conditional risk measures when the conditioning event depends on a number of random variables. Specifically, given a random vector \((\mathbf {X},Y)\), we consider risk measures that express the risk of Y given that \(\mathbf {X}\) assumes values in an extreme multidimensional region. In particular, the considered risky regions are related to the AND, OR, Kendall and Survival Kendall hazard scenarios that are commonly used in environmental literature. Several closed formulas are considered (especially in the AND and OR scenarios). An application to spatial risk analysis involving real data is discussed.     

Restoration of the eutrophic Orbetello lagoon (Tyrrhenian Sea, Italy): water quality management

The Orbetello lagoon (Tyrrhenian coast, Italy) receives treated urban and land based fishfarms wastewater. The development of severe eutrophication imposed the three main activity adoption focuses on (1) macroalgae harvesting; (2) pumping of water from the sea; (3) confining wastewater to phytotreatment ponds. The responses to these interventions were rapid and macroalgal reduction growth and seagrass return were recorded. Since 1999, a new macroalgal development was recorded. The aim of this research was to discover whether the recent macroalgal growth can be attributed to the continuing wastewater influx from the remaining persistent anthropic sources (PAS) or from the sediment nutrient release. A monitoring programme was carried out between August 1999 and July 2000 in order to measure dissolved inorganic nitrogen and phosphorus in the wastewaters entering into the lagoon and in central lagoon areas, seaweed and seagrass distribution and lagoon N, P annual budgets. The results showed higher N and P values close to PAS. The distribution of the macroalgal species confirms that the available P comes almost entirely from these remaining PAS. In conclusion, the environmental measures adopted produced a significant reduction in algal biomass development in the lagoon; the macroalgal harvesting activities produced a sediment disturbance with following oxidize conditions, which make P unavailable in the lagoon water, excepting close the PAS.     

Is the forward problem of ground water hydrology always well posed?

Complex aquifer systems are often modeled with quasi-three-dimensional models, which consider two-dimensional horizontal flow in the aquifers and one-dimensional vertical flow through aquitards. When the aquifer system consists of a phreatic aquifer and one or more semiconfined aquifers connected by aquitards, the discrete model consists of a nonlinear system of algebraic equations, because the transmissivity of the phreatic aquifer depends on the phreatic head. If the water extraction is very high, the phreatic aquifer can be depleted and the equations of the model must be modified accordingly. There are not simple and general criteria to state if the phreatic aquifer is depleted before solving the system of equations. Therefore, the iterative procedures (e.g., relaxation methods), used to find the solution to the forward problem, must handle these particular conditions and can suffer several problems of convergence. These problems can be caused by the choice of the initial head values or of the relaxation coefficient of the iterative algorithms; however, they can also be caused by the nonexistence or nonuniqueness of the solution to the system of nonlinear equations. The study of existence and uniqueness of the general problem is very difficult and, therefore, we consider a simplified problem, for which the discrete model can be handled analytically. The results of the numerical experiments show that the solution to the forward problem can be nonunique. Only for some cases it is possible to invoke physical arguments to eliminate tentative solutions.     

High-precision late Aptian Pb/U age for the Punta del Barco Formation (Baqueró Group), Santa Cruz Province,Argentina

The Baqueró Group holds a rich fossil flora including macrofloristic and palynological remains that characterize the Early Cretaceous vegetation of Argentina. The age of the upper part of the Group, known as Punta del Barco Formation, has been a topic of several discussions in the past. The type locality of this stratigraphic unit exposes fossiliferous tuffs together with muddy tuffs and tuffaceous sandstones beds. However, there have been no reliable age constraints for the fossil assemblages. ²⁰⁶Pb/²³⁸U analyses of zircon crystals yielded an age of 114.67 ± 0.18 Ma. This age control makes possible an improved analysis and comparison of the floras in the southern region.