Arsenic attenuation in tailings at a former Cu–W–As mine,SW Finland

Nearly half a century after mine closure, release of As from the Ylöjärvi Cu–W–As mine tailings in groundwater and surface water run-off was observed. Investigations by scanning electron microscopy (SEM), electron microprobe analysis (EMPA), synchrotron-based micro-X-ray diffraction (μ-XRD), micro-X-ray absorption near edge structure (μ-XANES) and micro-extended X-ray absorption fine structure (μ-EXAFS) spectroscopy, and a sequential extraction procedure were performed to assess As attenuation mechanisms in the vadose zone of this tailings deposit. Results of SEM, EMPA, and sequential extractions indicated that the precipitation of As bearing Fe(III) (oxy)hydroxides (up to 18.4 wt.% As₂O₅) and Fe(III) arsenates were important secondary controls on As mobility. The μ-XRD, μ-XANES and μ-EXAFS analyses suggested that these phases correspond to poorly crystalline and disordered As-bearing precipitates, including arsenical ferrihydrite, scorodite, kaňkite, and hydrous ferric arsenate (HFA). The pH within 200 cm of the tailings surface averaged 5.7, conditions which favor the precipitation of ferrihydrite. Poorly crystalline Fe(III) arsenates are potentially unstable over time, and their transformation to ferrihydrite, which contributes to As uptake, has potential to increase the As adsorption capacity of the tailings. Arsenic mobility in tailings pore water at the Ylöjärvi mine will depend on continued arsenopyrite oxidation, dissolution or transformation of secondary Fe(III) arsenates, and the As adsorption capacity of Fe(III) (oxy)hydroxides within this tailings deposit.     

Probable Neolithic footprints preserved in inter-tidal peat at Kenfig, South Wales (UK)

Holocene footprints have been reported from several locations around the UK coast preserved within inter-tidal sediments. These sediments are normally fine-grained silts, sands and clays. Here we report potential human footprints preserved in the lower of two inter-tidal peat units exposed on the foreshore at Kenfig in South Wales. The lower peat layer pre-dates 3810 ± 40 BP and its maximum age is constrained by two dates, one of 4930 ± 50 BP and another of 5110 ± 50 BP. The prints may have formed at any point within this time interval. Both peat units formed in a salt marsh, or fen environment, as indicated by the analysis of both diatoms and pollen and have been tentatively assigned to the middle Wentlooge Formation within the Holocene lithostratigraphy established for the Severn Estuary Holocene sequence. The footprints were digitised using an optical laser scanner and are compared to other Holocene human footprints exposed on the Sefton Coast in North West England. In comparison the Kenfig prints have poor anatomical form which may be the result of both the substrate and post-depositional modification. The paper demonstrates the value of using optical laser scanning in the data capture and analysis of transitory archaeological and geological trace evidence.     

A Comparative Plume Study of DRO,GRO, Benzene,and MTBE: Implications for Risk Management

Groundwater remediation and no-further action decision making at petroleum underground storage tank (UST) sites has largely been based on an understanding of plume length, plume stability, and attenuation rates for key hydrocarbon constituents. Regulatory guidance to support and guide such decisions is based in part on plume studies involving individual hydrocarbon constituents, namely benzene and methyl tert-butyl ether (MTBE). Questions remain regarding whether current guidance is applicable to chemical mixtures such as gasoline range organics (GRO), diesel range organics (DRO), and oxygen containing organic compounds (OCOCs) resulting from hydrocarbon biodegradation. To help address this concern, data from California's GeoTracker database were used to estimate maximum plume lengths, plume stability, and attenuation rates of DRO (which can be used as an analytical surrogate for OCOCs) and GRO relative to benzene and MTBE. The distributions of maximum plume lengths were similar for the four constituents with medians ranging from 27 to 32 m. The fraction of monitoring wells with a decreasing concentration trend ranged from 19% for DRO to 40% for MTBE, while fewer than 7% of the wells had an increasing concentration trend for any of the constituents. Median attenuation rates ranged from 0.10% day⁻¹ for DRO to 0.17% day⁻¹ for MTBE. The results suggest attenuation based risk management is appropriate for DRO and GRO plumes at most petroleum UST sites.     

Momentum and Turbulent Kinetic Energy Budgets Within the Park Avenue Street Canyon During the Joint Urban 2003 Field Campaign

Very few attempts have so far been made to quantify the momentum and turbulent kinetic energy (TKE) budgets within real urban canopies. In this study, sonic anemometer data obtained during the Joint Urban 2003 field campaign in Oklahoma City, U.S.A. were used for calculating the momentum and TKE budgets within a real-world urban street canyon. Sonic anemometers were deployed on multiple towers in the lower half of the canyon. Gradients in all three principal directions were included in the analyses. The storage and buoyancy terms were found to have negligible contributions to both the momentum and TKE budgets. The momentum budgets were generally found to be more complex than a simple balance of two physical processes. The horizontal terms were found to have significant and sometimes dominant contributions to the momentum and TKE budgets.     

The Quadrennial Ozone Symposium 2016

<正>1.Overview The 2016 Quadrennial Ozone Symposium(QOS-2016)was held on 4–9 September 2016 in Edinburgh,UK.The Symposium was organized by the International Ozone Commission(IO3C),the NERC Centre for EcologyHydrology and the University of Edinburgh,and was co-sponsored by the International Union of Geodesy and Geophysics,the International Association of Meteorology and Atmospheric     

Linking Inuit knowledge and meteorological station observations to understand changing wind patterns at Clyde River,Nunavut

Connecting indigenous and scientific observations and knowledge has received much attention in the Arctic, not least in the area of climate change. On some levels, this connection can be established relatively easily, linking observations of similar phenomena or of various effects stemming from the same cause. Closer examinations of specific environmental parameters, however, can lead to far more complex and difficult attempts to make those connections. In this paper we examine observations of wind at Clyde River, Nunavut, Canada. For Inuit, many activities are governed by environmental conditions. Wind, in particular, is identified by Inuit as one of the most important environmental variables, playing a key role in driving sea ice, ocean, and weather conditions that can either enable or constrain hunting, travel, or other important activities. Inuit observe wind patterns closely, and through many means, as a result of their close connection to the land and sea. Inuit in many parts of Nunavut are reporting changes in wind patterns in recent years. At Clyde River, a community on the eastern coast of Baffin Island, Inuit have observed that at least three key aspects of wind have changed over the last few decades: wind variability, wind speed, and wind direction. At the same time, wind observations are also available from an operational weather station located at Clyde River. An analysis of this information shows little change in wind parameters since the mid-1970s. Though the station data and Inuit observations correspond in some instances, overall, there is limited agreement. Although the differences in the two perspectives may point to possible biases that may exist from both sources—the weather station data may not be representative of the region, Inuit observations or explanations may be inaccurate, or the instrumental and Inuit observations may not be of the same phenomena—they also raise interesting questions about methods for observing wind and the nature of Arctic winds.     

Studying geoengineering with natural and anthropogenic analogs

Solar radiation management (SRM) has been proposed as a possible option for offsetting some anthropogenic radiative forcing, with the goal of reducing some of the associated climatic changes. There are clearly significant uncertainties associated with SRM, and even small-scale experiments that might reduce uncertainty would carry some risk. However, there are also natural and anthropogenic analogs to SRM, such as volcanic eruptions in the case of stratospheric aerosol injection and ship tracks in the case of marine cloud albedo modification. It is essential to understand what we can learn from these analogs in order to validate models, particularly because of the problematic nature of outdoor experiments. It is also important to understand what we cannot learn, as this might better focus attention on what risks would need to be solely examined by numerical models. Stratospheric conditions following a major volcanic eruption, for example, are not the same as those to be expected from intentional geoengineering, both because of confounding effects of volcanic ash and the differences between continuous and impulsive injection of material into the stratosphere. Nonetheless, better data would help validate models; we thus recommend an appropriate plan be developed to better monitor the next large volcanic eruption. Similarly, more could be learned about cloud albedo modification from careful study not only of ship tracks, but of ship and other aerosol emission sources in cloud regimes beyond the narrow conditions under which ship tracks form; this would benefit from improved satellite observing capabilities.