Thermohaline Anomalies in the Spring and Early Summer of 2000 in the Gulf of Trieste

Abstract. In the framework of the Interreg II Project (July 1998 - June 2001), hydro-logical, chemical and biological data were collected in the Gulf of Trieste.
During spring and summer 2000, some particular thermohaline anomalies were observed in the Gulf of Trieste. Especially in May and June the water body showed: a very strong thermohaline stratification, an increase of advective salt water coming from the south and the presence of sharp pycnoclines. In July the temperature was higher than usual in the whole water column. Moreover, in late May and in June, massive mucilaginous aggregates were observed along the water column and at the surface.
In order to highlight these particular thermohaline features the hydrological data of 16 stations were analysed (Fig. 1). Two stations, in particular, were considered: one offshore (St. AA1, average depth 20 m) and one close to the coast (St. C1, average depth 17 m). For these two stations a best-fit analysis, computed over 11 and 7 years, respectively, was performed on temperature, salinity and density excess data.
Moreover, the hydrological features were compared with the rainfall, air temperature, wind speed data (Istituto Sperimentale Talassografico di Trieste - ISTT) and the Isonzo River's flow rate (Direzione Regionale dell'Ambiente - Regione F. V. G.) collected from January 1998 to December 2000.     

Variation of the gradient and balmer discontinuity during the eclipse of the variable RW Tauri: Comparison between observations and theory

For the first time after Barbier and Chalonge's (1938, 1941) pioneering works, the variations of b andD during the eclipse of a variable (RT Tau), have been observed. The observations have been performed at the Observatories of Jungfraujoch and Haute Provence with the photoelectric system in seven colors of Geneva (Golay, 1964; Hauck, 1968). The comparison between the observed curves ofD and the theoretical ones, provides the limb darkening coefficients; the same comparison between the observed b (reddened) and theoretical ones (not reddened) together with that ofD, points out some anomalies of the variable RW Tau.

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Sommario Per la prima volta, dopo i primi lavori di Barbier e Chalonge (1938, 1941), sono state osservate le variazioni di b eD durante l'eclisse di una variabile (RW Tau). Le osservazioni sono state fatte agli Osservatori della Jungfraujoch e di Haute Provence col sistema fotoelettrico in sette colori di Ginevra (Golay, 1964; Hauck, 1968). Il confronto fra le curve osservate e teoriche diD, fornisce i coefficienti di oscuramento al bordo; lo stesso confronto fra i b osservati (arrossati) e quelli teorici (non arrossati) unitamente a quello delleD mette in evidenza alcune anomalie della variabile RW Tau.

     

黑河实验区地表净辐射区域分布及季节变化

利用卫星遥感信息和地面观测资料，分析研究黑河实验区地表净辐射的区域分布及季节变化特征。结果表明，卫星遥感结合地面观测，首先可以得到较为精确的地表反射率和地表温度分布，进而得到较为合理的地表净辐射的区域分布和季节变化特征。     

A Fe K-edge XAS study of amethyst

An X-ray absorption spectroscopy (XAS) study of the Fe local environment in natural amethyst (a variety of α-quartz, SiO₂) has been carried out. Room temperature measurements were performed at the Fe K-edge (7,112 eV), at both the X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) regions. Experimental results were then compared with DFT calculations. XANES experimental spectra suggest Fe to occur mainly in the trivalent state, although a fraction of Fe²⁺ is identified. EXAFS spectra, on the other hand, reveal an unusual short distance for the first coordination shell:  = 1.78(2) Å, the coordination number being 2.7(5). These results allow to establish that Fe replaces Si in its tetrahedral site, and that numerous local distortions are occurring as a consequence of the presence of Fe³⁺ variably compensated by protons and/or alkaline ions, or uncompensated. The formal valence of Fe, on the basis of both experimental and DFT structural features, can be either 4+ or 3+. Taking into account the XANES evidences, we suggest that Fe mainly occurs in the trivalent state, compensated by protons, and that a minor fraction of Fe⁴⁺ is stabilised by the favourable local structural arrangement.     

Carbonatites in a subduction system: The Pleistocene alvikites from Mt. Vulture (southern Italy)

We report here, for the first time, on the new finding of extrusive calciocarbonatite (alvikite) rocks from the Pleistocene Mt. Vulture volcano (southern Italy). These volcanic rocks, which represent an outstanding occurrence in the wider scenario of the Italian potassic magmatism, form lavas, pyroclastic deposits, and feeder dikes exposed on the northern slope of the volcano. The petrography, mineralogy and whole-rock chemistry attest the genuine carbonatitic nature of these rocks, that are characterized by high to very high contents of Sr, Ba, U, LREE, Nb, P, F, Th, high Nb/Ta and LREE/HREE ratios, and low contents of Ti, Zr, K, Rb, Na and Cs. The O–C isotope compositions are close to the “primary igneous carbonatite” field and, thus, are compatible with an ultimate mantle origin for these rocks. The Sr–Nd–Pb–B isotope compositions, measured both in the alvikites and in the silicate volcanic rocks, indicate a close genetic relationship between the alvikites and the associated melilitite/nephelinite rocks. Furthermore, these latter products are geochemically distinct from the main foiditic-phonolitic association of Mt. Vulture. We propose a petrogenetic/geodynamic interpretation which has important implications for understanding the relationships between carbonatites and orogenic activity. In particular, we propose that the studied alvikites are generated through liquid unmixing at crustal levels, starting from nephelinitic or melilititic parent liquids. These latter were produced in a hybrid mantle resulting from the interaction through a vertical slab window, between a metasomatized mantle wedge, moving eastward from the Tyrrhenian/Campanian region, and the local Adriatic mantle. The occurrence of carbonatite rocks at Mt. Vulture, that lies on the leading edge of the Southern Apennines accretionary prism, is taken as an evidence for the carbonatation of the mantle sources of this volcano. We speculate that mantle carbonatation is related to the introduction of sedimentary carbon from the Adriatic lithosphere during Tertiary subduction.     

Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.     

On the dependence of the saturated hydraulic conductivity upon the effective porosity through a power law model at different scales

We study the scale dependence of the saturated hydraulic conductivity K_s through the effective porosity n_e by means of a newly developed power‐law model (PLM) which allows to use simultaneously measurements at different scales. The model is expressed as product between a single PLM (capturing the impact of the dominating scale) and a characteristic function κ^? accounting for the correction because of the other scale(s). The simple (closed form) expression of the κ^?‐function enables one to easily identify the scales which are relevant for K_s. The proposed model is then applied to a set of real data taken at the experimental site of Montalto Uffugo (Italy), and we show that in this case two (i.e. laboratory and field) scales appear to be the main ones. The implications toward an important application (solute transport) in Hydrology are finally discussed. Copyright © 2016 John Wiley & Sons, Ltd.