Seismological structure and implications of collision between the Ontong Java Plateau and Solomon Island Arc from ocean bottom seismometer–airgun data

A seismic refraction–reflection experiment using ocean bottom seismometers and a tuned airgun array was conducted around the Solomon Island Arc to investigate the fate of an oceanic plateau adjacent to a subduction zone. Here, the Ontong Java Plateau is converging from north with the Solomon Island Arc as part of the Pacific Plate. According to our two-dimensional P-wave velocity structure modeling, the thickness of the Ontong Java Plateau is about 33 km including a thick (15 km) high-velocity layer (7.2 km/s). The thick crust of the Ontong Java Plateau still persists below the Malaita Accreted Province. We interpreted that the shallow part of the Ontong Java Plateau is accreted in front of the Solomon Island Arc as the Malaita Accreted Province and the North Solomon Trench are not a subduction zone but a deformation front of accreted materials. The subduction of the India–Australia Plate from the south at the San Cristobal Trench is confirmed to a depth of about 20 km below sea level. Seismicity around our survey area shows shallow (about 50 km) hypocenters from the San Cristobal Trench and deep (about 200 km) hypocenters from the other side of the Solomon Island Arc. No earthquakes occurred around the North Solomon Trench. The deep seismicity and our velocity model suggest that the lower part of the Ontong Java Plateau is subducting. After the oceanic plateau closes in on the arc, the upper part of the oceanic plateau is accreted with the arc and the lower part is subducted below the arc. The estimation of crustal bulk composition from the velocity model indicates that the upper portion and the total of the Solomon Island Arc are SiO₂ 58% and 53%, respectively, which is almost same as that of the Izu–Bonin Arc. This means that the Solomon Island Arc can be a contributor to growing continental crust. The bulk composition of the Ontong Java Plateau is SiO₂ 49–50%, which is meaningfully lower than those of continents. The accreted province in front of the arc is growing with the convergence of the two plates, and this accretion of the upper part of the oceanic plateau may be another process of crustal growth, although the proportion of such contribution is not clear.     

Growth of quartz crystals twinned after Japan Law

The flattened or elongated morphology often observed in contact twinned crystals has been referred to the so-called re-entrant corner effect at twin junctions. To re-investigate the validity of this mechanism, natural quartz crystals twinned after Japan Law have been subjected to re-growth in a commercial synthetic quartz autoclave, and the change in their morphology and surface microtopography by re-growth studied. It is found that although twin re-entrant corners may play a role of preferential growth sites, this role can be weakened considerably and in fact can become almost negligible when crystals grow under high supersaturation condition. Preferential growth at the re-entrant corner of a twin junction is probably due to clusters of dislocations concentrated in the composition plane, and not due to the so-called re-entrant corner effect in its original sense.     

Ar and Sr isotopes of mantle-derived rocks from the Japanese Islands

⁴⁰Ar-³⁰Ar and Sr isotope analyses have been made for ultramatic nodules in basaltic rocks from Itinome-gata and the Oki-Dōgo Island, northeast and southwest of Japan respectively, in order to examine the state of the upper mantle under the Japanese Islands. ⁴⁰Ar-³⁰Ar analyses have revealed that ultramafic nodules from Oki-Dōgo Island were involved in events which caused Ar redistribution in these rocks and probably were related to their formation not older than several tens of millions of years ago. These nodules are relatively depleted in both Rb and Sr contents together with some other incompatible elements compared to similar nodules from the other regions in the world. This may be typical for ultramafic nodules from the Japanese Islands. Ultramafic nodules show mostly a little higher⁸⁷Sr/⁸⁶Sr ratios (0.704–0.706) than those of host basaltic rocks (0.703–0.705) indicating the accidental origin for these nodules. Present results also suggest both horizontal and vertical inhomogeneities of the uppermost part of the mantle with respect to Sr isotopes on a regional scale. Hence, the ultramafic nodules in volcanic rocks may not always directly represent the upper mantle materials from which the magma is produced at present. Such ultramafic nodules might be relatively old material from the uppermost part of the mantle under the Japanese Islands.     

The Bay of Bengal — A major nutrient source for the deep Indian Ocean

The distribution of nutrient elements and dissolved oxygen in the deep Indian Ocean suggests that the Bay of Bengal Fan sediment serves as a major nutrient element source and oxygen sink. The distribution of nutrient element excesses and oxygen deficiences away from the fan is consistent with diffusion along isopycnal surfaces with circumpolar deep water acting as a sink for nutrient elements and source for dissolved oxygen. In the course of the entire GEOSECS program only at the Bengal Fan station were nutrient element excesses and oxygen deficiencies (relative to the overlying water column) observed in the benthic mixed layer. The unique aspect of this station is likely the result of very high rates of respiration and particle dissolution coupled with a high stability of the water column overlying the benthic mixed layer.The chemical data show that for each mole of organic carbon oxidized 1.5 moles of CaCO₃ must dissolve and that for each mole of CaCO₃ dissolved about one mole of silica go into solution. The NO₃ and PO₄ excesses are about two thirds those predicted from the Redfield ratios (i.e., O₂ : NO₃ : PO₄ = 135 : 15 : 1).     

Worldwide Estimates of Deep Natural Gas Resources Based on the U.S. Geological Survey World Petroleum Assessment 2000

The U.S. Geological Survey recently assessed undiscovered conventional gas and oil resources in eight regions of the world outside the U.S. The resources assessed were those estimated to have the potential to be added to reserves within the next thirty years. This study is a worldwide analysis of the estimated volumes and distribution of deep (>4.5 km or about 15,000 ft), undiscovered conventional natural gas resources based on this assessment. Two hundred forty-six assessment units in 128 priority geologic provinces, 96 countries, and two jointly held areas were assessed using a probabilistic Total Petroleum System approach. Priority geologic provinces were selected from a ranking of 937 provinces worldwide. The U.S. Geological Survey World Petroleum Assessment Team did not assess undiscovered petroleum resources in the U.S. For this report, mean estimated volumes of deep conventional undiscovered gas resources in the U.S. are taken from estimates of 101 deep plays (out of a total of 550 conventional plays in the U.S.) from the U.S. Geological Survey's 1995 National Assessment of Oil and Gas Resources. A probabilistic method was designed to subdivide gas resources into depth slices using a median-based triangular probability distribution as a model for drilling depth to estimate the percentages of estimated gas resources below various depths. For both the World Petroleum Assessment 2000 and the 1995 National Assessment of Oil and Gas Resources, minimum, median, and maximum depths were assigned to each assessment unit and play; these depths were used in our analysis. Two-hundred seventy-four deep assessment units and plays in 124 petroleum provinces were identified for the U.S. and the world. These assessment units and plays contain a mean undiscovered conventional gas resource of 844 trillion cubic ft (Tcf) occuring at depths below 4.5 km. The deep undiscovered conventional gas resource (844 Tcf) is about 17% of the total world gas resource (4,928 Tcf) based on the provinces assessed and includes a mean estimate of 259 Tcf of U.S. gas from the U.S. 1995 National Assessment. Of the eight regions, the Former Soviet Union (Region 1) contains the largest estimated volume of undiscovered deep gas with a mean resource of343 Tcf.     

Selective detection of Fe and Mn species at mineral surfaces in weathered granite by conversion electron yield X-ray absorption fine structure

A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO₂ and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 × 5 μm²) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction.     

Persistence and metallic composition of paint particles in sediments from a tidal inlet

Concentrations of Cu, Pb, Sn and Zn have been determined in sediment (<500 μm) and macroscopic paint particles (>500 μm) retrieved from sections of two cores collected from a tidal inlet of the Plym estuary, southwest England. Paint particles contributed up to about 0.2% of the total mass retrieved from each section and were most abundant towards the base of the cores where, according to (210)Pb dating, deposition took place about a decade prior to sampling. Metal concentrations in the paint particles pooled from the sections were highly variable, typically spanning two orders of magnitude in each core, and were greatest for Cu and Zn (up to 460,000 and 170,000 μg g(-1), respectively) due to their use in contemporary antifouling formulations applied to boat hulls. Concentrations of metals in the sediment were, however, relatively invariant, an effect attributed to the abundance and dispersion of microscopic paint particles throughout the cores.     

Geological relationship between Anyui Metamorphic Complex and Samarka terrane,Far East Russia

The Anyui Metamorphic Complex (AMC) of Cretaceous age is composed of metachert, schist, gneiss, migmatite and ultramafic rocks, and forms a dome structure within the northernmost part of the Jurassic accretionary complex of the Samarka terrane. The two adjacent geological units are bounded by a fault, but the gradual changes of grain size and crystallinity index of quartz in chert and metachert of the Samarka terrane and the AMC, together with the gradual lithological change, indicate that at least parts of the AMC are metamorphic equivalents of the Samarka rocks. Radiolarian fossils from siliceous mudstone of the Samarka terrane indicates Tithonian age (uppermost Jurassic), and hence, form a slightly later accretion. This signifies that the accretionary complex in the study area is one of the youngest tectonostratigraphic units of the Samarka terrane. The relationship between the Samarka terrane and AMC, as well as their ages and lithologies, are similar to those of the Tamba–Mino–Ashio terrane and Ryoke Metamorphic Complex in southwest Japan. In both areas the lower (younger) part of the Jurassic accretionary complexes were intruded and metamorphosed by Late Cretaceous granitic magma. Crustal development of the Pacific‐type orogen has been achieved by the cycle of: (i) accretion of oceanic materials and turbidites derived from the continent; and (ii) granitic intrusion by the next subduction and accretion events, accompanied by formation of high T/P metamorphic complexes.