Behaviour of proteinaceous substances in the estuary of the Tama River

Behaviour of dissolved and particulate proteinaceous substances in the estuary of the Tama River was investigated through field observations and laboratory experiments. Concentrations of dissolved proteinaceous substances in estuarine water were determined at eight stations between the mouth of the Tama River (TA-15) and a point 16km upstream (TA-8), using the colorimetric method of Lowryet al. (1951) that employs Folin phenol reagent. The results were expressed in terms of Folin phenol active substances (FPAS). It was found that FPAS decreased with increasing salinity and that the proportion of high molecular weight FPAS (molecular weight greater than 100,000) decreased rapidly in the estuary.The shapes, sizes and numbers of amorphous particulate substances stained by Amido Black 10B, called Amido Black active substances (ABAS), were determined under a microscope. The numbers of ABAS retained on Millipore HA filters (mean diameter: 10–80µm) amounted to 450ml^–1 in the estuarine water about 6km from the mouth of the estuary (Station TA-12M). Some of these aggregates are considered to be producedin situ by flocculation of high molecular weight FPAS during estuarine mixing. ABAS were also produced in experiments by mixing filtered river water with sea water.     

P-T history of a mantle diapir: the Horoman peridotite complex,Hokkaido, northern Japan

The Horoman peridotite complex, Hokkaido, Japan is divided into Lower and Upper zones on the basis of contrasting geological features. The complex recorded a consecutive decompression history in chemical zoning of pyroxenes and plagioclase in plagioclase lherzolite, which is interpreted to have been derived from garnet lherzolite by subsolidus decompression reactions. In the Lower Zone, and earlier decompression history is clearly preserved in large pyroxene porphyroclasts, which show marked M-shaped Al zoning characterized by low Al concentration at the core (Al=0.12/6 oxygens), gradual increase toward the marginal region, and rapid decrease toward the rim. The Ca content in the core is nearly constant (Ca=0.03/6 oxygens) with slight increase toward the margin followed by abrupt decrease toward the rim. The Al and Ca contents in the core of orthopyroxene in plagioclase lherzolite from the Upper Zone (Al=0.22, Ca=0.055/6 oxygens) are much higher than those for the Lower Zone, and the Al content typically decreases monotonously from the core to the rim with several exceptions that show poorly developed M-shaped zoning profiles. The earliest P-T conditions, inferable from the core compositions of pyroxenes are 900–950°C and 20 kbar for the Lower Zone and 1100–1150°C and 20 kbar for the Upper Zone. The increase of Al from the core to the margin is inferred to have resulted from nearly adiabatic decompression from these conditions into spinel peridotite facies. The complex experienced further decompression from the spinel stability field into the plagioclase stability field, which is inferred from plagioclase zoning in fine-grained aggregates composed mostly of plagioclase, chromite spinel, and olivine with minor pyroxenes. The Na-Ca ratio of each plagioclase grain decreases from the core to the rim, suggesting continuous decompression reaction producing olivine and plagioclase from pyroxenes and spinel. The sharp increase in Ca content toward the rim indicates that fairly rapid cooling associated with decompression is necessary to form and preserve the marked zoning. The sharp decrease in Al and Ca contents toward the rim of orthopyroxene was also formed during this final ascent of the complex. The systematic changes of the mineralogic and petrographic features that are gradational between the Lower and Upper zones suggest that the Horoman complex retains a temperature variation from the upper mantle. The Upper Zone is interpreted to have followed a higher temperature decompression path than the Lower Zone and probably represents a relatively hotter portion of a mantle diapir ascending from a depth greater than 60 km in the upper mantle.     

Estimation of lead sources in a Japanese cedar ecosystem using stable isotope analysis

Anthropogenic Pb affects the environment worldwide. To understand its effect on forest ecosystem, Pb isotope ratios were determined in precipitation, various components of vegetation, the forest floor, soil and parent material in a Japanese cedar (Cryptomeria japonica D. Don) forest stand. The average ²⁰⁶Pb/²⁰⁷Pb ratio in bulk precipitation was 1.14 ± 0.01 (mean ± SD), whereas that in the subsoil (20–130 cm) was 1.18 ± 0.01. Intermediate ratios ranging from 1.15 to 1.16 were observed in the vegetation, the forest floor, and the surface soil (0–10 cm). Using the ²⁰⁶Pb/²⁰⁷Pb ratios, the contribution of anthropogenic sources to Pb accumulated in the forest were estimated by the simple binary mixing model. Sixty-two percent of the Pb in the forest floor, 71% in the vegetation, and 55% in the surface soil (0–10 cm) originated from anthropogenic sources, but only 16% in the sub-surface soil (10–20 cm) was anthropogenic. These results suggest that internal Pb cycling occurs mainly between surface soil and vegetation in a Japanese cedar ecosystem, and that anthropogenic Pb strongly influences Pb cycling. Although the Japanese cedar ecosystem has a shallow forest floor, very little atmospherically derived Pb migrated downward over 10 cm in depth.     

Epithermal Gold-Silver Mineralization of the Asachinskoe Deposit in South Kamchatka, Russia

The Asachinskoe epithermal Au‐Ag deposit is a representative low‐sulfidation type of deposit in Kamchatka, Russia. In the Asachinskoe deposit there are approximately 40 mineralized veins mainly hosted by dacite–andesite stock intrusions of Miocene–Pliocene age. The veins are emplaced in tensional cracks with a north orientation. Wall‐rock alteration at the bonanza level (170–200 m a.s.l.) consists of the mineral assemblage of quartz, pyrite, albite, illite and trace amounts of smectite. Mineralized veins are well banded with quartz, adularia and minor illite. Mineralization stages in the main zone are divided into stages I–IV. Stage I is relatively barren quartz–adularia association formed at 4.7 ± 0.2 Ma (K‐Ar age). Stage II consists of abundant illite, Cu‐bearing cryptomelane and other manganese oxides and hydroxides, electrum, argentite, quartz, adularia and minor rhodochrosite and calcite. Stage III, the main stage of gold mineralization (4.5–4.4 ± 0.1–3.1 ± 0.1 Ma, K‐Ar age), consists of a large amount of electrum, naumannite and Se‐bearing polybasite with quartz–adularia association. Stage IV is characterized by hydrothermal breccia, where electrum, tetrahedrite and secondary covellite occur with quartz, adularia and illite. The concentration of Au+Ag in ores has a positive correlation with the content of K₂O + Al₂O₃, which is controlled by the presence of adularia and minor illite, and both Hg and Au also have positive correlations with the light rare‐earth elements. Fluid inclusion studies indicate a salinity of 1.0–2.6 wt% NaCl equivalent for the whole deposit, and ore‐forming temperatures are estimated as approximately 160–190°C in stage III of the present 218 m a.s.l. and 170–180°C in stage IV of 200 m a.s.l. The depth of ore formation is estimated to be 90–400 m from the paleo‐water table for stage IV of 200 m a.s.l., if a hydrostatic condition is assumed. An increase of salinity (>C_NaCl≈ 0.2 wt%) and decrease of temperature (>T ≈ 30°C) within a 115‐m vertical interval for the ascending hydrothermal solution is calculated, which is interpreted as due to steam loss during fluid boiling. Ranges of selenium and sulfur fugacities are estimated to be logfSe2 = ?17 to ?14.5 and logfS2 = ?15 to ?12 for the ore‐forming solution that was responsible for Au‐Ag‐Se precipitation in stage III of 200 m a.s.l. Separation of Se from S‐Se complex in the solution and its partition into selenides could be due to a relatively oxidizing condition. The precipitation of Au‐Ag‐Se was caused by boiling in stage III, and the precipitation of Au‐Ag‐Cu was caused by sudden decompression and boiling in stage IV.     

Two geomagnetic excursions during the Brunhes chron recorded in Chinese loess-palaeosol sediments

Detailed palaeomagnetic integrated with rock magnetic studies have been carried out on a loess-palaeosol sequence in Baoji, Shaanxi province, southern Chinese Loess Plateau. For most samples stepwise thermal demagnetization revealed two well-defined magnetization components. A low-temperature component (LTC), which was isolated between 100 and 200 °C, is consistent with the present geomagnetic field direction. A high-temperature component (HTC), which was isolated between 250 and 620–680 °C, shows normal, reversed or transitional polarities. Our new magnetostatigraphy revealed two distinct geomagnetic excursions recorded in loess unit of L5 and palaeosol unit of S7, respectively, and the Matuyama-Brunhes (M-B) polarity boundary in loess unit of L8. Rock magnetic experiments demonstrated that the specimens from the excursion zones have the same magnetic properties as those from the Brunhes normal or Matuyama reversed polarity zones. Measurements of anisotropy of magnetic susceptibility (AMS) showed that the sediments have primary sedimentary fabrics. Based on the palaeoclimatological and magnetostratigraphic age models, the middle Brunhes excursion in loess L5 is dated at 413–433 ka, and the early Brunhes excursion is estimated to occur 23–33 ka after the M-B reversal. Comparing with previously reported geomagnetic excursions in the Brunhes chron, the middle Brunhes excursion (L5) is likely global. For the early Brunhes excursion (S7), we need further studies to examine its global occurrence.     

Geochemical Changes in Spring Water Associated with the 2000 Eruption of the Miyakejima Volcano, Japan

Water was sampled from eight springs and a lake in volcanic Miyakejima Island of Japan after the 2000 eruption. Major chemical and isotopic compositions of the water were analyzed. Significant increases of sulfate ion are observed in several springs where the thickness of ejecta exceeds 32 mm. A good relationship of Cl/S mole ratios between spring water and leachate of the ejecta is observed. Sulfur isotopic compositions of the spring water become close to that of leachate of the ejecta as time elapses after the eruption. Consequently the sources of the added sulfate ion in the spring water after the eruption are interpreted to be anhydrite and adhered sulfur of the ejecta.     

Software framework for distributed experimental–computational simulation of structural systems

Supported by the recent advancement of experimental test methods, numerical simulation, and high‐speed communication networks, it is possible to distribute geographically the testing of structural systems using hybrid experimental–computational simulation. One of the barriers for this advanced testing is the lack of flexible software for hybrid simulation using heterogeneous experimental equipment. To address this need, an object‐oriented software framework is designed, developed, implemented, and demonstrated for distributed experimental–computational simulation of structural systems. The software computes the imposed displacements for a range of test methods and co‐ordinates the control of local and distributed configurations of experimental equipment. The object‐oriented design of the software promotes the sharing of modules for experimental equipment, test set‐ups, simulation models, and test methods. The communication model for distributed hybrid testing is similar to that used for parallel computing to solve structural simulation problems. As a demonstration, a distributed pseudodynamic test was conducted using a client–server approach, in which the server program controlled the test equipment in Japan and the client program performed the computational simulation in the United States. The distributed hybrid simulation showed that the software framework is flexible and reliable. Copyright © 2005 John Wiley & Sons, Ltd.     

Concentrations of 222 Rn, Its Short-Lived Daughters And 212 Pb And Their Ratios Under Complex Atmospheric Conditions And Topography

Atmospheric activity concentrations of ²¹²Pb and short-lived ²²²Rndaughters, together with meteorological elements, have been observed continuously atthree sites at Kamisaibara Village in Japan. In addition, atmospheric activity concentrationof ²²²Rn, equilibrium-equivalent concentration of ²²²Rn and conditionsof the lower atmosphere were observed for three intensive observation periods at Akawase,one of the three sites in Kamisaibara Village. The equilibrium-equivalent concentration of²²²Rn is almost the same as the atmospheric activity concentration of short-lived²²²Rn daughters.The activity concentrations of ²¹²Pb and the short-lived ²²²Rn daughtersand their ratio were low in the daytime owing to convective mixing, and high at nightowing to the surface-based inversion during periods of no precipitation. Their variationshave several patterns corresponding to the scale of the drainage wind or weak mixing.Mechanical mixing due to strong winds through both day and night during the first andsecond observation periods made the atmospheric activity concentrations of ²¹²Pb and the short-lived ²²²Rn daughters continuously low. However, their ratios werecontinuously high during the first period yet continuously low during the second period.This difference can be explained by the effect ofextraction of ²²⁰Rn and ²²²Rndue to strong winds and snow cover. There were also cases in which the ratio of theatmospheric activity concentration of ²¹²Pb to that of the short-lived ²²²Rndaughters at night was equal to or less than the ratio in the daytime. Thisinverse trend, asin the periods of no precipitation mentioned above, is considered to be due to near-neutralconditions on these nights.We find a difference in the ratio of the equilibrium-equivalent concentration of²²²Rn (the activity concentration of short-lived ²²²Rn daughters) tothe activity concentration of ²²²Rn during the first observation period and thatduring the second. The difference can be explained by snow cover on the ground. Wealso find differences among the ratios of the activity concentration of the short-lived²²²Rn daughters to that of ²²²Rn during the three observation periods.These differences can be explained by the submergence of paddy fields.     

Study of quantization effects on rainfall rate estimation from GPM dual-frequency radar

The effect of quantization on rainfall rate estimation from the Global Precipitation Measurement dual-frequency radar is studied quantitatively through numerical simulations. The error generated by a deterministic quantization or by a dithered quantization on rainfall rate estimation is combined with the errors from statistical fluctuation of the signal and the receiver noise. The preliminary results for the rain-rate range of 1-10 mmh/sup -1/ are presented.     

Seismological structure and implications of collision between the Ontong Java Plateau and Solomon Island Arc from ocean bottom seismometer–airgun data

A seismic refraction–reflection experiment using ocean bottom seismometers and a tuned airgun array was conducted around the Solomon Island Arc to investigate the fate of an oceanic plateau adjacent to a subduction zone. Here, the Ontong Java Plateau is converging from north with the Solomon Island Arc as part of the Pacific Plate. According to our two-dimensional P-wave velocity structure modeling, the thickness of the Ontong Java Plateau is about 33 km including a thick (15 km) high-velocity layer (7.2 km/s). The thick crust of the Ontong Java Plateau still persists below the Malaita Accreted Province. We interpreted that the shallow part of the Ontong Java Plateau is accreted in front of the Solomon Island Arc as the Malaita Accreted Province and the North Solomon Trench are not a subduction zone but a deformation front of accreted materials. The subduction of the India–Australia Plate from the south at the San Cristobal Trench is confirmed to a depth of about 20 km below sea level. Seismicity around our survey area shows shallow (about 50 km) hypocenters from the San Cristobal Trench and deep (about 200 km) hypocenters from the other side of the Solomon Island Arc. No earthquakes occurred around the North Solomon Trench. The deep seismicity and our velocity model suggest that the lower part of the Ontong Java Plateau is subducting. After the oceanic plateau closes in on the arc, the upper part of the oceanic plateau is accreted with the arc and the lower part is subducted below the arc. The estimation of crustal bulk composition from the velocity model indicates that the upper portion and the total of the Solomon Island Arc are SiO₂ 58% and 53%, respectively, which is almost same as that of the Izu–Bonin Arc. This means that the Solomon Island Arc can be a contributor to growing continental crust. The bulk composition of the Ontong Java Plateau is SiO₂ 49–50%, which is meaningfully lower than those of continents. The accreted province in front of the arc is growing with the convergence of the two plates, and this accretion of the upper part of the oceanic plateau may be another process of crustal growth, although the proportion of such contribution is not clear.