The nationwide investigation of endocrine disruptors in sediment of harbours

Various types of endocrine disruptors or environmental hormones flow from their sources down into harbours through rivers and other watercourses, and are accumulated in sediment on the sea bottom. Tributyltin, which has been used as paint for ship bottoms, is considered one of the endocrine disruptors.In close cooperation with the other ministries and agencies, the Ports and Harbours Bureau of the Ministry of Land, Infrastructure and Transport carried out an investigation in 1999 to determine the actual condition of 12 endocrine disruptors in the sediment of 39 harbours, in order to gather fundamental data to be used in future examinations of policy. Furthermore, in 2000 the bureau chose seven harbours out of the above 39 harbours as subjects of an additional investigation regarding the surface distribution of endocrine disruptors in the harbour areas and the synchronistic change of accumulation of dioxin and other substances. As the result of the investigation regarding the surface distribution of endocrine disruptors accumulated in seven harbours, relatively high concentrations were measured in the innermost parts of harbours and the mouths of rivers. Synchronistic changes in the amount of dioxin and other substances accumulated in sediments of five harbours were determined. Small amounts of dioxin and other substances, including an especially small amount of coplanar-PCBs, were found in the layers formed before or around 1950. Relatively large amounts of these substances were measured in the upper layers formed during roughly 1960-1990, though no significant yearly differences in concentration could be identified. This result coincides with the facts that, during roughly 1960-1980, PCP and CNP were used as agricultural chemicals and full-scale production of PCBs started in 1960.     

Estimation of methane emission from whole waste landfill site using correlation between flux and ground temperature

A methodology to estimate a methane emission in a waste landfill site was developed. The methane flux at a waste landfill site in summer, autumn, and winter was within the following ranges: from −1.3×10⁻² to 16, from −6.4×10⁻² to 7.5, and from −1.6×10⁻³ to 1.5×10⁻² g-CH₄ m⁻² h⁻¹, respectively. In those seasons, the mean methane emission rate and coefficient of variation were 1.1 g-CH₄ m⁻² h⁻¹ ±290%, 0.57 g-CH₄ m⁻² h⁻¹ ±347%, and 5.4×10⁻² g-CH₄ m⁻² h⁻¹ ±370%, respectively. These results simultaneously showed that fluctuations of methane emission from the landfill surface were both of spatial and temporal variability. In each season, an exponential relationship was observed between the methane flux density and the ground temperature. Total methane emissions were estimated to be 5.7×10⁻², 7.1×10⁻³, and 1.7×10⁻³ g-CH₄ m⁻² h⁻¹ in the summer, autumn, and winter surveys, respectively, using a temperature surrogated-kriging method. The results of this study would improve upon the labor-intensive closed-chamber method, and could be a more practical way to estimate methane emissions from waste landfills.     

The effects of torsion and motion coupling in site response estimation

Soil amplification characteristics are investigated using data from the Chibaken‐Toho‐Oki earthquake and its aftershocks recorded at Chiba dense array in Japan. The frequency‐dependent amplification function of soil is calculated using uphole‐to‐downhole spectral ratio analysis, considering the horizontal components of shear wave. The identified spectral ratios consistently demonstrate the splitting of peaks in their resonance frequencies and low amplification values in comparison with a 1D model. The torsional behaviour and horizontal ground motion coupling are clarified as the reasons for these phenomena at the site. To prove the hypothesis, the torsional motion is directly evaluated using the data of the horizontal dense array in different depths at the site. The comparison between Fourier spectra of torsional motion and identified transfer functions reveals the peaks at the same frequencies. The wave equation including torsion and horizontal motion coupling is introduced and solved for the layered media by applying wave propagation theory. Using the developed model, the effects of torsional motion with horizontal motion coupling on soil transfer function are numerically examined. Splitting and low amplification at resonance frequencies are confirmed by the results of numerical analysis. Furthermore, the ground motion in two horizontal directions at the site is simulated using site geotechnical specification and optimizing the model parameters. The simulated and recorded motions demonstrate good agreement that is used to validate the hypothesis. In addition, the spectral density of torsional ground motions are compared with the calculated one and found to be well predicted by the model. Finally, the results are used to explain the overestimation of damping in back‐calculation of dynamic soil properties using vertical array data in small strain level. Copyright © 2003 John Wiley & Sons, Ltd.     

The Nobeyama Millimeter Array Survey for protoplanetary disks around protostar candidates and T Tauri stars in Taurus

The Nobeyama Millimeter Array Survey for protoplanetary disks has been made for 19 protostellar IRAS sources in Taurus; 13 of them were optically invisible protostars and 6 were young T Tauri stars. We observed 98-GHz continuum and CS(J = 2 – 1) line emissions simultaneously with spatial resolutions of 2 _. 8-8 _. 8 (360-1,200 AU). The continuum emission was detected from 5 out of 6 T Tauri stars and 2 out of 13 protostar candidates: the emission was not spatially resolved and was consistent with being originated from compact circumstellar disks. Extended CS emission was detected around 2 T Tauri stars and 11 protostar candidates. There is a remarkable tendency for the detectability of the 98-GHz continuum emission to be small for protostar candidates. This tendency is explained if the mass of protoplanetary disks around protostars is not as large as that around T Tauri stars; the disk mass may increase with the increase of central stellar mass by dynamical accretion in the course of evolution from protostars to T Tauri stars.Paper presented at the Conference onPlanetary Systems: Formation, Evolution, and Detection held 7–10 December, 1992 at CalTech, Pasadena, California, U.S.A.     

Evaluation of pounding countermeasures and serviceability of elevated bridges during seismic excitation using 3D modeling

This paper conducts elaborate analyses to evaluate the effectiveness of pounding countermeasures and the serviceability of elevated bridges subject to severe ground motions using detailed 3‐dimensional non‐linear modeling of an entire bridge structure system. A three‐span elevated steel bridge is selected for a case study. The peak and residual magnitude of gaps between girders and the maximum shear deformations of bearings are computed and used in the serviceability evaluation. The results show that under proper configurations the mitigation devices work effectively in reducing pounding actions in both the longitudinal and rotational directions. Copyright © 2004 John Wiley & Sons, Ltd.     

Inclined single piles under vertical loadings in cohesionless soil

Physical-scaled model testing under 1 g conditions is carried out in obtaining the vertical response of fixed head floating-inclined single piles embedded in dry sand. Practical pile inclinations of 5° and 10° besides a vertical pile (0°) subjected to static and dynamic vertical pile head loadings are considered. To account for the effects of soil nonlinearity as well as the soil–pile interface nonlinearity on the response of piles, a range of low-to-high magnitude of pile head displacements is considered for the static case while a varying amplitude of harmonic accelerations for a wide range of frequencies is considered for the dynamic case. Experimental results are obtained in the form of pile head stiffnesses and strains generated in the pile under both the static and dynamic loadings. Results suggest that the nonlinear behavior of soil as well as the nonlinearity generated at the interface between the soil and the pile as the result of applied loading considerably affect the response of piles. The soil–pile interface nonlinearity that governs the slippage of pile shows a clear influence on the pile head stiffnesses by providing two distinct values of stiffnesses corresponding to the push and the pull directional movement of piles; the two values are significantly different. Axial and bending strains generated in the piles show expected dependency on the amplitude of applied loading; the pile head-level bending strain increases almost linearly with the increase in the angle of pile inclination.

     

Temporal change of characteristics of shallow volcano-tectonic earthquakes associated with increase in volcanic activity at Kuchinoerabujima volcano, Japan

Shallow volcano-tectonic (VT) earthquakes recorded at the Kuchinoerabujima island volcano in southwest Japan are analyzed in order to clarify the role of hydrothermal activity in the development of volcanic seismicity. From analysis of shallow VT earthquakes in 2006, two specific episodes of elevated seismicity are observed in April and November 2006. The VT earthquakes have hypocenters at depths of 0–0.4 km beneath the summit crater, and normal fault focal mechanisms with WNW–ESE extension consistent with the tensional stress field indicated by the alignment of craters and fissures. Although the hypocenters and focal mechanisms are found to be largely invariant during these episodes, the corner frequencies of the VT earthquakes underwent a pronounced increase and decrease accompanying the changes in seismicity rates. The corner frequencies increased to 20–25 Hz approximately one month prior to the onset of elevated seismicity, and then decreased to 10–15 Hz in the period of peak seismicity. The rupture length also decreased at the onset of seismicity, thereafter increasing as the seismicity continued. The peak seismicity in terms of the daily number of VT events was accompanied by inflation around the crater, suggestive of a pressure increase in the volcanic system. It is inferred that the increase in shallow VT seismicity and rupture length is related to the development of a fractured zone. The pressure increase in the volcanic system is attributed to the intrusion of hydrothermal fluids, which is supported by an observed increase in fumarolic temperature and activity. The preceding monochromatic events are thus considered to be generated by the effect of fluid-filled cracks. The shortening of rupture length is then inferred to be related to the closing of non-fluid-filled cracks in the fracture zone under the increasing pressure field, leading to a transition from monochromatic events to low-frequency and shallow VT seismicity.     

HPLC determination of phytoplankton pigments using N,N-dimethylformamide

The suitability of N,N-dimethylformamide (DMF) as an extractant for the standard reverse-phase HPLC method was examined using algal cultures. Good pigment separations and recovery were achieved with 20% (volume %) addition of an ion-pairing solution in an injection. While slight amounts of degradation products of chlorophylla, i.e., chlorophyllidea, allomeric and epimeric forms, were produced, adequate attention to filtration and extraction prevents the formation of degradation products, confining them to an acceptable level. Because of its strong extractability, which expedites the extraction process, DMF is an efficient solvent for HPLC analysis of phytoplankton pigments.     

Characteristics of ChgH-GFP transgenic medaka lines, an in vivo estrogenic compound detection system

We previously reported the characteristics of a ChgH-GFP transgenic medaka line that indicates estrogenic compound pollution in environmental water by the green fluorescence of their liver. Recently, we established four more lines. In this study, the characteristics of the five transgenic medaka lines were investigated. The intensity of reporter gene expression varied among transgenic lines and generally correlated well with the amount of integrated transgene in each line. Line-specific ectopic expression was also observed. However, the sensitivity to 17-beta estradiol did not differ among transgenic lines. Three transgenic lines are considered to be suitable as bio-indicators of estrogenic activity, due to the ease of observing green fluorescence in their livers. The transgenic lines can also detect the estrogenic activity of testosterone and 17-beta trenbolone at the nominal concentration of 30 and 100 microg/l, respectively.