Clearcutting and pine planting effects on nutrient concentrations and export in two mixed use headwater streams: Upper Coastal Plain,Southeastern USA

Timber harvest temporarily increases water yield; however, relationships between hydrologic and nutrient chemistry changes have not been consistent. This study quantified the effects of forest harvesting and site preparation without fertilization and with modern best management practices on nutrient concentrations and yields in small headwater streams of the Southeastern Coastal Plain. We monitored two watershed pairs for 2 years prior to and 1 year following timber harvest and for 2 more years following site preparation and planting. Treatment watersheds were clearcut, and downstream portions of streamside management zones were thinned in Fall 2003. Site preparation (herbicide application and burning) and planting followed a year later. All operations followed 1999 Georgia forestry best management practices. Previously published research revealed a large increase in water yield following harvest. Nutrient concentrations varied significantly within and between monitoring periods, even in reference watersheds. Silvicultural activities had no discernible effect on phosphorus and ammonium concentrations; however, statistically significant increases in nitrate/nitrite (67–340 µg L⁻¹) and total nitrogen concentrations (100–400 µg L⁻¹) in treatment watersheds followed stand re‐establishment. Nutrient yields increased after timber harvest largely as a result of increased water yields, although increased nutrient yields were small relative to inter‐annual and inter‐watershed variability and variability. Annual water yield largely explained the variability in annual nitrogen and phosphorus export from reference and treatment streams (r² values from 0.65 to 0.98). High NO_x concentrations coming from an upstream agricultural area decreased 1600–1800 µg L⁻¹ over several hundred metres in the treatment streams by dilution, uptake or denitrification. Copyright © 2013 John Wiley & Sons, Ltd.     

Mechanisms controlling the seasonal mixed-layer temperature and salinity of the Indonesian seas

We examine the seasonal mixed-layer temperature (MLT) and salinity (MLS) budgets in the Banda–Arafura Seas region (120–138° E, 8–3° S) using an ECCO ocean-state estimation product. MLT in these seas is relatively high during November–May (austral spring through fall) and relatively low during June–September (austral winter and the period associated with the Asian summer monsoon). Surface heat flux makes the largest contribution to the seasonal MLT tendency, with significant reinforcement by subsurface processes, especially turbulent vertical mixing. Temperature declines (the MLT tendency is negative) in May–August when seasonal insolation is smallest and local winds are strong due to the southeast monsoon, which causes surface heat loss and cooling by vertical processes. In particular, Ekman suction induced by local wind stress curl raises the thermocline in the Arafura Sea, bringing cooler subsurface water closer to the base of the mixed layer where it is subsequently incorporated into the mixed layer through turbulent vertical mixing; this has a cooling effect. The MLT budget also has a small, but non-negligible, semi-annual component since insolation increases and winds weaken during the spring and fall monsoon transitions near the equator. This causes warming via solar heating, reduced surface heat loss, and weakened turbulent mixing compared to austral winter and, to a lesser extent, compared to austral summer. Seasonal MLS is dominated by ocean processes rather than by local freshwater flux. The contributions by horizontal advection and subsurface processes have comparable magnitudes. The results suggest that ocean dynamics play a significant part in determining both seasonal MLT and MLS in the region, such that coupled model studies of the region should use a full ocean model rather than a slab ocean mixed-layer model.     

Phytoplankton and ice-algal communities in the seasonal ice zone during January (Southern Ocean,Indian sector)

Journal of Oceanography - In the seasonal ice zone (SIZ), sea-ice algae have been hypothesized to influence phytoplankton species composition in seawater after melting from sea ice. However,...     

Precise estimation of pressure–temperature paths from zoned minerals using Markov random field modeling: theory and synthetic inversion

The chemical zoning profile in metamorphic minerals is often used to deduce the pressure–temperature (P–T) history of rock. However, it remains difficult to restore detailed paths from zoned minerals because thermobarometric evaluation of metamorphic conditions involves several uncertainties, including measurement errors and geological noise. We propose a new stochastic framework for estimating precise P–T paths from a chemical zoning structure using the Markov random field (MRF) model, which is a type of Bayesian stochastic method that is often applied to image analysis. The continuity of pressure and temperature during mineral growth is incorporated by Gaussian Markov chains as prior probabilities in order to apply the MRF model to the P–T path inversion. The most probable P–T path can be obtained by maximizing the posterior probability of the sequential set of P and T given the observed compositions of zoned minerals. Synthetic P–T inversion tests were conducted in order to investigate the effectiveness and validity of the proposed model from zoned Mg–Fe–Ca garnet in the divariant KNCFMASH system. In the present study, the steepest descent method was implemented in order to maximize the posterior probability using the Markov chain Monte Carlo algorithm. The proposed method successfully reproduced the detailed shape of the synthetic P–T path by eliminating appropriately the statistical compositional noises without operator’s subjectivity and prior knowledge. It was also used to simultaneously evaluate the uncertainty of pressure, temperature, and mineral compositions for all measurement points. The MRF method may have potential to deal with several geological uncertainties, which cause cumbersome systematic errors, by its Bayesian approach and flexible formalism, so that it comprises potentially powerful tools for various inverse problems in petrology.     

Inflations prior to Vulcanian eruptions and gas bursts detected by tilt observations at Semeru Volcano,Indonesia

We examine the basic characteristics of inflations at Semeru Volcano, Indonesia, to clarify the pressurization process prior to two different styles of explosive eruptions: Vulcanian eruptions and gas bursts. Analysis of data obtained from tilt meters installed close to the active crater allows clarification of the common features and the differences between the two styles of eruptions. To improve the signal-to-noise ratio and to determine the mean characteristics of the inflations, we stack tilt signals obtained from eruptions of different magnitudes and evaluate the maximum amplitude of the seismic signal associated with these eruptions. Vulcanian eruptions, which explosively release large amounts of ash, are preceded by accelerating inflation about 200–300 s before the eruption, which suggests volume expansion of the gas phase. In contrast, gas bursts, which rapidly effuse water steam accompanied by explosive sounds, follow non-accelerating changes of inflation starting 20 s before each emission. Tilt amplitudes increase with the magnitude of eruptions for both eruption styles. This suggests that the volume and/or pressure of magma or gas stored in the conduit before eruptions controls the magnitude of volcanic eruptions. These results further suggest that the magnitude of eruptions can be predicted from geodetic measurements of volcano inflation.     

Relationship between trace elements and depositional environments in shallow sediments: a case study from Southern Kanto Plain,Central Japan

Underground developments such as subways and shopping facilities have been increasing in number and magnitude in the relatively shallow subsurface of many urban areas where the earth materials commonly are composed of marine sediments. Marine sediments can contain significant amounts of toxic trace elements such as arsenic, boron, and lead. Changes in the subsurface environment caused by excavation and construction in underground developments could potentially cause these toxic elements to be dissolved into pore water of the sediments, which might lead to groundwater pollution. The purpose of this study is to investigate correlations among chemical properties of marine sediments, such as pH and electrical conductivity (EC), concentrations of toxic trace elements, and stratigraphic characteristics of the sediments. We selected three sites with different stratigraphic settings in the southern Kanto Plain around the Tokyo Metropolis. We collected core samples from shallow strata at a site in the Arakawa Lowland, southern Saitama, and at two sites in the Musashino Upland, Middle Tokyo. All sites have both marine and non-marine sediments up to 50–60 m in thickness. We determined trace element concentrations in the pore water, pH, EC, and loss on ignition. The results show that (1) the marine sediments tend to have low pH, high EC, and high sulfur concentration compared to the non-marine sediments (2) the concentration of most of the soluble heavy metals vary depending on the concentration of sulfate, the pH, and the formation processes of the strata, (3) the arsenic concentration is not related to sulfur concentration but apparently to Fe and Al concentrations, (4) the boron concentration is not related to any other properties implying that the boron level is independent of and cannot be predicted by common chemical properties, and (5) for all three sites, concentrations of most of the trace elements, EC, pH, and sulfate concentration were correlated with each other. This study shows that the concentration and potential mobilization of many toxic trace elements in marine sediments could be predicted by easily measurable pore water chemical properties such as pH and EC. This could be useful for predicting and avoiding the risk of groundwater pollution during underground development projects.     

Cd adsorption onto Pseudomonas putida in the presence and absence of extracellular polymeric substances

The role of bacterial extracellular polymeric substances (EPS) in metal adsorption was determined by studying Cd adsorption onto the gram-negative bacterial species Pseudomonas putida with and without enzymatic removal of EPS from the biomass material. A range of experimental approaches were used to characterize the Cd adsorption reactions, including bulk proton and Cd adsorption measurements, FTIR spectroscopy, and fluorescence microscopy. The proton-reactivities of the biomass samples with EPS are not significantly different from those obtained for EPS-free biomass. Similarly, the presence of EPS does not significantly affect the extent of Cd removal from solution by the biomass on a mass-normalized basis, based on bulk Cd adsorption measurements conducted as a function of pH, nor does it appear to strongly affect the Cd-binding groups as observed by FTIR. However, fluorescence microscopy indicates that Cd, although concentrated on cell walls, is also bound to some extent to EPS. Together, the results from this study suggest that the P. putida EPS can bind significant concentrations of Cd from solution, and that the nature and mass-normalized extent of the binding is similar to that of the cell wall. Therefore, the EPS-bearing systems do not exhibit enhanced mass-normalized removal of Cd from solution relative to the EPS-free systems. The presence of the EPS effectively increases the viability of cells exposed to aqueous Cd, likely due to sequestration of the Cd away from the cells due to Cd-EPS binding.     

Exsolution textures in orthopyroxene in aluminous granulites as indicators of UHT metamorphism: New evidence from the Eastern Ghats Belt, India

Highly aluminous orthopyroxene, coexisting with sapphirine, cordierite, sillimanite, quartz and garnet in various combinations, constitute granoblastic mosaic peak metamorphic assemblages in aluminous granulites from three localities in the Eastern Ghats Belt, India. Orthopyroxene contains four types of intergrowths: (a) involving sapphirine with or without cordierite, (b) involving spinel, but without sapphirine, (c) involving cordierite, but without sapphirine and spinel, and (d) involving garnet, without sapphirine, spinel or cordierite. On the basis of textural and compositional data, origin of the intergrowths is ascribed to breakdown of Mg-Tschermak component, locally also involving Fe- and Ti-Tschermak. An attempt is made to compute the “pre-breakdown” compositions of orthopyroxene by image analysis, which shows maximum Al₂O₃ content of 13.4 wt.% in the pristine orthopyroxene. Geothermometry, phase equilibria consideration and application of existing experimental data on alumina solubility in orthopyroxene coexisting with sapphirine and quartz, collectively indicate extreme thermal conditions of metamorphism (> 1000 °C) for the studied assemblages. This re-affirms the notion that Al₂O₃ solubility in orthopyroxene is the most powerful indicator of UHT metamorphism (Harley, S.L., 2004. Extending our understanding of ultrahigh temperature crustal metamorphism. J. Mineral. Petrol. Sci. 99, 140–158). The intergrowths are considered to have formed due to cooling from the thermal peak spanning a temperature range of approximately 150 °C. Appearance of diverse types of intergrowths is probably related to subtle differences in bulk composition, particularly Fe:Mg ratios.     

Age of the Solomon Sea Basin from magnetic lineations

Magnetic anomalies measured in the central to western half of the Solomon Sea, when considered with other magnetic data, reveal the existence of linear patterns. Magnetic lineation anomaly models of the Cenozoic, 65 to 0 Ma, suggest that an age between 34 and 28 Ma and a half-rate spreading speed of 5.8 cm/yr for the northern flank of a former spreading center best fits our present magnetic data in the Solomon Sea Basin. Heat flow and bathymetry data support this preferred model.     

Current observation system using ship drift and its applications in Kumano-nada and Enshu-nada Seas

A continuous observation system of ship drift of ferry boats was developed using Loran C, ship direction, ship speed and wind velocity measurement. A formula to estimate the wind-driven lateral drift of the boat is proposed, and a measuring system of the surface current is described, including a discussions on its usefullness to monitor day-to-day variations of the circulation patterns in the coastal boundary regions of the Kuroshio.This system was applied to observe variations of the circulation in the Kumano-nada, and Enshu-nada Seas south of Japan. Some preliminary results were obtained by using this system as well as other methods. This work focuses on the behavior of warm eddies in the Kumano-nada Sea. The surface current patterns that include these phenomena obtained by the use of the ship drift show good correspondence with currents and thermal structures observed with GEK, CTD, moored current meters and satellite thermal images.