Inflations prior to Vulcanian eruptions and gas bursts detected by tilt observations at Semeru Volcano,Indonesia

We examine the basic characteristics of inflations at Semeru Volcano, Indonesia, to clarify the pressurization process prior to two different styles of explosive eruptions: Vulcanian eruptions and gas bursts. Analysis of data obtained from tilt meters installed close to the active crater allows clarification of the common features and the differences between the two styles of eruptions. To improve the signal-to-noise ratio and to determine the mean characteristics of the inflations, we stack tilt signals obtained from eruptions of different magnitudes and evaluate the maximum amplitude of the seismic signal associated with these eruptions. Vulcanian eruptions, which explosively release large amounts of ash, are preceded by accelerating inflation about 200–300 s before the eruption, which suggests volume expansion of the gas phase. In contrast, gas bursts, which rapidly effuse water steam accompanied by explosive sounds, follow non-accelerating changes of inflation starting 20 s before each emission. Tilt amplitudes increase with the magnitude of eruptions for both eruption styles. This suggests that the volume and/or pressure of magma or gas stored in the conduit before eruptions controls the magnitude of volcanic eruptions. These results further suggest that the magnitude of eruptions can be predicted from geodetic measurements of volcano inflation.     

Relationship between trace elements and depositional environments in shallow sediments: a case study from Southern Kanto Plain,Central Japan

Underground developments such as subways and shopping facilities have been increasing in number and magnitude in the relatively shallow subsurface of many urban areas where the earth materials commonly are composed of marine sediments. Marine sediments can contain significant amounts of toxic trace elements such as arsenic, boron, and lead. Changes in the subsurface environment caused by excavation and construction in underground developments could potentially cause these toxic elements to be dissolved into pore water of the sediments, which might lead to groundwater pollution. The purpose of this study is to investigate correlations among chemical properties of marine sediments, such as pH and electrical conductivity (EC), concentrations of toxic trace elements, and stratigraphic characteristics of the sediments. We selected three sites with different stratigraphic settings in the southern Kanto Plain around the Tokyo Metropolis. We collected core samples from shallow strata at a site in the Arakawa Lowland, southern Saitama, and at two sites in the Musashino Upland, Middle Tokyo. All sites have both marine and non-marine sediments up to 50–60 m in thickness. We determined trace element concentrations in the pore water, pH, EC, and loss on ignition. The results show that (1) the marine sediments tend to have low pH, high EC, and high sulfur concentration compared to the non-marine sediments (2) the concentration of most of the soluble heavy metals vary depending on the concentration of sulfate, the pH, and the formation processes of the strata, (3) the arsenic concentration is not related to sulfur concentration but apparently to Fe and Al concentrations, (4) the boron concentration is not related to any other properties implying that the boron level is independent of and cannot be predicted by common chemical properties, and (5) for all three sites, concentrations of most of the trace elements, EC, pH, and sulfate concentration were correlated with each other. This study shows that the concentration and potential mobilization of many toxic trace elements in marine sediments could be predicted by easily measurable pore water chemical properties such as pH and EC. This could be useful for predicting and avoiding the risk of groundwater pollution during underground development projects.     

Cd adsorption onto Pseudomonas putida in the presence and absence of extracellular polymeric substances

The role of bacterial extracellular polymeric substances (EPS) in metal adsorption was determined by studying Cd adsorption onto the gram-negative bacterial species Pseudomonas putida with and without enzymatic removal of EPS from the biomass material. A range of experimental approaches were used to characterize the Cd adsorption reactions, including bulk proton and Cd adsorption measurements, FTIR spectroscopy, and fluorescence microscopy. The proton-reactivities of the biomass samples with EPS are not significantly different from those obtained for EPS-free biomass. Similarly, the presence of EPS does not significantly affect the extent of Cd removal from solution by the biomass on a mass-normalized basis, based on bulk Cd adsorption measurements conducted as a function of pH, nor does it appear to strongly affect the Cd-binding groups as observed by FTIR. However, fluorescence microscopy indicates that Cd, although concentrated on cell walls, is also bound to some extent to EPS. Together, the results from this study suggest that the P. putida EPS can bind significant concentrations of Cd from solution, and that the nature and mass-normalized extent of the binding is similar to that of the cell wall. Therefore, the EPS-bearing systems do not exhibit enhanced mass-normalized removal of Cd from solution relative to the EPS-free systems. The presence of the EPS effectively increases the viability of cells exposed to aqueous Cd, likely due to sequestration of the Cd away from the cells due to Cd-EPS binding.     

Stable isotope and chemical composition of pearls: Biomineralization in cultured pearl oysters in ago bay, Japan

The δ¹⁸O, δ¹³C and trace element composition of pearls collected from Ago Bay, Japan, were investigated in order to evaluate biomineralization in the cultured pearl oyster (Pinctada fucata martensii). The oxygen isotopic data suggest that the pearls were produced around 23–24°C, mainly in June to early July, which is consistent with their occurrence in the field. Therefore the pearls were produced under or close to isotopic equilibrium conditions, although they showed high calcification rates (higher than 0.2–1.0 g cm^{− 2}yr⁻¹) under which, for example, coral skeletons (calcification rate ∼0.28 g cm^{− 2}yr⁻¹) often show non-equilibrium isotope partitioning. The δ¹³C values were ∼− 2.9‰ lower than those calculated for offshore waters under equilibrium conditions. This may be due to low-δ¹³C bottom waters resulting from the degradation of organic matter (OM) or to a contribution of low-δ ¹³C food. In the latter case, a simple mass balance calculation gives a respiration component of 14%. Twelve trace elements of bulk pearl samples were classified into four groups on the basis of their enrichment/depletion patterns relative to seawater and inter-element relationships: group 1, Co, Cr, Pb; group 2, Ba, Cs, U; group 3, Cu, Sn, V, and group 4, Mn, Rb, Mo. Comparison with coral skeletons suggests that Ba and Mn (groups 2 and 4) were definitely much enriched in proteinaceous OM relative to aragonite crystals in pearls and that V (group 3) in pearls showed only slight enrichment in the organicrich layer. By contrast, the other elements showed small differences between both layers (enrichment factor of <3), suggesting that these elements occur largely in aragonite crystals.     

Clearcutting and pine planting effects on nutrient concentrations and export in two mixed use headwater streams: Upper Coastal Plain,Southeastern USA

Timber harvest temporarily increases water yield; however, relationships between hydrologic and nutrient chemistry changes have not been consistent. This study quantified the effects of forest harvesting and site preparation without fertilization and with modern best management practices on nutrient concentrations and yields in small headwater streams of the Southeastern Coastal Plain. We monitored two watershed pairs for 2 years prior to and 1 year following timber harvest and for 2 more years following site preparation and planting. Treatment watersheds were clearcut, and downstream portions of streamside management zones were thinned in Fall 2003. Site preparation (herbicide application and burning) and planting followed a year later. All operations followed 1999 Georgia forestry best management practices. Previously published research revealed a large increase in water yield following harvest. Nutrient concentrations varied significantly within and between monitoring periods, even in reference watersheds. Silvicultural activities had no discernible effect on phosphorus and ammonium concentrations; however, statistically significant increases in nitrate/nitrite (67–340 µg L⁻¹) and total nitrogen concentrations (100–400 µg L⁻¹) in treatment watersheds followed stand re‐establishment. Nutrient yields increased after timber harvest largely as a result of increased water yields, although increased nutrient yields were small relative to inter‐annual and inter‐watershed variability and variability. Annual water yield largely explained the variability in annual nitrogen and phosphorus export from reference and treatment streams (r² values from 0.65 to 0.98). High NO_x concentrations coming from an upstream agricultural area decreased 1600–1800 µg L⁻¹ over several hundred metres in the treatment streams by dilution, uptake or denitrification. Copyright © 2013 John Wiley & Sons, Ltd.     

Recursive evaluation of interaction forces of unbounded soil in the time domain from dynamic-stiffness coefficients in the frequency domain

The interaction forces of the linear unbounded soil in a non-linear soil-structure-interaction analysis can be calculated recursively, starting directly from the dynamic-stiffness coefficients in the frequency domain. Two possibilities of choosing a recursive equation are discussed.

• (i) The recursive equation in the frequency domain. For each frequency, the interaction force at a specific time station is expressed as a function of the corresponding interaction force at the previous time station and of the displacements at the current time station and at the two most recent past time stations. This recursive evaluation of the convolution integral. which can be derived using the z-transformation, is rigorous. By using interpolation in the frequency domain, an approximate procedure results, which leads to a significant reduction in computational effort.
• (ii) The recursive equation in the time domain. By approximating the dynamic-stiffness coefficients as the ratios of two polynomials in frequency using a curve-fitting technique based on the least-squares method and by applying the partial-fraction expansion and using the z-transformation, the recursive coefficients can be determined explicitly. Alternatively, the ratio of two polynomials can also be transformed to an ordinary differential equation together with the initial conditions.

The recursive equations using interpolation in the frequency domain and based on a ratio of two polynomials lead to a reduction in the computational effort of one and up to three orders of magnitude, respectively.     

Mechanisms controlling the seasonal mixed-layer temperature and salinity of the Indonesian seas

We examine the seasonal mixed-layer temperature (MLT) and salinity (MLS) budgets in the Banda–Arafura Seas region (120–138° E, 8–3° S) using an ECCO ocean-state estimation product. MLT in these seas is relatively high during November–May (austral spring through fall) and relatively low during June–September (austral winter and the period associated with the Asian summer monsoon). Surface heat flux makes the largest contribution to the seasonal MLT tendency, with significant reinforcement by subsurface processes, especially turbulent vertical mixing. Temperature declines (the MLT tendency is negative) in May–August when seasonal insolation is smallest and local winds are strong due to the southeast monsoon, which causes surface heat loss and cooling by vertical processes. In particular, Ekman suction induced by local wind stress curl raises the thermocline in the Arafura Sea, bringing cooler subsurface water closer to the base of the mixed layer where it is subsequently incorporated into the mixed layer through turbulent vertical mixing; this has a cooling effect. The MLT budget also has a small, but non-negligible, semi-annual component since insolation increases and winds weaken during the spring and fall monsoon transitions near the equator. This causes warming via solar heating, reduced surface heat loss, and weakened turbulent mixing compared to austral winter and, to a lesser extent, compared to austral summer. Seasonal MLS is dominated by ocean processes rather than by local freshwater flux. The contributions by horizontal advection and subsurface processes have comparable magnitudes. The results suggest that ocean dynamics play a significant part in determining both seasonal MLT and MLS in the region, such that coupled model studies of the region should use a full ocean model rather than a slab ocean mixed-layer model.     

Age of the Solomon Sea Basin from magnetic lineations

Magnetic anomalies measured in the central to western half of the Solomon Sea, when considered with other magnetic data, reveal the existence of linear patterns. Magnetic lineation anomaly models of the Cenozoic, 65 to 0 Ma, suggest that an age between 34 and 28 Ma and a half-rate spreading speed of 5.8 cm/yr for the northern flank of a former spreading center best fits our present magnetic data in the Solomon Sea Basin. Heat flow and bathymetry data support this preferred model.     

Future changes in tropical cyclone activity in the North Indian Ocean projected by high-resolution MRI-AGCMs

New and previous versions of the high-resolution 20- and 60-km-mesh Meteorological Research Institute atmospheric general circulation models are used to investigate potential future changes in tropical cyclone (TC) activity in the North Indian Ocean (NIO). Fifteen ensemble experiments are performed under the International Panel on Climate Change A1B scenario. Most of the ensemble future (2075–2099) experiments do not project significant future changes in the basin-scale TC genesis number; however, they commonly show a substantial increase (by 46 %) in TC frequency over the Arabian Sea and a decrease (by 31 %) in the Bay of Bengal. Projected future changes in TC genesis frequency show a marked seasonal variation in the NIO: a significant and robust reduction during the pre-monsoon season, an increase during the peak-monsoon season, and a westward shift during the post-monsoon season. Several large-scale thermodynamic and dynamical parameters are analysed to elucidate the physical mechanism responsible for the future changes in TC activity; this analysis reveals a seasonal dependence of the relative contribution of these parameters to the projected future changes in TC genesis frequency.