Structural changes of synthetic opal by heat treatment

The structural changes of synthetic opal by heat treatment up to 1,400 °C were investigated using scanning electron microscopy, X-ray diffraction, and Fourier transform infrared and Raman spectroscopies. The results indicate that the dehydration and condensation of silanol in opal are very important factors in the structural evolution of heat-treated synthetic opal. Synthetic opal releases water molecules and silanols by heat treatment up to 400 °C, where the dehydration of silanol may lead to the condensation of a new Si–O–Si network comprising a four-membered ring structure of SiO₄ tetrahedra, even at 400 °C. Above 600 °C, water molecules are lost and the opal surface and internal silanol molecules are completely dehydrated by heat effect, and the medium-temperature range structure of opal may begin to thermally reconstruct to six-membered rings of SiO₄ tetrahedra. Above 1,000 °C, the opal structure almost approaches that of silica glass with an average structure of six-membered rings. Above 1,200 °C, the opal changes to low-cristobalite; however, minor evidence of low-tridymite stacking was evident after heat treatment at 1,400 °C.     

Age, geology, geophysics, and geochemistry of Mahukona Volcano, Hawai`i

The size, shape, and magmatic history of the most recently discovered shield volcano in the Hawaiian Islands, Mahukona, have been controversial. Mahukona corresponds to what was thought to be a gap in the paired sequence (Loa and Kea trends) of younger Hawaiian volcanoes (<4?Ma). Here, we present the results of marine expeditions to Mahukona where new bathymetry, sidescan sonar, gravity data, and lava samples were collected to address these controversies. Modeling of bathymetric and gravity data indicate that Mahukona is one of the smallest Hawaiian volcanoes (～6,000?km³) and that its magmatic system was not focused in a long-lived central reservoir like most other Hawaiian volcanoes. This lack of a long-lived magmatic reservoir is reflected by the absence of a central residual gravity high and the random distribution of cones on Mahukona Volcano. Our reconstructed subsidence history for Mahukona suggests it grew to at least ～270?m below sea level but probably did not form an island. New ⁴⁰Ar–³⁹Ar plateau ages range from 350 to 654?ka providing temporal constraints for Mahukona’s post-shield and shield stages of volcanism, which ended prematurely. Mahukona post-shield lavas have high ³He/⁴He ratios (16–21?Ra), which have not been observed in post-shield lavas from other Hawaiian volcanoes. Lava compositions range widely at Mahukona, including Pb isotopic values that straddle the boundary between Kea and Loa sequences of volcanoes. The compositional diversity of Mahukona lavas may be related to its relatively small size (less extensive melting) and the absence of a central magma reservoir where magmas would have been homogenized.     

Nitrogen stable isotope ratio in the manila clam, Ruditapes philippinarum, reflects eutrophication levels in tidal flats

Understanding the effects of anthropogenic eutrophication on coastal fisheries may help in the enhancement of fishery production by effective utilization of sewage effluents, as well as in the consequent reduction of eutrophication. In this study, it was revealed that the nitrogen stable isotope ratio (δ¹⁵N) in the soft tissues of the manila clam, Ruditapes philippinarum, can be used as an indicator of anthropogenic eutrophication levels in tidal flat environments by investigation of δ¹⁵N in dissolved inorganic nitrogen (DIN), particulate organic matter (POM), sedimentary organic matter (SOM) and soft tissues of the clam in five tidal flats in Japan with different levels of DIN concentration. In addition, it was found that the acid insoluble fraction of the shell organic matrix, conchiolin, can be used as a proxy for the soft tissues in δ¹⁵N analyses. This will contribute in easier storage handling and the expansion of chances for sample acquisition.     

1993年8月8日关岛地震前后ULF磁场异常变化

给出了1993年8月8日关岛地震(Ms=7.1,深度60km)前后ULF(Ultra Low Frequency:超低频信号,频段为O.005～10Hz)地磁信号的分析结果.ULF观测系统位于日本关岛,距离震中约65km.对观测数据进行分析后得出以下结论:①建议用非常细致的统计分析(月均值,标准偏差)来判断ULF信号的强度和极化值(比如:Z/H比值);②ULF信号活动强度和∑Kp的对比,有助于区别空间地磁脉动和非空间源地磁辐射;③发现Z/H比值的使用在把可能来自震源的辐射从空间等离子波中识别出来非常重要;④从对极化值的时间序列的统计分析发现极化值在震前仅一个月时有一个显著的增强,表明这期间的电磁异常现象很可能是震磁前兆信号;⑤Z分量的时间变化类似于Loma Prieta地震前的变化,即在震前10天到两周有明显的增强,在震前几天出现另一次增强;⑥可能与地震有关的电磁辐射是一种类似噪音的自然现象,它们的主要频带范围0.02～0.05Hz(最大幅值约为0.1nT).     

Damping systems that are effective over a wide range of displacement amplitudes using metallic yielding component and viscoelastic damper in series

A damper system that absorbs energy over a wide range of displacement amplitudes during building vibration was proposed. This system uses a serial connection of a metallic yielding component and viscoelastic damper with a displacement limit mechanism. Three types of the system were developed and tested: a diagonal bracing type, inverted V bracing type, and wall type. The test results showed that all these systems have damping ratios higher than 8% at small vibration amplitudes on the order of 0.1 mm. For a large vibration, a displacement limit mechanism with two pins limited the displacement of the viscoelastic damper as designed. Analytical simulations established that the system reduced the acceleration and the story drift to 60–70% and 80%, respectively, during a small earthquake compared with a conventional metallic yielding damper system. Furthermore, it showed an equivalent control performance during a severe earthquake. The damper system requires that a clearance be maintained for the displacement limit mechanism. However, this may be lost through construction error, residual displacement after an earthquake, and temperature effects. The changes in the clearance due to these effects were discussed. Copyright © 2014 John Wiley & Sons, Ltd.     

Effects of Bathymetric Grid-Cell Sizes on Habitat Suitability Analysis of Cold-water Gorgonian Corals on Seamounts

We investigated the effects of the spatial resolution of bathymetry data on the predicted local distribution of large gorgonian corals on the southern Emperor Seamounts in the high seas of North Pacific. Terrain attributes were calculated from bathymetric survey data at six different grid-cell sizes (25–800 m) to investigate how the values of bottom terrain attributes and the prediction of MaxEnt habitat suitability models would vary with grid-cell size. The values of each terrain attribute showed different patterns among different grid-cell sizes, and MaxEnt demonstrated better performance at grid-cell size of 100 m or less than at larger sizes.     

Presence of high nitrate to phosphate ratio subsurface water in the Tsushima Strait during summer

To identify water with an excess nitrate concentration to phosphate ratio and its potential source, the nutrient concentrations in the Tsushima Strait (TSS) were investigated over ten cruises in August and September 2007–2014, excluding 2010. On the basis of the Redfield ratio, water with an excess nitrate concentration of >1 μM (positive ExNOx water) was identified below the surface mixed layer during four cruises in 2011–2013. Positive ExNOx water was present mainly in less-saline (<34) waters with a density of 22–25 σ _θ , and 25–75 m depth. However, in August 2012, positive ExNOx was detected in dense (25–25.5 σ _θ ) and deep (50–110 m depth) waters near the salinity maximum, although the salinity during this period was significantly lower than that in other years. The horizontal length of positive ExNOx water was >100 km across the TSS during two cruises in August 2012 and September 2013, respectively. According to multi-regression analysis conducted on the silicate concentration, temperature, and salinity, the silicate concentration was increased in the less-saline subsurface water. The required amount of original freshwater was 10^8–9 m³ day^?1 based on the excess nitrate concentration. This evidence indicates that the positive ExNOx water originated from large river waters such as the Changjiang. Thus, discharged water from the rivers of the East Asia is contributing to the increased N:P ratio in the Tsushima Warm Current, southern Japan Sea.     

Decline in radiocesium in seafloor sediments off Fukushima and nearby prefectures

Radioactivity has been monitored in seafloor sediments off Fukushima and nearby prefectures regularly. During the initial monitoring period (May–September 2011), ¹³⁷Cs concentrations in the surface sediments (0–3 cm) generally increased to 8–580 Bq/kg. Subsequently, concentrations decreased at variable rates. In the latest data, from February 2016, concentrations were still higher at 0.8–141 Bq/kg than the pre-accident level. The geometric mean concentration declined steadily from 47 Bq/kg in September 2011 to 13 Bq/kg in February 2016. The ¹³⁷Cs abundance (Bq/m²) in the surface sediment at each station decreased similarly. The rate of decrease of surface abundance varied spatially by almost one order of magnitude, ranging from 1.1 × 10^?4 to 1.7 × 10^?3/day, equivalent to halving times of 16–1.1 years, respectively. The rate of decrease was related to the median sediment grain size at each station. In addition, bottom-water dynamics, through the redistribution of bottom sediments, may have caused spatial variability in the rate of decrease, whereas vertical profiles of ¹³⁷Cs concentrations in the sediment suggest that vertical migration of ¹³⁷Cs was not a major mechanism reducing the surface ¹³⁷Cs concentration. From September 2011 to February 2016, the overall halving time of ¹³⁷Cs in the surface sediment in the monitoring area, excluding the area inside a 30-km radius from the Fukushima Dai-ichi Nuclear Power Plant, was 2.3 years. Thus, 76% of the originally deposited ¹³⁷Cs (46 × 10¹² Bq) in the surface sediment was transported out of the area during that period.     

Relationship between trace elements and depositional environments in shallow sediments: a case study from Southern Kanto Plain,Central Japan

Underground developments such as subways and shopping facilities have been increasing in number and magnitude in the relatively shallow subsurface of many urban areas where the earth materials commonly are composed of marine sediments. Marine sediments can contain significant amounts of toxic trace elements such as arsenic, boron, and lead. Changes in the subsurface environment caused by excavation and construction in underground developments could potentially cause these toxic elements to be dissolved into pore water of the sediments, which might lead to groundwater pollution. The purpose of this study is to investigate correlations among chemical properties of marine sediments, such as pH and electrical conductivity (EC), concentrations of toxic trace elements, and stratigraphic characteristics of the sediments. We selected three sites with different stratigraphic settings in the southern Kanto Plain around the Tokyo Metropolis. We collected core samples from shallow strata at a site in the Arakawa Lowland, southern Saitama, and at two sites in the Musashino Upland, Middle Tokyo. All sites have both marine and non-marine sediments up to 50–60 m in thickness. We determined trace element concentrations in the pore water, pH, EC, and loss on ignition. The results show that (1) the marine sediments tend to have low pH, high EC, and high sulfur concentration compared to the non-marine sediments (2) the concentration of most of the soluble heavy metals vary depending on the concentration of sulfate, the pH, and the formation processes of the strata, (3) the arsenic concentration is not related to sulfur concentration but apparently to Fe and Al concentrations, (4) the boron concentration is not related to any other properties implying that the boron level is independent of and cannot be predicted by common chemical properties, and (5) for all three sites, concentrations of most of the trace elements, EC, pH, and sulfate concentration were correlated with each other. This study shows that the concentration and potential mobilization of many toxic trace elements in marine sediments could be predicted by easily measurable pore water chemical properties such as pH and EC. This could be useful for predicting and avoiding the risk of groundwater pollution during underground development projects.