Geochemical characteristics of Tertiary oils derived from siliceous sources in Japan, Russia and U.S.A.

Siliceous sourced Tertiary oils from the Circum-Pacific area of Japan, Russia and the U.S.A. have a heavy carbon isotope composition, monomodal n-alkane distributions, and nearly identical regular sterane compositions with a predominance of C₂₇ homologues. These are consistent with open marine depositional environments dominated by diatomaceous organic matter. However, a number of alkane and biomarker parameters such as Pr/Ph, CPI, relative concentration of 28,30-bisnorhopane, and the C₃₅/C₃₄ homohopane ratio indicate more oxic depositional environments for the source rocks of Japan and Russia. In contrast to the California Monterey Formation sourced oils, petroleums with low maturity levels from the North Sakhalin basin, Russia and the Akita basin, Japan have lower concentrations of asphaltenes and sulphur and are characterized by higher API gravities. A correlation of extractable organic matter from source rocks vs the least matured petroleums demonstrates that oil expulsion in siliceous shales of the Akita basin occurs at a maturity level corresponding to R_o≥0.65%, which is in the range of the conventional oil window (R_o = 0.6−1.1%).     

Notes on extended–range atmospheric prediction in the Northern Hemisphere winter

We examined the characteristic feature and predictability of low frequency variability (LFV) of the atmosphere in the Northern Hemisphere winter (January and February) by using the empirical orthogonal functions (EOFs) of the geopotential height at 500 hPa. In the discussion, we used the EOFs for geostrophic zonal wind (Uznl) and the height deviation from the zonal mean (Zeddy). The set of EOFs for Uznl and Zeddy was denoted as Uznl-1. Uznl-2, …, Zeddy-1, Zeddy-2…, respectively. We used the data samples of 396 pentads derived from 33 years of NMC, ECMWF and JMA analyses, from January 1963 to 1995. From the calculated scores for Uznl-1, Uznl-2, Zeddy-1, Zeddy-2 and so on we found that Uznl-1 and Zeddy-1 were statistically stable and their scores were more persistent than those of the other EOFs. A close relationship existed between the scores of Uznl-1 and those of Zeddy-1 30-day forecast experiments were carried out with the medium resolution version of JMA global spectral model for 20 cases in January and February for the period of 1984-1992. Results showed that Zeddy-1 was more predicta?ble than the other EOFs for Zeddy Considering these results, we argued that prediction of the Zeddy-1 was to be one of the main target of extended range forecasting     

Fluctuation in volume transport distribution accompanied by the Kuroshio front migration in the Tokara Strait

A relation between migration of the Kuroshio front and fluctuation of distribution of volume transport in the Tokara Strait was described, using sea level records at five tide gauge stations around the strait and data which were composed of sea surface temperature, XBT casts, sea surface salinity and velocities at 20 m, 75 m and 150 m depths taken en route a ferryboat. The Kuroshio front extends to about 150 m depth. The sea surface salinity and the horizontal velocities abruptly change at the front. There is a good correlation in a period range from half a month to two months between the migration of the front, which is not only at the surface but also in the subsurface, and the sea level fluctuation at Nakano-shima. A northward migration of the front with a period range from 17 to 50 days decreases the transport in the southern strait between Naze and Nakano-shima but increases in the northern strait between Nakano-shima and Sata-misaki. The northward migration intensifies inflow into Kagoshima Bay and the Ohsumi Branch Current. Correlation between the transport in the northern strait and the Ohsumi Branch Current is significant in the period range from 30 to 50 days. In this significant period range, the former leads the latter by about 3 days.     

Dredge petrology of the boninite‐ and adakite‐bearing Hahajima Seamount of the Ogasawara (Bonin) forearc: An ophiolite or a serpentinite seamount?§

Abstract During the Hakuho‐Maru KH03‐3 cruise and the Tansei‐Maru KT04‐28 cruise, more than 1000 rock samples were dredged from several localities over the Hahajima Seamount, a northwest–southeast elongated, rectangular massif, 60 km × 30 km in size, with a flat top approximately 1100 m deep. The rocks included almost every lithology commonly observed among the on‐land ophiolite outcrops. Volcanic rocks included mid‐oceanic ridge basalt (MORB)‐like tholeiitic basalt and dolerite, calc‐alkaline basalt and andesite, boninite, high‐Mg adakitic andesite, dacite, and minor rhyolite. Gabbroic rocks included troctolite, olivine gabbro, olivine gabbronorite (with inverted pigeonite), gabbro, gabbronorite, norite, and hornblende gabbro, and showed both MORB‐type and island arc‐type mineralogies. Ultramafic rocks were mainly depleted mantle harzburgite (spinel Cr? 50–80) and its serpentinized varieties, with some cumulate dunite, wehrlite and pyroxenites. This rock assemblage suggests a supra‐subduction zone origin for the Hahajima Seamount. Compilation of the available dredge data indicated that the ultramafic rocks occur in the two northeast–southwest‐oriented belts on the seamount, where serpentinite breccia and gabbro breccia have also developed, but the other areas are free from ultramafic rocks. Although many conical serpentinite seamounts 10 km in size are aligned along the Izu–Ogasawara (Bonin)–Mariana forearc, the Hahajima Seamount may be better interpreted as a fault‐bounded, uplifted massif composed of ophiolitic thrust sheets, resembling the Izki block of the Oman ophiolite in its shape and size. The ubiquitous roundness of the dredged rocks and their thin Mn coating (<2 mm) suggest that the Hahajima Seamount was uplifted above sealevel and wave‐eroded, like the present Macquarie Is., a rare example of ophiolite exposure in an oceanic setting. The Ogasawara Plateau on the Pacific Plate is adjacent to the east of the Hahajima Seamount, and collision and subduction of the plateau may have caused uplift of the forearc ophiolite body.     

Paleointensity determination by a modified thellier method

It has been frequently observed that the ferromagnetic minerals in volcanic rocks may undergo some physical/chemical changes when they are heated in a laboratory. For paleointensity determinations, it is therefore desirable to use the Thellier method, in which internal consistency of the data assures that such undesirable changes did not take place in a particular sample. The most serious drawback of this method is that it requires a considerable number of heatings and coolings and measurements of the remanent magnetization. Following a suggestion of Kono, a modified version of Thellier's technique was developed and applied to a historical lava flow of Hawaii and Oligocene rhyolites and welded tuffs of San Juan volcanic field, Colorado, U.S.A. Samples were heated only once to each temperature and cooled under a magnetic field applied perpendicular to the NRM directions. Results were compared to those obtained by the conventional Thelliers' technique. It was found that the modified method gives results as satisfactory as the original method. With the selection of appropriate samples, the modified method will cut down the time required for the experiment to almost half of what is required in the original method, without losing the merits of Thelliers' technique.     

Stratospheric ozone response to a solar proton event: Hemispheric asymmetries

Ozone depression in the polar stratosphere during the energetic solar proton event on 4 August 1972 was observed by the backscattered ultraviolet (BUV) experiment on the Nimbus 4 satellite. Distinct asymmetries in the columnar ozone content, the amount of ozone depressions and their temporal variations above 4 mb level (38 km) were observed between the two hemispheres. The ozone destroying solar particles precipitate rather symmetrically into the two polar atmospheres due to the geomagnetic dipole field These asymmetries can be therefore ascribed to the differences mainly in dynamics and partly in the solar illumination and the vertical temperature structure between the summer and the winter polar atmospheres. The polar stratosphere is less disturbed and warmer in the summer hemisphere than the winter hemisphere since the propagation of planetary wave from the troposphere is inhibited by the wind system in the upper troposphere, and the air is heated by the prolonged solar insolation. Correspondingly, the temporal variations of stratospheric ozone depletion and its recovery appear to be smooth functions of time in the (northern) summer hemisphere and the undisturbed ozone amount is slighily, less than that of its counterpart. On the other hand, the tempotal variation of the upper stratospheric ozone in the winter polar atmosphere (southern hemisphere) indicates large amplitudes and irregularities due to the disturbances produced by upward propagating waves which prevail in the polar winter atmosphere. These characteristic differences between the two polar atmospheres are also evident in the vertical distributions of temperature and wind observed by balloons and rocker soundings.     

Monitoring system for environmental risk management of a landfill disposal site

A landfill disposal site can be described as “an artificial vessel” and must satisfy the following three demands (1) storage and disposal of waste; (2) protection of the environment; and (3) benefit for nearby residents by taking advantage of consequential effects. The concept of risk was effectively considered to emphasize the importance of monitoring systems in landfill disposal sites, especially to protect the environment. Because a part of the R&D was involved in creating a monitoring system for a landfill disposal site, the present development and future potential of a system which can detect the leakage of watershield sheets, was discussed.