Possibility of recent changes in vertical distribution and size composition of chlorophyll-a in the western North Pacific region

Our analysis of the last three decades of retrospective data of vertical distributions and size composition of chlorophyll-a (Chl-a) over the western North Pacific has revealed significant changes of three indices related to Chl-a during summer season, as follows: (1) decreasing linear trend of the proportion of Chl-a in surface layer to that of the whole water column by 0.4 and 2.3% year⁻¹ in the subtropical area along 137°E (STA₁₃₇) during 1972 to 1997 and in the Kuroshio Extension area along 175°E (KEA₁₇₅) during 1990 to 2001; (2) increasing linear trend of the depth of subsurface Chl-a maximum (DCM) by 0.4 and 2.6 m year⁻¹ in STA₁₃₇ and KEA₁₇₅; and (3) decreasing linear trend of larger-size Chl-a (>3 μm) by 0.1 and 2.5% year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. Water density (σ _θ ) at 75 m depth had also decreased by 0.006 and 0.05 year⁻¹ in STA₁₃₇ and KEA₁₇₅, respectively. The ratio of biogenic opal to biogenic CaCO₃ in the sinking flux decreased by 0.015 year⁻¹ in the subtropical region from 1997 to 2005. These findings may indicate that the subsurface chlorophyll maximum is deepening and larger phytoplankton such as diatoms has been decreasing during the past decade, associated with the decreasing density of surface water caused by warming in the western North Pacific, especially in the summer.     

Traveling wave effects on a tall and narrow building: Observation and analysis

The purpose of this paper is to investigate the seismic response of a tall and narrow building, for example, a turbine building of thermal power plant, due to a traveling shear wave. It is considered that the dynamic response of the building can be affected by the spatial variance of seismic ground motion, because the building has a long-shaped foundation (43 meters wide by 343 meters long by 4 meters thick). First, analytical study was conducted using obliquely incident harmonic motion. And comparing the earthquake response observed at different points of foundation slab, it was found that the response at the end point where input wave reaches later is larger than that at the other end. From these studies, it was assured that the antisymmetric mode, which can be neglected in ordinary analysis, is excited by phase difference of input motion.     

Paleomagnetic study of Cretaceous rocks of Peru, South America: Evidence for rotation of the Andes

Paleomagnetic data for the Cretaceous volcanic and sedimentary rocks in the Andean region of Peru are given. Reliable paleomagnetic field directions were obtained for three Cretaceous (Albian to Cenomanian) formations from calcareous sediments in northern Peru. Stable remanent magnetization directions were also derived from twelve Cretaceous lava flows and dikes in coastal Peru. Paleomagnetic data of the same age from the stable areas of South America such as Brazil demonstrate that the paleomagnetic poles are nearly coincident with the present pole, but Peruvian paleomagnetic directions studied here showed several tens of degrees of counterclockwise declination shifts. This suggests counterclockwise tectonic rotation of an extensive block which includes the whole of Andean Peru.     

软岩的强度—变形—时间之间关系的试验分析

对软岩和有不连续面的软岩试样进行一系列固结不排水三轴压缩和蠕变试验,测定并分析了它们在正常固结和超固结状态下的应变软化性状、蠕变特性和残余强度的变化规律。探讨了软岩中存在的不连续面对应力－应变关系、残余强度特性和蠕变应变速率的影响。     

Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.     

Coastal aquifer system in late Pleistocene to Holocene deposits at Horonobe in Hokkaido,Japan

The groundwater flow systems and chemistry in the deep part of the coastal area of Japan have attracted attention over recent decades due to government projects such as geological disposal of radioactive waste. However, the continuous groundwater flow system moving from the shallow to deep parts of the sedimentary soft rock has not yet been characterized. Therefore, the Cl^–, δD and δ¹⁸O values of the pore water in the Horonobe coastal area in Hokkaido, Japan, were measured to 1,000 m below the ground surface, and a vertical profile of the pore-water chemistry was constructed to assist in elucidating groundwater circulation patterns in the coastal area. The results show that the groundwater flow regime may be divided into five categories based on groundwater age and origin: (1) fresh groundwater recharged by modern rainwater, (2) fresh groundwater recharged by paleo rainwater during the last glacial age, (3) low-salinity groundwater recharged during the last interglacial period, (4) mixed water in a diffusion zone, and (5) connate water consisting of paleo seawater. These results suggest that the appearance of hydrological units is not controlled by the boundaries of geological formations and that paleo seawater is stored in younger Quaternary sediments.     

North-south asymmetries of solar particle events in upper stratospheric ozone

Stratospheric ozone depressions, following intense solar particle events (SPE) observed by the backscattered ultraviolet (BUV) experiment on the Nimbus-4 satellite, indicate the existence of distinct asymmetries between the Northern and Southern Hemispheres. These asymmetries are observed in the magnitude of the depressions above the 5-mb level, their temporal variations, and the spatial (i.e., latitude and longitude) dependence of these variations. Possible causes of asymmetries, shown by two events on 4 August 1972 and 25 January 1971, can be attributed to: (1) tilt of the interplanetary magnetic field (IMF) with respect to the Earth's dipole magnetic field which influences the precipitation of energetic solar particles into the polar atmospheres; (2) differences in ozone chemistry caused by the large change in atmospheric temperature between summer and winter hemispheres; (3) seasonal differences of the stratosphere's dynamic states which are affected by upward propagating planetary waves in winter in contrast to the relatively undisturbed zonal flow in summer; (4) topographic asymmetry between Northern and Southern Hemispheres.These effects are shown by three-dimensional plots of the events in geographic coordinates and by color contour plots of the stratospheric ozone distributions in geomagnetic and geographic polar coordinates, respectively.     

Preliminary Results from the Magnetic Field Measurements Using MAGDAS at Ilorin, Nigeria

MAGDAS, the Magnetic Data Acquisition System, was successfully installed at the University of Ilorin, Nigeria—an equatorial station—in August 2006. MAGDAS is an important component of the International Heliophysical Year, IHY. We examined the preliminary results obtained from the analysis of the geomagnetic data obtained from the MAGDAS measurement. Diurnal variations of the solar quiet daily variation in the three geomagnetic elements, H, D, Z were studied. The obtained signatures of the magnetic field variations were discussed in the context of the literature. The day-to-day variability of the horizontal and vertical intensities as well as the declination of the geomagnetic field were examined. The study justified the need for a partner magnetic field observatory along same meridian as Ilorin, north or south of it, to facilitate synthesis of the equatorial electrojet effect.