Onboard experiment investigating metal leaching of fresh hydrothermal sulfide cores into seawater

We observed the initial release rate of metals from four fresh (i.e., without long time exposure to the atmosphere) hydrothermal sulfide cores into artificial seawater. The sulfide samples were collected by seafloor drilling from the Okinawa Trough by D/V Chikyu, powdered under inert gas, and immediately subjected to onboard metal-leaching experiments at different temperatures (5 °C and 20 °C), and under different redox conditions (oxic and anoxic), for 1–30 h. Zinc and Pb were preferentially released from sulfide samples containing various metals (i.e., Mn, Fe, Cu, Zn, Cd, and Pb) into seawater. Under oxic experimental conditions, Zn and Pb dissolution rates from two sulfide samples composed mainly of iron disulfide minerals (pyrite and marcasite) were higher than those from two other sulfide samples with abundant sphalerite, galena, and/or silicate minerals. Scanning electron microscopy confirmed that the high metal-releasing sample contained several galvanic couples of iron disulfide with other sulfide minerals, whereas the low metal-releasing sample contained fewer galvanic couples or were coated by a silicate mineral. The experiments overall confirmed that the galvanic effects with iron disulfide minerals greatly induce the initial release of Zn and Pb from hydrothermal sulfides into seawater, especially under warm oxic conditions.     

Investigation on the Performance of Pipe Roof Method Adjacent to the Underground Construction

In this paper, the behaviour of the pipe roof method with different pipe roofs disposition schemes including the pipe roof gate system and L-shaped system is discussed in terms of ground settlement reduction in the condition of underground space construction adjacent to the existing structure by using numerical simulation method. Considering the construction sequences of parallel underground tunnels with rectangular cross sections, the appropriate parameters and ground response characteristics of the corresponding pipe roof methods are evaluated by the ground surface displacement. The results indicated that the construction impacts from new buildings can be reduced by the pipe roof method. However, the theoretical performance of pipe roofs is highly dependent on the spacing between two structures. Generally, the L-shaped system is more effective in case of the distance (D) that is less than or equal to 1/2 width of box culvert (R) under the condition of a new structure constructed nearby the existing building. When two structures are constructed simultaneously, the excavation and the construction of structures influence each other reciprocally. The conclusions could provide a reference for the pipe roof method with the application scenario of adjacent building protection.

     

Effects of spatial variation of soil properties on seismic performance of port structures

From past seismic events such as the 1995 Kobe (Hyogoken-Nanbu) and 2001 Nisqually earthquakes, it was found that liquefaction-induced lateral spread has caused significant damage to structures such as buildings and bridges, in addition to underground utility facilities like pipelines. In this respect, seaport facilities are particularly vulnerable to these liquefaction-related damages, because they are usually constructed on poorly consolidated natural deposit or fills. This study investigates the effect of the liquefaction and lateral spread on the seismic response of caisson type quay walls. For this purpose, 2D nonlinear dynamic analyses of soil–structure system are carried out with the aid of finite difference software, FLAC. The unique feature of this study lies in the fact that the 2D soil system is idealized as homogeneous non-Gaussian random field. A simulation algorithm is then used to generate a set of digital realizations of 2D random field sample. Each realization is used for the dynamic analysis to generate a unique response of the soil–structure system. Repeating this analysis for the entire set of realizations, the probabilistic nature of the response is characterized in the Monte Carlo sense. This result based on random field is compared with the response obtained under the uniform field assumption with the mean value of soil property. The comparison shows that in general the uniform model provides unconservative result compared with the response from the random field model due to nonlinear behavior of the soil–structure system. It is also found that the consideration of spatial variation of soil can capture the dispersion of observed response of quay walls.     

Depositional ages and characteristics of Middle–Upper Jurassic and Lower Cretaceous lacustrine deposits in southeastern Mongolia

Lower Cretaceous lacustrine oil shales are widely distributed in southeastern Mongolia. Due to the high organic carbon content of oil shale, many geochemical studies and petroleum exploration have been conducted. Although most of the oil shales are considered to be Early Cretaceous in age, a recent study reveals that some were deposited in the Middle Jurassic. The present study aims at establishing depositional ages and characteristics of the Jurassic and Cretaceous lacustrine deposits in Mongolia. The Lower Cretaceous Shinekhudag Formation is about 250 m thick and composed of alternating beds of shale and dolomite. The Middle Jurassic Eedemt Formation is about 150 m thick and composed of alternating beds of shale, dolomitic marl, and siltstone. The alternations of shale and dolomite in both formations were formed by lake level changes, reflecting precipitation changes. Shales were deposited in the center of a deep lake during highstand, while dolomites were formed by primary precipitation during lowstand. Based on the radiometric age dating, the Shinekhudag Formation was deposited between 123.8 ±2.0 Ma and 118.5 ±0.9 Ma of the early Aptian. The Eedemt Formation was deposited at around 165–158 Ma of Callovian–Oxfordian. The calculated sedimentation rate of the Shinekhudag Formation is between 4.7 ±2.6 cm/ky and 10.0 ±7.6 cm/ky. Shales in the Shinekhudag Formation show micrometer‐scale lamination, consisting of algal organic matter and detrital clay mineral couplets. Given the average thickness of micro‐laminae and calculated sedimentation rate, the micro‐lamination is most likely of varve origin. Both Middle–Upper Jurassic and Lower Cretaceous lacustrine oil shales were deposited in intracontinental basins in the paleo‐Asian continent. Tectonic processes and basin evolution basically controlled the deposition of these oil shales. In addition, enhanced precipitation under humid climate during the early Aptian and the Callovian–Oxfordian was another key factor inducing the widespread oil shale deposition in Mongolia.     

A Raman spectroscopic study of shock-wave densification of anorthite (CaAl2Si2O8) glass

Structural modifications induced by shock-wave compression up to 40 GPa in anorthite glass are investigated by Raman spectroscopy. In the first investigation, densification increases with increasing shock pressure. A maximum densification of 2.2% is obtained for a shock pressure of 24 GPa. This densification is attributed to a decrease of the average ring size, favoring three-membered rings. The densification is much lower than in silica glass subject to shock at similar pressures (11%), because the T-O-T bond angle decrease is impeded in anorthite glass. For higher shock pressures, the decrease of the recovered densification is attributed to partial annealing of the samples due to high after-shock residual temperatures. The study of the annealing process of the most densified glass by in-situ high temperature Raman spectroscopy confirms that relaxation of the three-membered rings occurs above about 900 K. Received: 21 July 1998 / Revised and accepted: 27 January 1999     

实验变形岩石低温破裂作用的微观机制

通过对湿度和压力分别达300℃和3GPa干条件下实验变形的一系列花岗岩样品的系统光学和扫描电镜显微构造分析,识别出了几种具有不同特点及不同变形机制的显微破裂型式:a.微破碎带;b.微透镜带;c.短程破裂;d.扭折带破裂;e.粒内破裂;f.颗粒边界破裂。评价了它们与高压型和低压型破裂的显微构造对应性,认为a和f是低压破裂的特征性构造型式;b、c和d在高压破裂中最为典型;而e则可以出现在两种破裂型式中。本文阐述了破裂作用的微观机制,包括破裂的成核、扩展、生长和连接。破裂作用、由破裂诱发的脆性破裂和碎裂流动在目前实验变形条件下占主导地位,而在相对较高温条件下晶质塑性也起着一定的作用。破裂作用的成核可以始于颗粒边界,而引起摩擦颗粒边界滑移,也可以始于相邻颗粒或晶内包体颗粒的一些端点,或始于晶内双晶和解理面。破裂的生长和扩展一般是由于一些破裂的侧向延伸、相近破裂系统的联合和不同破裂系统的转变。低压样品的最终破裂一般归咎于一些贯穿性微断层的出现及主断层附近微破裂群的产生,微破碎角砾岩是其主要构造岩类型,类似于天然张性断层带构造;而沿主高压破裂附近却从未见到这种微破裂群的出现,主要表现为主破裂面及一些均匀分布的短程破裂构造, 典型构造岩为构造透镜体, 类似于天然压性与压扭性断层构造。两种破裂在成核、扩展与位移发育诸方面表现出的差别有助理解它们在声发射方面的差异。     

Biomarker records from core GH02-1030 off Tokachi in the northwestern Pacific over the last 23,000 years: Environmental changes during the last deglaciation

We investigated marine and terrestrial environmental changes at the northern Japan margin in the northwestern Pacific during the last 23,000 years by analyzing biomarkers (alkenones, long-chain n-alkanes, long-chain n-fatty acids, and lignin-derived materials) in Core GH02-1030. The U ₃₇^K′-derived temperature in the last glacial maximum (LGM) centered at 21 ka was ∼10°C, which was 2°C lower than the core-top temperature (∼12°C). This small temperature drop does not agree with pollen evidence of a large air temperature drop (more than 4°C) in the Tokachi area. This disagreement might be attributed to a bias of U ₃₇^K′-derived temperature within 2.5°C by a seasonal shift in alkenone production. The U ₃₇^K′-derived temperature was significantly low during the last deglaciation. Because this cooling was significant in the Kuroshio-Oyashio transition zone, the temperature drops are attributable to the southward displacement of the Kuroshio-Oyashio boundary. Abundant lignin-derived materials, long-chain n-alkanes and long-chain n-fatty acids indicate a higher contribution of terrigenous organic matter from 17 to 12 ka. This phenomenon might have resulted from an enhanced coastal erosion of terrestrial soils due to marine transgression and/or an efficient inflow of higher plant debris to river waters from 17 to 12 ka.     

Particle size effect on the saturation of methane hydrate in sediments – Constrained from experimental results

Except for those occurring at seafloor, most of natural gas hydrate form in sediments and are subject to the influence of sediment. Among these factors, the particle size effect on hydrate saturation level in sediment have been studied with a series of silica sands with various sizes, and the results obtained clearly indicate that particle size does play an important role in affecting the saturation level of hydrate in sediments. The proton relaxation times of water confined in the same series of silica sands, which were determined with NMR measurement, show logarithmic relationship with particle size. By comprehensive consideration of the results of hydrate saturation and water proton relaxation times, the particle size effect observed is tentatively explained by the water availability for hydrate formation in sediments.