Geochemical assessment of arsenic contamination in well water and sediments from several communities in the Nawalparasi District of Nepal

Arsenic contamination of well water is a serious issue in the Nawalparasi District of the Terai region in Nepal. A local investigation was carried out on 137 tube wells in 24 communities of the district in December 2011. The investigation revealed that the average arsenic concentration in the tube wells was 350 μg/L, and that nearly 98 % of the wells exceeded the WHO guideline arsenic level limit of 10 μg/L. Highly contaminated well water, with more than 400 μg/L of arsenic, was found within the limited depth ranges of 18–22 and 50–80 m. High arsenic levels exceeding 500 μg/L were detected in shallower wells at Patkhauli, Mahuawa, Thulokunwar, and Goini located between 27.517° and 27.543°N and between 83.648° and 83.748°E. Boring sampling at five communities of Kashiya, Goini, Sanokunwar, Thulokunwar, and Mahuawa revealed two aquifers located at the two depths around 14–22 and 41–50 m in each community. Dark gray or black-colored peaty clay layers rich in organic matter were distributed at depths of 18–21 m beside the upper aquifers with high arsenic concentration in each community. Positive correlations were shown between iron and arsenic in the sediments from the five communities. It can be inferred that these results were caused by dissolution of iron-oxyhydroxide molecules with arsenic from solid phases. Microbial metabolisms have a great potential to induce the dissolution and release arsenic attached on the solid phases into aqueous phases depending on the level of redox potential and pH.     

Transit time evaluation using a chloride concentration input step shift after forest cutting in a Japanese headwater catchment

Mean transit times were estimated for a small headwater catchment in Japan (the Fukuroyamasawa Experimental Watershed) using the step shift in input chloride (Cl^?) concentrations that occurred immediately after an episode of forest clear‐cutting. Measured Cl^? concentrations in stream water began to decrease immediately after clear‐cutting, and this trend continued for 6 years. Before clear‐cutting, the input Cl^? concentrations were controlled by wet and dry deposition processes, and most of the dry Cl^? deposition was collected by the forest canopy and reached the ground as throughfall and stemflow. After clear‐cutting, dry deposition was no longer collected by the canopy in this way, thus causing a sharp decrease in input Cl^? concentrations. By comparing measured Cl^? concentrations in stream water with estimates based on the input and evaporative Cl^? concentrations, it was shown that the decrease in stream water Cl^? concentrations was caused mainly by this step shift in the Cl^? input. It was proposed that the change in Cl^? concentrations after forest cutting could be used to represent the replacement of ‘old’ water that existed before cutting by ‘new’ water that was supplied after cutting. The breakthrough curve for the new water fraction gave an approximately exponential distribution of transit times in flow‐corrected time. The mean flow‐corrected transit time was estimated as 1068 days (runoff: 3497 mm). It was therefore concluded that the step change in input Cl^? concentrations immediately following forest clear‐cutting could be successfully used to estimate transit times for the entire catchment. Copyright © 2009 John Wiley & Sons, Ltd.     

Analysis of suspended sediment yields after low impact forest harvesting

Disturbances to forest catchments have profound effects on the environment of headwater streams and have an impact on suspended sediment (SS) management. Forest harvesting is a dominant factor in increasing SS yields. Road construction, skidder activity and ploughing associated with harvesting cause serious soil disturbance that results in SS increases. However, few studies have shown whether harvesting itself increases SS yields. This study examined how harvesting influenced SS yields in a steep forested area. During harvesting, soil surface disturbance was prevented as much as possible by using skyline logging treatments and piling branches and leaves at selected locations in the watershed. Using these methods, the representative SS rating curve did not change significantly after harvesting. The results also show that the characteristics of SS transport were related to the SS source area, and reveal that the riparian zone/stream bank was a dominant SS source area at the study site. Annual SS yields did not increase despite increasing annual water yields after harvesting. The limited water capacity of the soil at the study site likely led to only slight differences in pre‐ and post‐harvest water discharge from heavy rainfall events. Most SS was transported during heavy rainfall events, and increases in SS yields were not detected after harvesting. We concluded that it is possible to prevent post‐harvest SS increases by performing careful, low‐impact harvesting procedures. Copyright © 2007 John Wiley & Sons, Ltd.     

Estimation of vertical profiles of leaf drying times after daytime rainfall within a Bornean tropical rainforest

South‐east Asian Bornean tropical rainforests have large and complex canopy structures. To clarify how forest structure affects wet‐canopy evaporation, it is necessary to consider wet‐canopy evaporation processes within the forest canopy, such as vertical profiles of canopy drying time. In a previous study a method was proposed that utilizes sap flow measurements to estimate canopy drying time after rainfall (CDTobs) during daytime. In this present study, the method was applied to estimations of the vertical variations in CDTobs in 11 individual trees of various heights, ranging from 2·7 m to 53 m. The study derived vertical profiles and showed that the lengths of CDTobs in lower canopy trees were 2–4 h longer than those in the upper canopy trees. The new method for CDTobs profiles presented in this study, which is available for validation of multi‐layer biosphere‐atmospheric models, is a useful illustration for clarifying wet‐canopy evaporation processes in tropical rainforests. Copyright © 2008 John Wiley & Sons, Ltd.     

Constituents of Vertical-component Coda Waves at Long Periods

Aki (1969) first modeled coda waves of a local earthquake as a superposition of scattered surface waves. This paper attempts to clarify the constituents of surface-wave coda at long periods at very long lapse times. For a large earthquake of magnitude 7 or larger, vertical component oscillation in periods from 90 to 180 s persists for more than 20 hours from the earthquake origin time. Although the early portion of the coda envelope is successfully modeled by assuming incoherent scattered Rayleigh waves by heterogeneities distributed all over the Earth, the later potion of the observed coda envelope (roughly later than 35,000 s) has systematically larger amplitude than theoretical prediction. To clarify the cause of this discrepancy, we studied the constituents of vertical-component seismograms of three large earthquakes recorded by the F-net in Japan using the f-k power spectral analysis. We found that the direct and scattered fundamental-mode Rayleigh waves of velocity about 3.7 km/s are dominant in the earlier part of each envelope. It justifies the use of a scattering model of the fundamental Rayleigh waves for synthesizing the envelope. At lapse times later than 20,000 s–35,000 s, higher modes with phase velocities around 20 km/s become dominant. The transition time to the dominance of higher modes is found to become earlier for a deeper focus earthquake. The small coda attenuation factor from (1.90±0.23) × 10⁻³ to (2.38±0.32) × 10⁻³ estimated from later coda envelopes recorded at IRIS stations distributed worldwide also agrees with the attenuation factor of spheroidal modes according to PREM. We may interpret that higher mode waves are uniformly distributed at large lapse time due to large velocity dispersion and/or scattering and they dominate over the fundamental mode waves because of smaller attenuation in the lower mantle. The coda attenuation measurement proposed by Aki is found to be useful even for long periods and at very large lapse times.     

Accretion process of the moon

Recent geochemical and geophysical data suggest that the initial temperature of the Moon was strongly peaked toward the lunar surface. To explain such an initial temperature distribution, a simple model of accretion process of the Moon is presented. The model assumes that the Moon was formed from the accumulation of the solid particles or gases in the isolated, closed cloud. Two equations are derived to calculate the accretion rate and surface temperature of the accreting Moon. Numerical calculations are made for a wide range of the parameters particle concentration and particle velocity in the cloud. A limited set of the parameters gives the initial temperature profiles as required by geochemical and geophysical data. These models of the proto-moon cloud indicate that the lunar outershell, about 400 km thick, was partially or completely molten just after the accretion of the Moon and that the Moon should have been formed in a period shorter than 1000 yr. If the Moon formed at a position nearer to the Earth than its present one, the Moon might have been formed in a period of less than one year.On leave from Geophysical Institute, University of Tokyo.Contribution No. 2104, Division of Geological and Planetary Sciences, California Institute of Technology.     

Latitudinal distribution of HDO abundance above Venus’ clouds by ground-based 2.3 μm spectroscopy

The abundance of HDO above the clouds in the dayside atmosphere of Venus was measured by ground-based 2.3 μm spectroscopy over 4 days. This is the first HDO observation above the clouds in this wavelength region corresponding to a new height region. The latitudinal distributions found show no clearly defined structure. The disk-averaged mixing ratio is 0.22 ± 0.03 ppm for a representative height region of 62–67 km. This is consistent with measurements found in previous studies. Based on previous H₂O measurements, the HDO/H₂O ratio is found to be 140 ± 20 times larger than the telluric ratio. This lies between the ratios of 120 ± 40 and 240 ± 25, respectively, reported for the 30–40 km region by ground-based nightside spectroscopy and for the 80–100 km region by solar occultation measurement on board the Venus Express.     

Inter-model variability of projected sea level changes in the western North Pacific in CMIP3 coupled climate models

We investigate sea level changes in the western North Pacific for twenty-first century climate projections by analyzing the output from 15 coupled models participating in the Coupled Model Intercomparison Project phase 3 (CMIP3). Projected changes in the wind stress due to those in sea level pressure (SLP) result in the projected sea level changes. In the western North Pacific (30?50°N, 145?170°E), the inter-model standard deviation of the sea level change relative to the global mean is comparable to that based on the multi-model ensemble (MME) mean. Whereas a positive SLP change in the eastern North Pacific (40?50°N, 170?150°W) induces a large northward shift of the Kuroshio Extension (KE), a negative SLP change in this region induces a strong intensification of the KE. Large inter-model variability of the SLP projection in the eastern North Pacific causes a large uncertainty of the sea level projection in the western North Pacific. Models with a larger northward shift (intensification) of the KE exhibit a poleward shift (an intensification) of the Aleutian Low (AL) larger than that for the MME mean. However, models that exhibit a larger intensification of the AL do not necessarily show a larger intensification of the KE. Our analysis suggests that the SLP change that induces an intensification of the KE is associated with a teleconnection from the equatorial Pacific, and that the SLP change that induces a northward shift of the KE is characterized by a zonal mean change.     

Prolonged impact of earthquake-induced landslides on sediment yield in a mountain watershed: The Tanzawa region, Japan

To determine for how long a landslide affects sediment discharge, the sediment yields of 15 check-dam basins were compared with the time series of landslide distributions in a mountain basin in the Tanzawa region, central Japan. The distribution of sediment yield was quantitatively estimated from deposition in the sediment pools of check dams. The relationship between the landslide history and sediment discharge in the Nakagawa River basin was examined for an approximately 80-year period. Two major landslide events occurred during this period: the 1923 Kanto Earthquake and the 1972 disaster caused by heavy rainfall. The resulting trend in sediment discharge of the whole basin, estimated using reservoir sedimentation in the Miho Dam at its base, was nearly constant, with high sediment discharge (2897 m³ km^− 2 yr^− 1) in the intervening quarter-century, despite the recovery of vegetation on landslide areas in this period. Comparisons of the landslide distributions resulting from the two disasters, the sediment yields of check-dam basins, and the sediment discharge of the whole basin indicate that recent sediment discharge contains landslide debris that was originated by the Kanto Earthquake that occurred over 80 years ago. Thus, to understand high sediment discharge, it is essential to investigate not only the current basin condition and recent events, but also the landslide history of the basin for at least the previous 100 years.