Diagenetic behavior of manganese in Tokyo Bay sediment

To understand the behavior of manganese in diagenetic processes in sediments of an enclosed bay which is similar to those of an estuary, chemical analyses have been carried out on both sediment and interstitial water of a core sample collected from Tokyo Bay. The results suggest that redistribution of manganese takes place within the sediment as a result of the dissolution of buried manganese oxides and hydroxides under reducing condition, the downward diffusion of Mn²⁺ through the interstitial water toward lower layers and then the precipitation of carbonate. The carbonate formed in the sediment contains managanese carbonate probably as a solid solution between calcitic calcium carbonate and manganese carbonate.     

Pin‐supported walls for enhancing the seismic performance of building structures

An application of a pin‐supported wall‐frame system in retrofitting an eleven‐story steel reinforced concrete frame is introduced. The retrofit aims at enhancing integrity and avoiding weak story failure in an existing moment‐resisting frame. Seismic performance of the building before and after the retrofit is assessed through nonlinear dynamic analysis. The results show that the pin‐supported walls are effective in controlling the deformation pattern of the ductile frame and hence in avoiding weak story failure. With the well‐controlled deformation pattern, carefully arranged energy dissipating devices are able to concentrate energy dissipations so that damage to the rest of the structure can be significantly reduced. Copyright © 2012 John Wiley & Sons, Ltd.     

Detrital zircon multi‐chronology,provenance, and low‐grade metamorphism of the Cretaceous Shimanto accretionary complex,eastern Shikoku,Southwest Japan: Tectonic evolution in response to igneous activity within a subduction zone

Detrital zircon multi‐chronology combined with provenance and low‐grade metamorphism analyses enables the reinterpretation of the tectonic evolution of the Cretaceous Shimanto accretionary complex in Southwest Japan. Detrital zircon U–Pb ages and provenance analysis defines the depositional age of trench‐fill turbidites associated with igneous activity in provenance. Periods of low igneous activity are recorded by youngest single grain zircon U–Pb ages (YSG) that approximate or are older than the depositional ages obtained from radiolarian fossil‐bearing mudstone. Periods of intensive igneous activity recorded by youngest cluster U–Pb ages (YC1σ) that correspond to the younger limits of radiolarian ages. The YC1σ U–Pb ages obtained from sandstones within mélange units provide more accurate younger depositional ages than radiolarian ages derived from mudstone. Determining true depositional ages requires a combination of fossil data, detrital zircon ages, and provenance information. Fission‐track ages using zircons estimated YC1σ U–Pb ages are useful for assessing depositional and annealing ages for the low‐grade metamorphosed accretionary complex. These new dating presented here indicates the following tectonic history of the accretionary wedge. Evolution of the Shimanto accretionary complex from the Albian to the Turonian was caused by the subduction of the Izanagi plate, a process that supplied sediments via the erosion of Permian and Triassic to Early Jurassic granitic rocks and the eruption of minor amounts of Early Cretaceous intermediate volcanic rocks. The complex subsequently underwent intensive igneous activity from the Coniacian to the early Paleocene as a result of the subduction of a hot and young oceanic slab, such as the Kula–Pacific plate. Finally, the major out‐of‐sequence thrusts of the Fukase Fault and the Aki Tectonic Line formed after the middle Eocene, and this reactivation of the Shimanto accretionary complex as a result of the subduction of the Pacific plate.     

Adsorption of tributyltin by tributyltin resistant marine Pseudoalteromonas sp. cells

The isolate, Pesudoalteromonas sp. TBT1, could grow to overcome the toxicity of tributyltin chloride (TBTCl) up to 30 μM in the absence of Cl⁻ in the medium until the cells reached an exponential phase of growth. The viability, however, was reduced after the cells reached a stationary phase. The degradation products, such as dibutyltin (DBT) and monobutyltin (MBT), were not detected in the growth medium, indicating that the isolate has no ability to degrade TBT into less toxic DBT and MBT. Up to about 10^7.5 TBT molecules were adsorbed by a single cell. The observation of morphological changes with an electron microscope showed that the cell surface became wrinkled after exposure to the lethal concentration of 10 mM TBTCl. These results indicate that the resistance of the isolate toward the toxicity of TBTCl is not related to the unique cell surface, which seems to play an important role in preventing the diffusion of TBTCl into the cytoplasm.     

Secular change in lifetime of granitic crust and the continental growth: A new view from detrital zircon ages of sandstones

U-Pb ages of detrital zircons were newly dated for 4 Archean sandstones from the Pilbara craton in Australia, Wyoming craton in North America, and Kaapvaal craton in Africa. By using the present results with previously published data, we compiled the age spectra of detrital zircons for 2.9, 2.6, 2.3,1.0, and0.6 Ga sandstones and modern river sands in order to document the secular change in age structure of continental crusts through time. The results demonstrated the following episodes in the history of continental crust:(1) low growth rate of the continents due to the short cycle in production/destruction of granitic crust during the Neoarchean to Paleoproterozoic(2.9-23 Ga),(2) net increase in volume of the continents during Paleo-to Mesoproterozoic(2.3-1.0 Ga), and(3) net decrease in volume of the continents during the Neoproterozoic and Phanerozoic(after 1.0 Ga). In the Archean and Paleoproterozoic, the embryonic continents were smaller than the modern continents, probably owing to the relatively rapid production and destruction of continental crust. This is indeed reflected in the heterogeneous crustal age structure of modern continents that usually have relatively small amount of Archean crusts with respect to the post-Archean ones. During the Mesoproterozoic, plural continents amalgamated into larger ones comparable to modern continental blocks in size. Relatively older crusts were preserved in continental interiors, whereas younger crusts were accreted along continental peripheries.In addition to continental arc magmatism, the direct accretion of intra-oceanic island arc around continental peripheries also became important for net continental growth. Since 1.0 Ga, total volume of continents has decreased, and this appears consistent with on-going phenomena along modern active arc-trench system with dominant tectonic erosion and/or arc subduction. Subduction of a huge amount of granitic crusts into the mantle through time is suggested, and this requires re-consideration of the mantle composition and heterogeneity.     

Formation of thermohaline front by cooling of the sea surface and inflow of the fresh water

A numerical study of characteristics of the front formed by cooling of the sea surface and inflow of the fresh water is made within a vertical two-dimensional plane without the rotation of the earth. The convective adjustment technique is employed to parameterize the small scale convective overturning process.A sharply edged shelf causing the marked difference of the heat capacity of the water columns between over the shelf (50 m depth) and in the deeper region (150 m depth), is responsible for the formation of a thermal front over the shelf edge and two cell circulations of the same sense with each other adjoining at the frontal region.Inflow of the fresh water at the upper region of the coast (which is equivalently replaced by the outflow of the salt from the same region) adds a circulation of the opposite sense to the above ones, which transports the water of low salinity and low temperature offshore and forms a sharp front both of temperature and salinity with the offshore water of high salinity and high temperature. This thermohaline front or Oceanic front has a remarkable character that the horizontal density gradient is minimal at the front due to the counteracting contributions of temperature and salinity to density. Response of this front to the sudden ceases of the surface cooling and the fresh water supply, is also studied in order to understand its transient behaviors.     

Audio frequency magneto-telluric survey of Norikura Volcano in central Japan

Norikura Volcano has not been active during the last 10,000 years in spite of the activity of the surrounding volcanic mountains. To study past volcanic activities, geological studies were carried out extensively. However, quite a few geophysical investigations were conducted to contribute to volcanology. Our objective is to detect the present subsurface structure of Norikura Volcano and to define volcanic stratifications. In the vicinity of Norikura Volcano, geothermal fields are still active. Subsurface volcanic rocks in this area have been exposed to geothermal activity and altered. To comprehend volcanic stratifications of Norikura and geothermal activity, we conducted audio frequency magneto-telluric (AMT) surveys around Norikura Volcano. AMT survey is useful in clearly defining the resistivity structure related to volcanic regions. The AMT data were acquired over a frequency range 10 Hz–10 kHz. Decomposition analysis was applied to the tensor impedance data. Subsequently, apparent resistivity and phase data were inverted using a two-dimensional magneto-telluric (MT) inversion and a model of Norikura was derived. The final model manifests that the surface resistors are in agreement with andesite lava or dacite lava. As for the deeper structure, a horizontal conductor is situated above resistive basements. The alteration of the conductor was weak, while basement rocks were strongly altered and/or heated through the thermal activity. The existence of these layers seems to indicate the degree of thermal activity of Norikura Volcano.     

Thermal evolution of the Tseel terrane,SW Mongolia and its relation to granitoid intrusions in the Central Asian Orogenic Belt

The timing and thermal effects of granitoid intrusions into accreted sedimentary rocks are important for understanding the growth process of continental crust. In this study, the petrology and geochronology of pelitic gneisses in the Tseel area of the Tseel terrane, SW Mongolia, are examined to understand the relationship between igneous activity and metamorphism during crustal evolution in the Central Asian Orogenic Belt (CAOB). Four mineral zones are recognized on the basis of progressive changes in the mineral assemblages in the pelitic gneisses, namely: the garnet, staurolite, sillimanite and cordierite zones. The gneisses with high metamorphic grades (i.e. sillimanite and cordierite zones) occur in the central part of the Tseel area, where granitoids are abundant. To the north and south of these granitoids, the metamorphic grade shows a gradual decrease. The composition of garnet in the pelitic gneisses varies systematically across the mineral zones, from grossular‐rich garnet in the garnet zone to zoned garnet with grossular‐rich cores and pyrope‐rich rims in the staurolite zone, and pyrope‐rich garnet in the sillimanite and cordierite zones. Thermobarometric analyses of individual garnet crystals reveal two main stages of metamorphism: (i) a high‐P and low‐T stage (as recorded by garnet in the garnet zone and garnet cores in the staurolite zone) at 520–580 °C and 4.5–7 kbar in the kyanite stability field and (ii) a low‐P and high‐T stage (garnet rims in the staurolite zone and garnet in the sillimanite and cordierite zones) at 570–680 °C and 3.0–6.0 kbar in the sillimanite stability field. The earlier high‐P metamorphism resulted in the growth of kyanite in quartz veins within the staurolite and sillimanite zones. The U–Pb zircon ages of pelitic gneisses and granitoids reveal that (i) the protolith (igneous) age of the pelitic gneisses is c. 510 Ma; (ii) the low‐P and high‐T metamorphism occurred at 377 ± 30 Ma; and (iii) this metamorphic stage was coeval with granitoid intrusion at 385 ± 7 Ma. The age of the earlier low‐T and high‐P metamorphism is not clearly recorded in the zircon, but probably corresponds to small age peaks at 450–400 Ma. The low‐P and high‐T metamorphism continued for c. 100 Ma, which is longer than the active period of a single granitoid body. These findings indicate that an elevation of geotherm and a transition from high‐P and low‐T to low‐P and high‐T metamorphism occurred, associated with continuous emplacement of several granitoids, during the crustal evolution in the Devonian CAOB.     

Disorder and damage of base‐isolated medical facilities when subjected to near‐fault and long‐period ground motions

A series of full‐scale shaking table tests were conducted at E‐Defense for a four‐story base‐isolated hospital. The operation room in the specimen was chosen for detailed examination of its disorder and damage during large ground motions. It was arranged with various medical appliances in as a realistic manner as possible, and the appliances were characterized by casters installed at the bottom to ensure mobility. Two types of ground motion, the near‐fault ground motion and long‐period ground motion, were adopted, and the responses of the appliances were recorded using the motion capture technique. Thanks to the base isolation, the floor response was greatly reduced, and no disorder or damage was observed in the operation room except for the case when subjected to a long‐period ground motion. In this case, the unlocked appliances moved seriously (by more than 3 m), and collisions occurred between the appliances and between appliances and the surrounding wall. The force of collision reached 36 kN, which is sufficient to injure a person. The acceleration due to collision was as high as 10 g, which is far beyond what can be tolerated by acceleration‐sensitive appliances. It is notable that such large motion was not observed once the appliances were locked. The test was also carried out for the corresponding fixed‐base structure. Among all cases in the experiment, by far the most serious damage occurred in the fixed‐base structure when subjected to the near‐fault ground motion, clearly because the floor response was significantly amplified from the ground motion. Copyright © 2014 John Wiley & Sons, Ltd.