Mass balance and sources of mercury in Tokyo Bay

The mass balance and sources of mercury in Tokyo Bay were investigated on the basis of observations from December 2003 to January 2005. Estimated input terms included river discharge (70 kg yr⁻¹) and atmospheric deposition (37 kg yr⁻¹), and output terms were evasion (49 kg yr⁻¹), export (13 kg yr⁻¹) and sedimentation (495 kg yr⁻¹). Thus, the outputs (557 kg yr⁻¹) considerably exceeded the inputs (107 kg yr⁻¹). In addition, the imbalance between the inputs and outputs of mercury was much larger than that of other trace metals (Cd, Cr, Cu, Pb and Zn), which suggests that there are other major inputs of mercury to Tokyo Bay. The mercury concentrations in rivers correlated significantly with the concentrations of Al and Fe, major components of soil. In Japan, large amounts of organomercurous fungicides (about 2500 tons as Hg) were used extensively in fields in the past, and most of the mercury was retained in the soil. In this study, the mercury concentration in rivers was measured primarily in ordinary runoff. These observations lead to the hypothesis that field soil discharged into stormwater runoff is a major source of mercury in Tokyo Bay. As a preliminary approach to validating this hypothesis, we measured the concentrations of mercury and other trace metals in river water during a typhoon. The mercury concentrations in stormwater runoff increased to 16–50 times the mean value in ordinary runoff, which is much higher than the increases for other metals. This tends to support the hypothesis.     

A numerical experiment on the variations of western boundary currents: Part II. Response to a moving typhoon

Response of the barotropic western boundary current to typhoon passage is investigated by the use of the numerical models described in Part I. Steady states obtained in Part I are chosen as the initial conditions for undisturbed currents. In these models it is assumed that an axially symmetric typhoon (radius = 100 km, maximum wind speed = 27.4 m/sec) moves parallel to the western boundary.For the model with a flat bottom the boundary flow diminishes its strength and broadens its width after the passage of the typhoon offshore. For the model with a continental slope the effect of the typhoon is significantly different depending on the distance of the path of the typhoon from the western boundary. Specifically the north wind on the continental slope causes the formation of cyclonic vortex, which progresses southwards along the slope in the northern hemisphere. Linear theory of continental shelf waves indicates that the phase speed of the propagation of the vortex is 2.4 m/sec. Anomalies of the water level along the coast are also calculated from geostrophic relationships.     

Contribution of abiogenic and biogenic particles to trace-metal composition of phytoplankton assemblages in seawater of Shimizu Port, Japan

The contribution of abiogenic and biogenic particles to trace-metal (As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sb, Ti, V, and Zn) composition was investigated for phytoplankton (primarily diatoms) collected in Shimizu Port, a coastal seawater region. Except for Cd, the trace metals occurred predominantly in lithogenic or nonlithogenic abiogenic particles associated with plankton. In contrast, it is likely that Cd in seawater is taken up intracellularly, and not adsorbed extracellularly by phytoplankton. The lower P-normalized quotas of Cd in Shimizu Port than in offshore regions may be because plankton are dominated by diatoms.     

Dynamical evolution of two-component star clusters

The dynamical evolution of two-component star clusters, each of which is enclosed within a perfectly reflecting sphere, is investigated by numerically solving moment equations derived from the Boltzmann equation. One of the two adopted model clusters evolves, starting from a state of no mass segregation, toward an equilibrium state at a quite slow rate. The other one evolves away from an equilibrium state and its central density increases without limit. The different evolutionary behaviors of the two model clusters are explained by the fact that there exists no equilibrium state for such clusters if the total energy is less than a certain critical value. The critical value increases with increasing total mass fraction of the heavier stars. This is qualitatively the same as Spitzer's theorem (1969) expressed in another way.     

Steel slit shear walls with double‐tapered links capable of condition assessment

The concept of using a hysteretic damper as a condition assessment device that functions immediately after a damaging earthquake is realized by making use of the residual out‐of‐plane deformation of links that are arranged in slit shear walls. According to the proposed inspection procedure, the maximum drift ratio experienced by the slit wall is estimated based on the number of torsionally deformed links whose dimensions are determined so that the links would exhibit notable torsional deformation at the target deformations. The adoption of a double‐tapered shape for the links enables us to significantly increase the amount of out‐of‐plane deformation. The relationship between the dimensions and the torsional deformation of the links is established using numerical simulations. The effectiveness of the proposed condition assessment scenario is verified by using a series of cyclic loading tests for individual links and groups of links. As a hysteretic damper, the strength and stiffness of the links predicted by design equations matched well with test results. Copyright © 2014 John Wiley & Sons, Ltd.     

Cathodoluminescence microscopy and spectroscopy of forsterite from Kaba meteorite: An application to the study of hydrothermal alteration of parent body

Highly forsteritic olivine (Fo: 99.2–99.7) in the Kaba meteorite emits bright cathodoluminescence (CL). CL spectra of red luminescent forsterite grains have two broad emission bands at approximately 630 nm (impurity center of divalent Mn ions) in the red region and above 700 nm (trivalent Cr ions) in the red–IR region. The cores of the grains show CL blue luminescence giving a characteristic broad band emission at 400 nm, also associated with minor red emissions related to Mn and Cr ions. CL color variation of Kaba forsterite is attributed to structural defects. Electron probe microanalyzer (EPMA) analysis shows concentrations of Ca, Al, and Ti in the center of the forsterite grain. The migration of diffusible ions of Mn, Cr, and Fe to the rim of the Kaba meteoritic forsterite was controlled by the hydrothermal alteration at relatively low temperature (estimated at about 250 °C), while Ca and Al ions might still lie in the core. A very unusual phase of FeO (wüstite) was also observed, which may be a terrestrial alteration product of FeNi‐metal.     

Naturally occurring radionuclides and rare earth elements in weathered Japanese soil samples

The activity concentrations of ²²⁶Ra and ²²⁸Ac in weathered Japanese soils from two selected prefectures have been measured using a γ-ray spectroscopy system with high purity germanium detector. The uranium, thorium, and rare earth elements (REEs) concentrations were determined from the same soil samples using inductively coupled plasma mass spectrometry (ICP-MS). For example, granitic rocks contain higher amounts of U, Th, and light REEs compared to other igneous rocks such as basalt and andesites. Therefore, it is necessary to understand the interaction between REEs and nature of soils since soils are complex heterogeneous mixture of organic and inorganic solids, water, and gases. In this paper, we will discuss about distribution pattern of ²³⁸U and ²³²Th along with REEs in soil samples of weathered acid rock (granite) collected from two prefectures of Japan: Hiroshima and Miyagi.